a) Đề bài sai phải không? (CO₃  ----> CO₂ chứ)

CO₂ + H₂O -----> H₂CO₃

C_M= 0,36 (M)

b)  n_CuO=\(\frac{10}{80}\)  = 0,125 (mol)

n_H2CO3= \(\frac{2}{11}\) (mol)

                  CuO    +    H₂CO₃ ------>   CuCO₃   +    H₂O

ban đầu    0,125          \(\frac{2}{11}\)                                                         }

pư             0,125  --->  0,125    --->     0,125                           }    (mol)

sau pư          0                \(\frac{5}{88}\)                   0,125                          }

C_M(H2CO3)=\(\frac{\frac{5}{88}}{0,5}\)=0,11 (M)

C_M(CuCO3)=\(\frac{0,125}{0,5}\)=0,25 (M)

\(n_{SO_3}=\dfrac{8}{80}=0.1\left(mol\right)\)

\(SO_3+H_2O\rightarrow H_2SO_4\)

\(0.1......................0.1\)

\(C_{M_{H_2SO_4}}=\dfrac{0.1}{0.5}=0.2\left(M\right)\)

\(n_{CuO}=\dfrac{10}{80}=0.125\left(mol\right)\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(0.1...........0.1\)

\(m_{CuO\left(dư\right)}=\left(0.125-0.1\right)\cdot80=2\left(g\right)\)

nCuO=0,125 mol

nHCl=0,5 mol

CuO +     2HCl-->   CuCl2 + H2O

0,125       0,5           

0,125        0,25          0,125

0                0,25          0,125

C_CuCl2=0,125/0,5=0,25 M

C_{HCl du}=0,25/0,5=0,5 M    

nCuO=0,125mol

nH2SO4=0,5 mol

CuO +        2H2SO4-->     CuCl2 +   H2O

0,125          0,5

0,125          0,25                  0,125

C_CuCl2=0,125/0,5=0,25 M

C_{HCl du}=0,25/0,5=0,5 M

0                  0,25                  0,125

C_CuCl2= 0,125/

\(n_{SO_3}=\dfrac{20}{80}=0,25\left(mol\right)\\ PTHH:SO_3+H_2O\rightarrow H_2SO_4\\ Mol:0,25\rightarrow0,25\rightarrow0,25\\ C_{MH_2SO_4}=\dfrac{0,25}{0,5}=0,5M\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\\ Mol:0,25\leftarrow0,25\\ m_{Mg}=0,25.24=6\left(g\right)\)

\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)

\(K_2O+H_2O\rightarrow2KOH\)

\(0.25...................0.5\)

\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.5............0.25............0.25\)

\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)

\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)

\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)

nK2O = 23,5 : 94 = 0,25 (mol)
Vdd = 500ml = 0,5l

PT K2O + H2O ==> 2KOH
TPT 1 1 2 (mol)
TĐB: 0,25 --> 0,5 (mol)

a) C_{M KOH} = 0,5 : 0,5 = 1(M)

b) PT: H2SO4 + 2KOH ==> K2SO4 + 2H2O
TPT: 1 2 1 2 (mol)

a.

\(n_{K_2O}=\dfrac{m}{M}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ PT:\\ K_2O+H_2O\rightarrow2KOH\)

Theo pt: \(n_{KOH}=2n_{K_2O}=0,5\left(mol\right)\)

\(\Rightarrow C_{M\left(KOH\right)}=\dfrac{n}{V}=\dfrac{0,5}{0,5}=1\left(M\right)\)

b.

\(PT:\\ 2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)(2)

Theo pt, \(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{m_{dd}}{D}=\dfrac{n.M:C\%}{D}=\dfrac{0,25.98:20\%}{1,14}=\)107,46(ml)

c.

dd spư có chất tan là K₂SO₄

Theo pt (2), \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

=> C_M = \(\dfrac{n}{V}=\dfrac{0,25}{0,107}=2,336\left(M\right)\)

Bài 1

\(a,n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\ CuO+2HCl\xrightarrow[]{}CuCl_2+H_2O\\ n_{CuCl_2}=n_{CuO}=0,2mol\\ m_{CuCl_2}=0,2.135=27\left(g\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ C_{MHCl}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)

Bài 5

\(a,n_{NaOH}=0,2.1=0,2\left(mol\right)\\ 2NaOH+H_2SO_4\xrightarrow[]{}Na_2SO_4+2H_2O\\ n_{H_2SO_4}=0,2:2=0,1\left(mol\right)\\ C_{MH_2SO_4}=\dfrac{0,1}{0,4}=0,25\left(M\right)\\ b,n_{Na_2SO_4}=0,2:2=0,1\left(mol\right)\\ C_{MNa_2SO_4}=\dfrac{0,1}{0,2+0,4}=\dfrac{1}{6}\left(M\right)\\ c,m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)

PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

            \(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\downarrow\)

a+b) Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

\(\Rightarrow n_{HCl}=0,2\left(mol\right)=n_{KOH}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2\cdot36,5}{300}\cdot100\%\approx2,43\%\\C_{M_{KOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)

c) PTHH: \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

Theo các PTHH: \(n_{CuO\left(lý.thuyết\right)}=n_{Cu\left(OH\right)_2}=n_{Cu}=0,1\left(mol\right)\)

\(\Rightarrow n_{CuO}=0,1\cdot95\%=0,095\left(mol\right)\) \(\Rightarrow m_{CuO}=0,095\cdot80=7,6\left(g\right)\)