\(\left\{{}\begin{matrix}n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\n_{KOH}=1.0,2=0,2\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{n_{KOH}}{n_{SO_2}}=\dfrac{0,2}{0,3}=0,67\) => Tạo muối KHSO₃

PTHH: KOH + SO₂ --> KHSO₃

             0,2------------->0,2

=> m_KHSO3 = 0,2.120 = 24 (g)

Gọi số mol CO₂ và SO₂ là a, b (mol)

= >\(\left\{{}\begin{matrix}n_{khí}=a+b=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\\dfrac{44a+64b}{a+b}=29,5.2=59\end{matrix}\right.\) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,3\left(mol\right)\end{matrix}\right.\)

\(n_{NaOH}=1.0,4=0,4\left(mol\right)\)

PTHH: NaOH + CO₂ --> NaHCO₃

________0,1<----0,1------->0,1_______(mol)

NaOH + SO₂ --> NaHSO3

_0,3<----0,3-------->0,3_____________(mol)

=> \(\left\{{}\begin{matrix}C_{M\left(NaHCO_3\right)}=\dfrac{0,1}{0,4}=0,25M\\C_{M\left(NaHSO_3\right)}=\dfrac{0,3}{0,4}=0,75M\end{matrix}\right.\)

a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)

\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CaCO_3}=n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\)

a, Ta có: \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(n_{KOH}=\dfrac{44,8}{56}=0,8\left(mol\right)\)

\(\Rightarrow\dfrac{n_{KOH}}{n_{SO_2}}=1,3333\)

⇒ Dd sau pư gồm: K₂SO₃ và KHSO₃.

b, PT: \(SO_2+2KOH\rightarrow K_2SO_3+H_2O\)

\(SO_2+KOH\rightarrow KHSO_3\)

Giả sử: \(\left\{{}\begin{matrix}n_{K_2SO_3}=x\left(mol\right)\\n_{KHSO_3}=y\left(mol\right)\end{matrix}\right.\)

Theo PT: \(\left\{{}\begin{matrix}x+y=0,6\\2x+y=0,8\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,4\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,2.158=31,6\left(g\right)\\m_{KHSO_3}=0,4.120=48\left(g\right)\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_{SO_2}=\dfrac{8.96}{22.4}=0.4mol\)

\(n_{NaOH}=0.5mol\)

Lập tỉ lệ: \(\dfrac{n_{NaOH}}{n_{SO_2}}=\dfrac{0.5}{0.4}=1.25\)

=> Thu được 2 muối \(NaHSO_3\) và \(Na_2SO_3\)

\(SO_2+NaOH\rightarrow NaHSO_3\)

 a           a                 a

\(SO_2+2NaOH\rightarrow Na_2SO_3+H_2O\)

 b            2b                 b        

Ta có: \(\left\{{}\begin{matrix}a+b=0.4\\a+2b=0.5\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.3\\b=0.1\end{matrix}\right.\)

Khối lượng muối thu được: \(m_{muoi}=0.3\times104+0.1\times126=43.8g\)

C

 B