\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

\(nH_2=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Bảo toàn nguyên tử H:

\(nH_2SO_4=nH_2=0,1\)

\(\Rightarrow mddH_2SO_4=\dfrac{0,1.98.100}{10}=98\left(g\right)\)

\(mdd_{saupứ}=m_{kimloại}+mddH_2SO_4-mH_2=3,68+98-0,1.2=101,48\left(g\right)\)

 do đó n_H2SO4 = n_{H2 =} 0,1 mol

m_{dd_H2SO4} = 0,1.98÷10% = 98 gam

OK bảo toàn kL:

m_{dd sau PƯ}= m_{dd_H2SO4} + m_{hh_KL} - m_H2 = 98+3,68-0,1×2= 101,48

Al, Fe không tác dụng với H₂SO₄ đặc nguội

Rắn không tan ở TN2 là Cu

m_Cu = 6,4 (g)

=> \(n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

           0,1-------------------------->0,1

=> V = 0,1.22,4 = 2,24 (l)

Bài 1 : 

\(a) Fe_2O_3 + 3H_2 \xrightarrow{t^o}2Fe + 3H_2O\\ b) n_{Fe_2O_3} = \dfrac{80}{160}= 0,5(mol)\\ n_{H_2} = 3n_{Fe_2O_3} = 1,5(mol)\\ \Rightarrow V_{H_2} = 1,5.22,4 = 33,6(lít)\\ n_{Fe} = 2n_{Fe_2O_3} = 1(mol)\\ m_{Fe} = 1.56 = 56(gam)\)

Bài 2 :

\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = n_{Fe} =\dfrac{5,6}{56} = 0,1(mol)\\ V_{H_2} = 0,1.22,4 = 2,24(lít)\\ n_{HCl} =2 n_{Fe} = 0,2(mol)\\ m_{HCl} = 0,2.36,5 = 7,3(gam)\)

\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)

\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)

\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)

a) 2Al + 6HCl --> 2AlCl₃ + 3H₂

Fe + 2HCl --> FeCl₂ + H₂

b) Gọi số mol Al, Fe lần lượt là a,b 

=> 27a + 56b = 13,9

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)

2Al + 6HCl --> 2AlCl₃ + 3H₂

a----->3a--------->a------->1,5a______(mol)

Fe + 2HCl --> FeCl₂ + H₂

b------>2b-------->b----->b__________(mol)

=> 1,5a + b = 0,35

=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)

c) n_HCl = 3a + 2b = 0,7 (mol)

=> m_HCl = 0,7.36,5 = 25,55(g)

=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)

\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)

\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)

a) Sửa đề: dd H₂SO₄ 9,8%

Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)

Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)

\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)

b) Tương tự câu a

Fe+H2SO4->FeSO4+H2

0,15-----------------------0,15 mol

n H2=0,15 mol

=>m Fe=0,15.56=8,4g

=>m Cu=11,8-8,4=3,4g

a)

$Mg + H_2SO_4 \to MgSO_4 + H-2$

b) $n_{H_2SO_4} = n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)$
$C\%_{H_2SO_4} = \dfrac{0,2.98}{200}.100\% = 9,8\%$

$n_{H_2} = n_{Mg} = 0,2(mol)$

$\Rightarrow m_{dd\ A} = 4,8 + 200 - 0,2.2 = 204,4(gam)$
$C\%_{MgSO_4} = \dfrac{0,2.120}{204,4}.100\% = 11,7\%$

c) $V_{H_2} = 0,2.22,4 = 4,48(lít)$

\(n_{H_2}=\dfrac{3,36}{22,4}0,15(mol)\\ a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{Fe}=n_{H_2}=0,15(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,15.56}{14,8}.100\%=56,76\%\\ \Rightarrow \%_{Cu}=100\%-56,76\%=43,24\%\\ c,n_{H_2SO_4}=0,15(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,15.98}{20\%}=73,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{73,5}{1,4}=52,5(l)\)