Bài 19. Sắt

nCO2 =nCa(OH)2=6/100=0,06 mol=nCO pứ
nFe2O3=16/160=0,1 mol
=>nFe=0,2 mol
bảo toàn Fe nFe hh sau pứ=0,2 mol
bảo toàn klg=> m cr sau pứ=16+0,06.28-0,06.44=15,04 gam
GS hh cr sau pứ gồm Fe và O
=>mO=15,04-0,2.56=3,84 gam
=>nO=0,24 mol
khi cho hh cr tác dụng với H2SO4 đặc nóng
O          +2e     => O−2
0,24 mol=>0,48 mol
S+6 +2e     => S+4
          0,12 mol=>0,06 mol
Fe             => Fe+3 +3e
0,2 mol                      =>0,6 mol
VSO2=0,06.22,4=1,344 lit

c giải cho e r mà?

nCO2=nCa(OH)2=6/100=0,06 mol=nCO

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O" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OO" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OH2SO4" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">H2SO4O" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OO−2" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">O−2
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Vì còn Cu nên chứng tỏ Fe+3 đã bị chuyển hết thành Fe+2 rồi. 
gọi x là số mol Cu+2 và 2x là số mol Fe+2 
Ta dùng phương pháp tăng giảm KL 
64x + 56.2x - 24.3x = m tăng 
m tăng = 4 + 0,05.24 ( một phần bị axit hòa tan ) suy ra x = 0,05 
Vậy khối lượng Cu ban đầu là
1 + 0,05 .64 = 4,2 g 
Số Mol axit bằng 
3x.2 + 2.nH2 = 0,4 mol 

Gọi công thức oxit sắt là Fe_xO_y

Do Fe chiếm 7 phần trong Oxit , Oxi chiếm 2 phần , Suy ra :

  => (56x/7)*2 = 16x = 16y

<=> x=y => x = y chỉ có thể bằng 1 

Được rồi nhé bạn !!

D chứa hơn 70% là Fe3O4

Manhetit chứa 69,6% Fe₃O₄   

69,6% Fe3O4

nSO2=0,1mol

nFe2(SO4)3=,3mol

PTHH:

2FexOy + (6x-2y)H2SO4 ---> xFe2(SO4)3 + (3x-2y)SO2 + (6x-2y)H2O

   ta có phương trình từ PTHH trên là :

\(\frac{0,2x}{3x-2y}=0,3\)

<==> 0,2x=0,9x-0,6y

<=> 0,6y=0,7x

=> x:y=7:6=> VTHH của oxit sắt là Fe7O6

gọi công thức hoá học của oxit sắt cần tìm là Fe₂O_x

Theo đề bài ta có PTHH:

Fe₂O_x + 2xHCl -> 2FeCl_x + xH₂O

Theo phương trình hoá học ta có

2n_Fe2Ox=n_FeClx

=> 2 X \(\frac{7,2}{56\cdot2+16\cdot x}\) = \(\frac{12,7}{56+35,5\cdot x}\)

=>14,4(56+35,5.x) = 12,7(112 + 16x)

(=) 806,4 + 511,2x = 1422,4 + 203,2x

=>308x = 616

=> x =2

=> CTHH là Fe₂O₂ hay FeO

Gọi CTHH của oxit sắt là Fe_xO_y

Ta có : 56x+16y = 160

Vì mFe chiếm 70% nên : \(\frac{56x}{56x+16y}=\frac{70}{100}\Leftrightarrow5600x=3920x+1120y\Leftrightarrow1680x=1120y\)

\(\Rightarrow\frac{x}{y}=\frac{2}{3}\)

=> x = 2, y = 3

Vậy CTHH của Oxit sắt là Fe₂O₃

Fe2O3