a) \(n_O=\dfrac{34,8-25,2}{16}=0,6\left(mol\right)\)

=> \(n_{H_2O}=0,6\left(mol\right)\) (bảo toàn O)

=> \(n_{H_2}=0,6\left(mol\right)\) (bảo toàn H)

=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)

b) \(n_{Fe}=\dfrac{25,2}{56}=0,45\left(mol\right)\)

n_Fe : n_O = 0,45 : 0,6 = 3 : 4

=> CTHH: Fe₃O₄

c) \(m_{H_2O}=0,6.18=10,8\left(g\right)\)

Mà \(d_{H_2O}=1\left(g/ml\right)\)

=> \(V_{H_2O}=10,8\left(ml\right)\)

a)

\(Zn + 2HCl \to ZnCl_2 + H_2\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2\)

Theo PTHH : \(n_{Zn} = n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\)

\(\Rightarrow n_{Fe_2O_3} = \dfrac{35,5-0,3.65}{160} = 0,1\\ \Rightarrow n_{HCl} = 2n_{Zn} + 6n_{Fe_2O_3} = 0,3.2 + 0,1.6 = 1,2(mol)\\ \Rightarrow m_{HCl} = 1,2.36,5 = 43,8(gam)\)

b)

\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\)

Gọi \(n_{CuO} = a;n_{Fe_2O_3} = b\)

\(\left\{{}\begin{matrix}80a+160b=19,6\\a+3b=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,135\\b=0,055\end{matrix}\right.\)

Vậy : 

\(\left\{{}\begin{matrix}n_{Cu}=0,135\\n_{Fe}=0,055.2=0,11\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,135.64=8,64\left(gam\right)\\m_{Fe}=0,11.56=6,16\left(gam\right)\end{matrix}\right.\)

Đặt CTHH oxit sắt: \(Fe_xO_y\)

\(Fe_xO_y+yCO\rightarrow\left(t^o\right)xFe+yCO_2\)

hh khí A gồm: khí CO₂ và có thể có CO (dư)

\(d_{\dfrac{A}{H_2}}=22\) \(\Rightarrow M_A=22.2=44\) \((g/mol)\)

\(\Leftrightarrow\dfrac{44n_{CO_2}+28n_{CO\left(dư\right)}}{n_{CO_2}+n_{CO\left(dư\right)}}=44\)

\(\Leftrightarrow16n_{CO\left(dư\right)}=0\)

\(\Leftrightarrow n_{CO\left(dư\right)}=0\left(mol\right)\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\)

                       0,15         0,15                ( mol )

\(n_{CaCO_3}=\dfrac{15}{100}=0,15\left(mol\right)\)

Bảo toàn O: \(n_{O\left(Fe_xO_y\right)}=n_{CO_2}=0,15\left(mol\right)\)

\(\Rightarrow n_{Fe\left(Fe_xO_y\right)}=\dfrac{8-0,15.16}{56}=0,1\left(mol\right)\)

\(\dfrac{x}{y}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\) \(\Rightarrow\) CTHH: \(Fe_2O_3\)

\(V_{CO}=V_{CO_2}=0,15.22,4=3,36\left(l\right)\)

1)Khí sau phản ứng gồm : 

CO : a(mol)

CO₂:b(mol)

Bảo toàn nguyên tố với C: a + b = \(\dfrac{6,72}{22,4} = 0,3(mol)\)(1)

\(M_{khí} = 20.2 = 40(đvC)\)

Ta có : 28a + 44b = (a + b).40(2)

Từ (1)(2) suy ra : a = 0,075; b = 0,225

\(CO + O_{oxit} \to CO_2\\ n_{O(oxit)} = n_{CO_2} = 0,225(mol)\\ m_{Fe} + m_O = m_{oxit}\\ \Rightarrow n_{Fe} = \dfrac{13,05-0,225.16}{56}=0,16875(mol)\)

Ta thấy : \(\dfrac{n_{Fe}}{n_O} = \dfrac{0,16875}{0,225} = \dfrac{3}{4}\)

Vậy oxit cần tìm : Fe₃O₄

2) \(\%V_{CO_2} = \dfrac{0,225}{0,225+0,075}.100\% = 75\%\)