n chất rắn =m Cu=19,2 g

=>m Mg, Al=29,4-19,2=10,2g

Mg+2HCl->MgCl₂+H₂

x-------------------------x

2Al+6HCl->2AlCl₃+3H₂

y--------------------------\(\dfrac{3}{2}\)y

=>Ta có :

\(\left\{{}\begin{matrix}24x+27y=10,2\\x+\dfrac{3}{2}y=\dfrac{11,2}{22,4}\end{matrix}\right.\)

=>x=0,2 mol , y=0,2 mol

=>% Cu=\(\dfrac{19,2}{29,4}\).100=65,3%

=>%Mg=\(\dfrac{0,2.24}{29,4}\).100=16,32%

=>%Al=100-65,3-16,32=18,28%

b)MgCl₂+2AgNO₃->2AgCl+Mg(NO₃)₂

     0,2----------------------0,4

   AlCl₃+3AgNO₃->Al(NO₃)₃+3AgCl

0,2-----------------------------------------0,6

=>m _AgCl=(0,6+0,4).143,5=143,5g

- Thấy Cu không phản ứng với HCl .

\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

.x.......................................1,5x.........

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

.y....................................y.............

Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )

b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

.......0,1.........0,2...............................

\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)

...0,2.......0,6..........................

\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)

=> Trong B còn có HCl dư .

\(NaOH+HCl\rightarrow NaCl+H_2O\)

...0,2..........0,2....................

=> Dư 0,2 mol HCl .

\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)

\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)

Vậy ....

Rainbow

nH2SO4=0,4*1=0,4 mol

nH2=6,72/22,4=0,3 mol

2Al + 3H2SO4 -->Al2(So4)3 + 3H2

 0,2                                             0,3          mol 

=> mAl = 0,2*27=5,4 g

=> mCu =5,9-5,4=0,5 g

BaCl2 + H2SO4 --> BaSO4 + 2HCl

                0,4              0 ,4                       mol

=> m BaSO4 = 0,4 * 233=93,2 g      

\(a) 2Al+ 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ n_{Al} = \dfrac{2}{3}n_{H_2} = 0,2(mol)\\ m_{Al} = 0,2.27 = 5,4(gam)\\ m_{Cu} = 5,9 - 5,4 = 0,5(gam)\\ b) \)

Bảo toàn nguyên tố với S :

\(n_{BaSO_4} = n_{H_2SO_4} = 0,4(mol)\\ m = 0,4.233 = 93,2(gam)\)

\(a) 2Al+ 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ n_{Al} = \dfrac{2}{3}n_{H_2} = 0,2(mol)\\ m_{Al} = 0,2.27 = 5,4(gam)\\ m_{Cu} = 5,9 - 5,4 = 0,5(gam)\\ b) \)

Bảo toàn nguyên tố với S :

\(n_{BaSO_4} = n_{H_2SO_4} = 0,4(mol)\\ m = 0,4.233 = 93,2(gam)\)