CH3CHO + 2AgNO3 + 3NH3 + H2O → CH3COONH4 + 2Ag↓ + 2NH4NO3    (1)

CH3COOH + NaOH → CH3COONa + H2O    (2)

Theo (1):

Đáp án A

n_OH-= n_H+ nên 0,02.a+ 0,02.b = 0,3.0,1

n_Cl-= n_AgCl = 0,02 mol = 0,02a suy ra a = 1M suy ra b = 0,5

Ta có: \(n_{Ca\left(OH\right)_2}=0,2.1=0,2\left(mol\right)\)

PT: \(Ca\left(OH\right)_2+Na_2CO_3\rightarrow CaCO_{3\downarrow}+2NaOH\)

_______0,2_______0,2________0,2 (mol)

\(\Rightarrow C_{M_{Na_2CO_3}}=\dfrac{0,2}{0,25}=0,8\left(M\right)\)

\(m_{CaCO_3}=0,2.100=20\left(g\right)\)

\(n_{AgNO_3}=0,2.2=0,4\left(mol\right)\)

\(AgNO_3+KCl\rightarrow AgCl+KNO_3\)

0,4                          0,4 

\(m_{kt}=0,4.143,5=57,4\left(g\right)\)

1)

- TN1:

\(n_{AgCl}=\dfrac{35,875}{143,5}=0,25\left(mol\right)\)

PTHH: AgNO₃ + HCl --> AgCl + HNO₃

                          0,25<--0,25

TN2:

n_NaOH = 0,5.0,3 = 0,15 (mol)

PTHH: NaOH + HCl --> NaCl + H₂O

             0,15--->0,15

\(n_{HCl\left(dd.C\right)}=0,25+0,15\) = 0,4 (mol)

=> \(C_{M\left(dd.C\right)}=\dfrac{0,4}{2}=0,2M\)

2)

Có \(\left\{{}\begin{matrix}C_{M\left(A\right)}=\dfrac{0,25}{V}M\\C_{M\left(B\right)}=\dfrac{0,15}{V^,}M\end{matrix}\right.\)

n_HCl(A) = \(\dfrac{0,025}{V}\left(mol\right)\) 

PTHH: Fe + 2HCl --> FeCl₂ + H₂

                     \(\dfrac{0,025}{V}\)------>\(\dfrac{0,0125}{V}\)

n_HCl(B) = \(\dfrac{0,015}{V^,}\) (mol)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

                    \(\dfrac{0,015}{V^,}\)-------->\(\dfrac{0,0075}{V^,}\)

TH1: \(\dfrac{0,0125}{V}=\dfrac{0,0075}{V^,}+0,02\) 

Mà V + V^' = 2 (l)

=> \(\left[{}\begin{matrix}V=1,5;V^,=0,5\left(KTM\right)\\V=0,5;V^,=1,5\left(TM\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C_{M\left(A\right)}=\dfrac{0,25}{0,5}=0,5M\\C_{M\left(B\right)}=\dfrac{0,15}{1,5}=0,1M\end{matrix}\right.\)

TH2: \(\dfrac{0,0125}{V}+0,02=\dfrac{0,0075}{V^,}\)

=> \(\left[{}\begin{matrix}V=\dfrac{1+\sqrt{6}}{2};V^,=\dfrac{3-\sqrt{6}}{2}\\V=\dfrac{1-\sqrt{6}}{2}\left(L\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C_{M\left(A\right)}=\dfrac{0,25}{\dfrac{1+\sqrt{6}}{2}}=\dfrac{-1+\sqrt{6}}{10}M\\C_{M\left(B\right)}=\dfrac{0,15}{\dfrac{3-\sqrt{6}}{2}}=\dfrac{3+\sqrt{6}}{10}M\end{matrix}\right.\)

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CH3CHO + 2AgNO3 + 3NH3 + H2O → CH3COONH4 + 2Ag↓ + 2NH4NO3

Từ phương trình ta có:

a) \(CaCl_2+2AgNO_3\rightarrow Ca\left(NO_3\right)_2+2AgCl\)

b) \(n_{CaCl_2}=0,2.1=0,2\left(mol\right)\)

=> \(n_{AgCl}=2n_{CaCl2}=0,4\left(mol\right)\)

=> \(m_{AgCl}=0,4.143,5=57,4\left(g\right)\)

c) \(n_{AgNO_3}=2n_{CaCl2}=0,4\left(mol\right)\)

=> \(CM_{AgNO_3}=\dfrac{0,4}{0,4}=1M\)