Gọi CT oxit sắt là FexOy

Gọi nCu=a(mol)

nH2=\(\dfrac{6,72}{22,4}\)=0,3(mol)

FexOy+yH2to→xFe+yH2O(1)

Fe+2HCl→FeCl2+H2(2)

Theo pthh(2) 

nFe=nH2=0,3(mol)

Theo pthh(1)

nFexOy=\(\dfrac{0,3}{x}\)(mol)

Ta có: 64a+56.0,3=29,6

⇒a=0,2(mol)

⇒mCu=0,2.64=12,8(g)

⇒mFexOy=36−12,8=23,2(g)

=>MFexOy= \(\dfrac{\dfrac{23,2}{0,3}}{x}\)=\(\dfrac{232x}{3}\)

=>56x+16y=\(\dfrac{232x}{3}\)

=>\(\dfrac{64x}{3}=16y\)

->\(\dfrac{x}{y}=\dfrac{3}{4}\)

⇒CTHH:Fe3O4

Ta có :

%m Cu=\(\dfrac{12,8}{36}100\)=35,56%

=>%m Fe3O4=100%-35,56%=64,44%

Hỗn hợp oxit gì của Fe thế em

a) Gọi \(n_{Cu}=a\left(mol\right)\rightarrow n_{Fe}=\dfrac{3}{2}a=1,5a\left(mol\right)\)

PTHH: 

\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)

a<------a<------a

\(Fe_3O_4+4H_2\xrightarrow[]{t^o}3Fe+4H_2O\)

0,5a<-----2a<------1,5a

\(\rightarrow80a+0,5a.232=39,2\\ \Leftrightarrow a=0,2\left(mol\right)\)

\(\rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2.80=16\left(g\right)\\m_{Fe_3O_4}=0,5.0,2.232=23,2\left(g\right)\end{matrix}\right.\)

b) \(V_{H_2}=\left(0,2.2+0,2\right).22,4=13,44\left(l\right)\)

\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=0,5a\left(mol\right)\\ m_{hhB}=17,6\\ \Leftrightarrow56a+64.0,5a=17,6\\ \Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow n_{Fe}=0,2\left(mol\right);n_{Cu}=0,1\left(mol\right)\\ a,n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,2+0,1=0,4\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ b,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ \Rightarrow ddC:FeCl_2,HCldư\\ n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\)

\(\Rightarrow m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)

\(\left[O\right]_{KL}+H_2->H_2O\\ n_{H_2O}=n_{H_2}=\dfrac{14,4}{18}=0,8mol\\ v=0,8.22,4=17,92L\\ m_{KL}=m=47,2-16.0,8=34,4g\)

Đáp án C

tk

n H2O= =0,8 mol

⇒n H2=0,8 mol

   n O=0,8 mol

⇒V H2(đktc)=0,8.22,4=17,92 l

theo đlbt khối lượng:

  mkl+mO=m oxit

⇔mkl+0,8.16=47,2

⇔mkl=34,4 g

\(n_{H_2O}=n_{H_2}=n_{O\left(mất\right)}=\dfrac{14,4}{18}=0,8\left(mol\right)\\ \Rightarrow m=m_{kim.loại}=m_{hhoxit}-m_{O\left(mất\right)}=47,2-0,8.16=34,4\left(g\right)\\ V=V_{H_2\left(đktc\right)}=0,8.22,4=17,92\left(l\right)\)