giup mk voi

\(a)2NaOH+CuCl_2\rightarrow Cu\left(OH\right)_2+2NaCl\\ b)n_{NaOH}=\dfrac{4}{40}=0,1mol\\ n_{CuCl_2}=n_{Cu\left(OH\right)_2}=0,1:2=0,05mol\\ m_{ddCuCl_2}=\dfrac{0,05.135}{10}\cdot100=67,5g\\ c)n_{NaCl}=n_{NaOH}=0,1mol\\ C_{\%NaCl}=\dfrac{0,1.58,5}{\dfrac{4}{10}\cdot100+67,5-0,05.98}\cdot100=14,0625\%\)

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

\(n_{CuO}=\dfrac{8}{80}=0.1\left(mol\right)\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(0.1...........0.1.........0.1\)

\(n_{NaOH}=0.24\cdot0.5=0.12\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

\(0.12..........0.06\)

\(n_{H_2SO_4}=0.1+0.06=0.16\left(mol\right)\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.16}{1}=0.16\left(l\right)\)

\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.06}{0.16}=0.375\left(M\right)\)

\(C_{M_{CuSO_4}}=\dfrac{0.1}{0.16}=0.625\left(M\right)\)

PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

a, Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

⇒ 24x + 27y = 12,6 (1)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y\left(mol\right)\)

\(\Rightarrow x+\dfrac{3}{2}y=0,6\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{MG}=\dfrac{0,3.24}{12,6}.100\%\approx57,1\%\\\%m_{Al}\approx42,9\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{H_2SO_4}=0,6.98=58,8\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{58,8}{14,7\%}=400\left(g\right)\)

Ta có: m _{dd sau pư} = 12,6 + 400 - 0,6.2 = 411,4 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{0,3.120}{411,4}.100\%\approx8,75\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{411,4}.100\%\approx8,31\%\end{matrix}\right.\)

Bạn tham khảo nhé!

a)\(n_{MgO}\)=6:40=0,15(mol)

Ta có PTHH:

MgO+\(H_2SO_4\)->MgS\(O_4\)+\(H_2O\)

0,15......0,15...........0,15..................(mol)

Theo PTHH:\(m_{H_2SO_4}\)=0,15.98=14,7g

b)Ta có:\(m_{ddH_2SO_4}\)=D.V=1,2.50=60(g)

=>Nồng độ % dd \(H_2SO_4\) là:

\(C_{\%ddH_2SO_4}\)=\(\dfrac{14,7}{60}\).100%=24,5%

c)Theo PTHH:\(m_{MgSO_4}\)=0,15.120=18(g)

Khối lượng dd sau pư là:

\(m_{ddsau}\)=\(m_{MgO}\)+\(m_{ddH_2SO_4}\)=6+60=66(g)

Vậy nồng độ % dd sau pư là:

\(C_{\%ddsau}\)=\(\dfrac{18}{66}\).100%=27,27%

\(n_{CuO}=\dfrac{1,6}{80}=0,02\left(mol\right)\)

Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)

          1           1                1            1

       0,02                         0,02

\(n_{CuSO4}=\dfrac{0,02.1}{1}=0,02\left(mol\right)\)

⇒ \(m_{CuSO4}=0,02,160=3,2\left(g\right)\)

\(m_{ddspu}=1,6+300=301,6\left(g\right)\)

\(C_{CuSO4}=\dfrac{3,2.100}{301,6}=1,6\)⁰/₀

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