\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)

Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)

\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)

Rainbow

\(n_{FeCl_3}=0.2\cdot0.4=0.08\left(mol\right)\)

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

\(0.08...........0.24..............0.08\)

\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)

\(0.08...........0.04\)

\(m_{Fe_2O_3}=0.04\cdot160=6.4\left(g\right)\)

\(V_{dd_{NaOH}}=\dfrac{0.24}{0.5}=0.48\left(l\right)\)

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\) (1)

\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\) (2)

\(n_{FeCl_3}=0,2.0,4=0,08\left(mol\right)\)

Bảo toàn nguyên tố Fe : \(n_{FeCl_3}=2n_{Fe_2O_3}=0,08\left(mol\right)\)

=> \(n_{Fe_2O_3}=0,04\left(mol\right)\)

=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)

Theo PT (1) : \(n_{NaOH}=3n_{FeCl_3}=0,08.3=0,24\left(mol\right)\)

=> \(V_{NaOH}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)

\(n_{FeCl_3}=C_M.V=0,4.0,2=0,08\left(mol\right)\)

PT: FeCl₃ + 3NaOH \(\rightarrow\) 3NaCl + Fe(OH)₃ \(\downarrow\)

       0,08 -> 0,24                     ->  0,08          (mol)

      2Fe(OH)₃ \(\underrightarrow{t^o}\) Fe₂O₃ + 3H₂O

        0,08       ->    0,04                                  (mol)

m_cr=m_Fe2O3=n.M=0,04.160=6,4(g)

\(V_{NaOH}=\dfrac{n}{C_M}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)

a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)

                 \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)

b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)

\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)

c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\) 

(Coi như thể tích dd thay đổi không đáng kể)

d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\) 

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)

a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)

c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)

\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

PTHH:

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

0,8         2,4                 0,8             2,4

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

0,8                 0,4         1,2

\(C_{M\left(NaCl\right)}=\dfrac{2,4}{0,6}=4\left(M\right)\)

\(m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)

PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

              0,8----------------------->0,8----------->2,4

b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)

c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)

0,8--------------->0,4

\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)

Đáp án B

Fe³⁺+ 3OH^- → Fe(OH)₃

0,1 mol           0,1 mol

Al³⁺+ 3OH^- → Al(OH)₃

Zn²⁺+ 2OH^- → Zn(OH)₂

Do Al(OH)₃ và Zn(OH)₂ là hidroxit lưỡng tính nên bị tan trong NaOH dư

Kết tủa thu được có Fe(OH)₃

2Fe(OH)₃  → Fe₂O₃+ 3H₂O

0,1               0,05 mol

m_Fe2O3 = 0,05.160 = 8 gam

a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)

c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)