\(n_{Ba\left(OH\right)_2}=0,5.0,2=0,1\left(mol\right);n_{H_2SO_4}=0,3.0,4=0,12\left(mol\right)\)

PTHH: Ba(OH)₂ + H₂SO₄ → BaSO₄↓ + 2H₂O

Mol:        0,1             0,1           0,1

Ta có: \(\dfrac{0,1}{1}< \dfrac{0,12}{1}\) ⇒ Ba(OH)₂ hết, H₂SO₄ dư

\(C_{M_{H_2SO_4dư}}=\dfrac{0,12-0,1}{0,2+0,3}=0,04M\)

m_{dd sau pứ} = 200.2,3+300.1,6-0,1.233 = 916,7 (g)

\(C\%_{H_2SO_4dư}=\dfrac{0,02.98.100\%}{916,7}=0,21\%\)

n_HCl = 0.4 (mol) 

n_Ba(OH)2 = 0.15 (mol) 

Ba(OH)₂ + 2HCl => BaCl₂ + H₂O

0.15_______0.3_____0.15 

C_{M HCl(dư)} = 0.3/0.4 = 0.75M

C_{M BaCl2} = 0.15/(0.4 + 0.3) = 3/14 (M) 

\(a,n_{Na_2SO_4}=0,2\cdot0,2=0,04\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\cdot0,1=0,02\left(mol\right)\\ PTHH:Na_2SO_4+Ba\left(OH\right)_2\rightarrow2NaOH+BaSO_4\downarrow\\ TL:....1.....1......2......1\left(mol\right)\\ BR:.......0,02.....0,02......0,04......0,02\left(mol\right)\)

Vì \(\dfrac{n_{Na_2SO_4}}{1}>\dfrac{n_{Ba\left(OH\right)_2}}{1}\) nên \(Na_2SO_4\) dư, \(Ba\left(OH\right)_2\) hết

\(b,C_{M_{NaOH}}=\dfrac{0,04}{0,2+0,2}=0,1M\)

\(n_{H_2SO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(m_{dd_{H_2SO_4}}=100\cdot1.2=120\left(g\right)\)

\(n_{BaCl_2}=0.1\cdot1=0.1\left(mol\right)\)

\(m_{dd_{BaCl_2}}=100\cdot1.32=132\left(g\right)\)

\(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)

\(0.1................0.1.........0.1...............0.2\)

\(\Rightarrow H_2SO_4dư\)

\(m_{BaSO_4}=0.1\cdot233=23.3\left(g\right)\)

\(V_{dd}=0.1+0.1=0.2\left(l\right)\)

\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.2-0.1}{0.2}=0.5\left(M\right)\)

\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)

\(m_{\text{dung dịch sau phản ứng}}=120+132-23.3=228.7\left(g\right)\)

\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{0.1\cdot98}{228.7}\cdot100\%=4.28\%\)

\(C\%_{HCl}=\dfrac{0.2\cdot36.5}{228.7}\cdot100\%=3.2\%\)

Giúp mình với 

\(a.n_{CuSO_4}=\dfrac{7,5}{250}=0,03\left(mol\right)\\ C_{MddCuSO_4}=\dfrac{0,03}{0,2}=0,15\left(M\right)\\ b.C_{MddBa\left(OH\right)_2}=\dfrac{C\%_{ddBa\left(OH\right)_2}.10.D_{ddBa\left(OH\right)_2}}{M_{Ba\left(OH\right)_2}}\\ =\dfrac{20,684.10.1,25}{171}\approx1,512\left(M\right)\)

nCO₂ =\(\dfrac{4,48}{22,4}\)=0,2 mol 

PTHH CO₂  + Ba(OH)₂ --> BaCO₃  + H₂O

CO₂ phản ứng vừa đủ với Ba(OH)₂ => nBa(OH)₂ = 0,2 mol

=> mBa(OH)₂ = 0,2.171 = 34,2 gam

khối lượng 200ml dung dịch Ba(OH)₂ có d = 1,12g/ml = 200.1,12 = 224 gam

C%_Ba(OH)2 = \(\dfrac{m_{\left(ct\right)}}{m_{\left(dd\right)}}.100\)= \(\dfrac{34,2}{224}.100\)= 15,27%

200ml = 0,2l

\(n_{CuSO4}=1.0,2=0,2\left(mol\right)\)

a) Pt : \(CuSO_4+2KOH\rightarrow Cu\left(OH\right)_2+K_2SO_4|\)

               1               2                1                  1

              0,2          0,4               0,2                0,2

b) \(n_{KOH}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\) 

200ml = 0,2l

\(C_{M_{ddKOH}}=\dfrac{0,4}{0,2}=2\left(M\right)\)

c) \(n_{Cu\left(OH\right)2}=\dfrac{0,4.1}{2}=0,2\left(mol\right)\)

⇒ \(m_{Cu\left(OH\right)2}=0,2.98=19,6\left(g\right)\)

d) \(n_{K2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{ddspu}=0,2+0,2=0,4\left(l\right)\)

\(C_{M_{K2SO4}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)

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