a, \(n_{H^+}=0,025.0,2=0,005\left(mol\right)\)

\(n_{OH^-}=0,01.2.0,3=0,006\left(mol\right)\)

\(\Rightarrow n_{OH^-dư}=0,001\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]_{dư}=\dfrac{0,001}{1}=10^{-3}\)

\(\Rightarrow\left[H^+\right]=10^{-11}\)

\(\Rightarrow pH=11\)

b, \(n_{Fe^{2+}}=n_{SO_4^{2-}}=0,02.0,1=0,002\left(mol\right)\)

\(n_{Ba^{2+}}=0,01.0,3=0,003\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{BaSO_4\downarrow}=n_{SO_4^{2-}}=0,002\left(mol\right)\\n_{Fe\left(OH\right)_2\downarrow}=n_{OH^-dư}=0,001\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{\downarrow}=0,002.233+0,001.90=0,556\left(g\right)\)

\(pH=10\)

\(\Rightarrow\left[H^+\right]=10^{-10}\)

\(\Rightarrow\left[OH^-\right]=10^{-4}\)

\(n_{OH^-}=10^{-4}.0,1=10^{-5}\left(mol\right)\)

\(n_{H^+}=0,1.2.0,01=0,003\left(mol\right)\)

\(\Rightarrow n_{H^+dư}=2,99.10^{-3}\left(mol\right)\)

\(\Rightarrow\left[H^+_{dư}\right]=\dfrac{2,99.10^{-3}}{0,2}=0,01495M\)

\(\Rightarrow pH\approx1,83\)

a, \(\left[Na^+\right]=0,1\)

\(\left[K^+\right]=0,1\)

\(\left[OH^-\right]=0,2\)

\(\left[SO_4^{2-}\right]=0,2\)

\(\left[H^+\right]=0,4\)

b, \(n_{H^+}=0,1.0,4=0,04\left(mol\right)\)

\(n_{OH^-}=0,1.0,2=0,02\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+dư}=0,02\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,02}{200}=10^{-4}\)

\(\Rightarrow pH=4\)

$n_{NaOH} = n_{KOH} = 0,1.0,1 = 0,01(mol)$
$n_{H_2SO_4} = 0,02(mol)$

              OH^- + H⁺ → H₂O

       Bđ : 0,01...0,04..................(mol)

      Pư : 0,01...0,01...................(mol)

Sau pư :   0......0,03...................(mol)

$V_{dd} = 0,1 + 0,1 = 0,2(lít)$

Vậy : 

 $[K^+] = [Na^+] = \dfrac{0,01}{0,2} = 0,05M$
$[H^+] = \dfrac{0,03}{0,2} = 0,15M$
$[SO_4^{2-}] = \dfrac{0,02}{0,2} = 0,1M$

b)

$pH = -log(0,15) = 0,824$

Ta có: \(n_{HCl}=0,1.0,02=0,002\left(mol\right)\Rightarrow n_{H^+}=0,002\left(mol\right)\)

\(n_{NaOH}=0,1.0,04=0,004\left(mol\right)\Rightarrow n_{OH^-}=0,004\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,002→0,002 _______ (mol)

⇒ OH^- dư.

\(\Rightarrow n_{OH^-\left(dư\right)}=0,002\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]=\frac{0,002}{0,2}=0,01M\)

\(\Rightarrow\left[H^+\right]=\frac{10^{-14}}{0,01}=10^{-12}\)

\(\Rightarrow pH=12\)

Bạn tham khảo nhé!

a) \(n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,1\cdot0,12+0,1\cdot0,04=0,016\)

    \(C_M=\dfrac{0,016}{0,2}=0,08M\)

     \(\Rightarrow pH=-log\left(0,08\right)=1,1\)

b) \(n_{OH^-}=n_{KOH}+2n_{Ba\left(OH\right)_2}=0,012+2\cdot0,004=0,02\)

     \(C_M=\dfrac{0,02}{0,2}=0,1\)

     \(\Rightarrow pH=-log\left(\dfrac{10^{-14}}{0,1}\right)=13\)