Ok, để thử coi chứ tui ngu hóa thấy mồ :(

a/ \(n_{NaOH}=0,2.0,1=0,02\left(mol\right)\)

\(NaOH\rightarrow Na^++OH^-\)

\(n_{Na^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow C_{MNa^+}=\frac{0,02}{0,4+0,1}=0,04\left(mol/l\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,4=0,12\left(mol\right)\)

\(Ba\left(OH\right)_2=Ba^{2+}+2OH^-\)

\(\Rightarrow n_{OH^-}=0,24\left(mol\right);n_{Ba^{2+}}=0,12\left(mol\right)\)

\(\Rightarrow C_{MBa^{2+}}=\frac{0,12}{0,5}=0,24\left(mol/l\right)\)

\(n_{OH^-}=0,02+0,24=0,26\left(mol\right)\)

\(\Rightarrow C_{MOH^-}=\frac{0,26}{0,5}=0,52\left(mol/l\right)\)

b/ \(n_{HCl}=0,2V\left(mol\right)\)

\(\Rightarrow n_{H^+}=n_{Cl^-}=0,2V\)

\(\Rightarrow C_{MCl^-}=\frac{0,2V}{2V}=0,1\left(mol/l\right)\)

\(n_{H_2SO_4}=0,3V\left(mol\right)=\frac{n_{H^+}}{2}=n_{SO_4^{2-}}\)

\(\Rightarrow C_{MSO_4^{2-}}=\frac{0,3V}{2V}=0,15\left(mol/l\right)\)

\(n_{H^+}=0,2V+0,6V=0,8V\left(mol\right)\)

\(\Rightarrow C_{MH^+}=\frac{0,8V}{2V}=0,4\left(mol/l\right)\)

Bác nào hảo tâm giúp em mấy câu còn lại chớ đến đây thì em chịu chết òi :(

a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)

\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)

\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\) 

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,03___0,03 (mol) ⇒ n_H⁺ dư = 0,05 (mol)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

0,015___0,015______0,015 (mol) ⇒ n_SO4^2- dư = 0,015 (mol)

⇒ m = m_BaSO4 = 0,015.233 = 3,495 (g)

\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)

\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)

b, pH = -log[H⁺] = 1

a, \(n_{Ba\left(OH\right)_2}=0,1.0,1=0,01\left(mol\right)=n_{Ba^{2+}}\)

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,02\left(mol\right)\)

\(n_{NaOH}=0,1.0,1=0,01\left(mol\right)=n_{Na^+}=n_{OH^-}\)

⇒ Σn_OH^- = 0,02 + 0,01 = 0,03 (mol)

\(n_{H_2SO_4}=0,4.0,0175=0,007\left(mol\right)=n_{SO_4^{2-}}\)

\(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,014\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,014___0,014 (mol) ⇒ n_OH^- dư = 0,03 - 0,014 = 0,016 (mol)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

0,007____0,007_____0,007 (mol) ⇒ n_Ba²⁺ dư = 0,01 - 0,007 = 0,003 (mol)

⇒ m = 0,007.233 = 1,631 (g)

\(\left[OH^-\right]=\dfrac{0,016}{0,1+0,4}=0,032\left(M\right)\)

\(\left[Ba^{2+}\right]=\dfrac{0,003}{0,1+0,4}=0,006\left(M\right)\)

\(\left[Na^+\right]=\dfrac{0,01}{0,1+0,4}=0,02\left(M\right)\)

b, pH = 14 - (-log[OH^-]) ≃ 12,505

\(n_{Ba^{2+}}=0,1.0,1=0,01\left(mol\right)\)

\(n_{SO_4^{2-}}=0,4.0,0175=7.10 ^{-3}\left(mol\right)\)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\downarrow\)

\(\Rightarrow m=m_{BaSO_4}=7.10^{-3}.233=1,631\left(g\right)\)

Ta có:

\(n_{H^+}=0,4.0,0175.2=0,014\left(mol\right)\)

\(n_{OH^-}=0,1.0,1.2+0,1.0,1=0,03\left(mol\right)\)

Trong dung dịch X:

\(n_{OH^-}=0,03-0,014=0,016\left(mol\right)\)\(\Rightarrow\left[OH^-\right]=\dfrac{0,016}{0,1+0,4}=0,032\left(M\right)\)

\(n_{Ba^{2+}}=0,01-7.10^{-3}=3.10^{-3}\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{3.10^{-3}}{0,1+0,4}=6.10^{-3}\left(M\right)\)

\(n_{Na^+}=0,1.0,1=0,01\left(mol\right)\Rightarrow\left[Na^+\right]=0,02\)

\(pOH=-lg\left(0,032\right)\approx1,5\Rightarrow pH=14-1,5=12,5\)

a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)

b, Để trung hòa dung dịch A thì:

\(n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)

\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)

cần lời giải chi tiết ạ

Đáp án B

[OH^-]= (0,5.2.0,1+0,1.0,5)/0,2= 0,75M

\(n_{HCl}=Cm.V=1.0,1=1mol\)

\(n_{H_2SO_4}=Cm.V=0,5.0,1=0,05mol\)

Thể thích của dd D là 200ml = 0,2l

\([H^+]=\frac{n_{HCl}+2.n_{H_2SO_4}}{V}=\frac{0,1+0,1}{0,2}=1M\)

\([Cl^-]=\frac{n_{HCl}}{V}=\frac{0,1}{0,2}=0,5M\)

\([SO_4^{2-}]=\frac{n_{H_2SO_4}}{V}=\frac{0,05}{0,2}=0,25M\)

Khi cho dd D vào \(Ba\left(OH\right)_2\) chỉ có \(H_2SO_4\) tác dụng, tạo kết tủa

\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)

\(0,05....\rightarrow0,05mol\)

\(\rightarrow m_{BaSO_4}=n.M=0,05.233=11,65g\)

nKOH = 0,0015 mol
nBa(OH)2 = 0,001 mol
=> n[OH-] = 0,0015+0,001.2=0,0035 mol
=> p[OH-] = 2,456
=> p[H+] = 14-p[OH-]=11,544