1) nZn=13/65=0,2(mol)

PTHH: Zn +  2 HCl -> ZnCl2 + H2

nH2=nZnCl2=nZn=0,2(mol)

nHCl=2.0,2=0,4(mol)

=> mHCl=0,4 x 36,5=14,6(g)

=> mddHCl=(14,6.100)/8=182,5(g)

2) V(H2,đktc)=0,2 x 22,4= 4,48(l)

mZnCl2=0,2.136=27,2(g)

3) mddsau=mZn+mddHCl - mH2= 13+182,5-0,2.2=195,1(g)

4) C%ddZnCl2=(27,2/195,1).100=13,941%

a)\(m_{ddHCl}=\dfrac{4,8}{10\%}.100\%=48\left(g\right)\)

b)\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)

\(PTHH:Mg+2HCl\xrightarrow[]{}MgCl_2+H_2\)

\(n_{MgCl_2}=n_{Mg}=n_{H_2}=0,2\)

\(m_{MgCl_2}=0,2.95=19\left(g\right)\)

\(V_{H_2}=0,2.22,4=4.48\left(l\right)\)

c)\(m_{H_2}=0,2.2=0,4\left(g\right)\)

\(m_{ddMgCl_2}=4,8+48-0,4=52,4\left(g\right)\)

\(C\%_{MgCl_2}=\dfrac{19}{52,4}.100\%=36\%\)

\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ n_{Zn} = \dfrac{13}{65} = 0,2 < n_{H_2SO_4} = \dfrac{200.24,5\%}{98} = 0,5 \to H_2SO_4\ dư\\ n_{H_2SO_4\ pư} =n_{Zn} = 0,2(mol)\\ \Rightarrow m_{H_2SO_4\ dư} = (0,5 - 0,2).98 = 29,4(gam)\\ c) n_{FeSO_4} = n_{H_2} = n_{Zn} = 0,2(mol)\\ m_{FeSO_4} = 0,2.152 = 30,4(gam)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\)

n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)

n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)

       \(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)

bđ    0,1............0,5

pư    0,1............0,3..................0,1

spu   0 ................0,2................0,1 

=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O

m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)

m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)

m dd = \(490+10,2=500,2g\)

% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)

% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)

`a)PTHH:`

`Fe + 2HCl -> FeCl_2 + H_2`

`0,3`    `0,6`          `0,3`     `0,3`       `(mol)`

`n_[Fe]=[22,4]/56=0,4(mol)`

`n_[HCl]=0,3.2=0,6(mol)`

Ta có:`[0,4]/1 > [0,6]/2`

   `=>Fe` dư

`b)m_[FeCl_2]=0,3.127=38,1(g)`

`c)m_[Fe(dư)]=(0,4-0,3).56=5,6(g)`

\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ n_{HCl}=0,3.2=0,6\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\\ LTL:\dfrac{0,4}{1}>\dfrac{0,6}{2}\) 
=> Fe dư 
\(n_{FeCl_2}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\\ m_{FeCl_2}=0,3.127=38,1\left(g\right)\\ n_{Fe\left(p\text{ư}\right)}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\\ m_{Fe\left(d\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)

\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)

\(n_{HCl}=0,3.2=0,6\left(mol\right)\)

       \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Xét: \(\dfrac{0,4}{1}>\dfrac{0,6}{2}\)                            ( mol )

         0,3      0,6          0,3               ( mol )

\(m_{FeCl_2}=0,3.127=38,1\left(g\right)\)

\(m_{Fe\left(dư\right)}=\left(0,4-0,3\right).56=5,6\left(g\right)\)

a)

$Mg + 2HCl \to MgCl_2 + H_2$

Theo PTHH : 

$n_{MgCl_2} = n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol)$
$m_{MgCl_2} = 0,25.95 = 23,75(gam)$

b)

$n_{HCl} = 2n_{H_2} = 0,5(mol)$
$m_{dd\ HCl} = \dfrac{0,5.36,5}{7,3\%} = 250(gam)$

c)

$2K + 2H_2O \to 2KOH + H_2$
$n_K = 2n_{H_2} = 0,5(mol)$
$m_K = 0,5.39 = 19,5(gam)$

Bài 1 :

PTHH : Zn + H₂SO₄ ------> ZnSO₄ + H₂

\(n_{Zn}=\frac{m}{M}=\frac{26}{65}=0,4\left(mol\right)\)

Theo PTHH : n_H2 = n_Zn = 0,4 mol

=> Khối lượng H₂ được tạo ra ở đktc là :

\(V=n\times22,4\)

\(\Rightarrow V_{H_2}=0,4\times22,4\)

\(\Rightarrow V_{H_2}=8,96\left(l\right)\)

Theo PTHH : n_ZnSO4 = n_Zn = 0,4 mol

=> Khối lượng muối được tạo thành là :

\(m=n\times M\)

\(\Rightarrow m_{ZnSO_4}=0,4\times161\)

\(\Rightarrow m_{ZnSO_4}=64,4\left(g\right)\)

b) Theo PT : \(n_{H_2SO_4}=n_{Zn}=0,4\left(mol\right)\)

=> Khối lượng \(H_2SO_4\)cần dùng cho phản ứng là :

\(m=n\times M\)

\(\Rightarrow m_{H_2SO_4}=0,4\times98\)

\(\Rightarrow m_{H_2SO_4}=39,2\left(g\right)\)

c) Nồng độ phần trăm thu được sau phản ứng là :

\(C\%=\frac{m_{ct}}{m_{dd}}\times100\%\)

\(\Rightarrow C\%=\frac{39,2}{64,4}\times100\%\approx60,9\%\)

Vậy :.........................