a, \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)

c, Ta có: \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)

Theo PT: \(n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)

PT: \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)

Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,4\left(mol\right)\)

Mà: H = 80%

\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,4}{80\%}=0,5\left(mol\right)\)

\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,5.46=23\left(g\right)\)

\(\Rightarrow V_{C_2H_5OH}=\dfrac{23}{0,8}=28,75\left(ml\right)\)

\(\Rightarrow V_{C_2H_5OH\left(18,4^o\right)}=\dfrac{28,75}{18,4}.100=156,25\left(ml\right)=0,15625\left(l\right)\)

448ml = 0,448l

\(n_{CO2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

a) Pt : \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O|\)

                  1             2              2           1           1

                0,02                                    0,02

b) \(n_{Na2CO3}=\dfrac{0,02.1}{1}=0,02\left(mol\right)\)

\(m_{Na2CO3}=0,02.106=2,12\left(g\right)\)

\(m_{NaCl}=5-2,12=2,88\left(g\right)\)

c) ⁰/₀NaCl = \(\dfrac{2,88.100}{5}=57,6\)⁰/₀

     ⁰/₀Na₂CO₃ = \(\dfrac{2,12.100}{5}=42,4\)⁰/₀

 Chúc bạn học tốt

\(n_{Na_2CO_3}=x(mol);n_{NaHCO_3}=y(mol)\\ \Rightarrow 106x+84y=3,8(1)\\ n_{CO_2}=\dfrac{0,896}{22,4}=0,04(mol)\\ Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow\\ NaHCO_3+HCl\to NaCl+H_2O+CO_2\uparrow\\ \Rightarrow x+y=0,04(2)\\ (1)(2)\Rightarrow x=y=0,02(mol)\\ \Rightarrow \begin{cases} m_{Na_2CO_3}=106.0,02=2,12(g)\\ m_{NaHCO_3}=84.0,02=1,68(g) \end{cases}\)

không biết làm

Gọi mNa2CO3 là xnNa2CO3= x/106 mNaHCO3 là ynNaHCO3=y/84 Có x+y=3,8 PTHH: Na2CO3+2HCl2NaCl+H2O+CO2 x/106mol x/106mol PTHH:NaHCO3+HClNaCl+H2O+CO2 x/84mol x/84mol (x/84+x/106)x22,4=0,896 76x/159=0,896 x=1,8gam y=2gam

2Al + 6HCl -> 2AlCl₃ + 3H₂ (1)

ZnO + 2HCl -> ZnCl₂ + H₂O (2)

a) n_H2= 13,44/22.4=0.6(mol) -> mH2=0,6.2=1,2(g)

Theo PTHH: n_Al = 2/3 n_H2 = 2/3 . 0,6= 0,4(mol) -> m_Al = 0,4 . 27=10,8(g)

-> m_ZnO = 27-10,8= 16,2(g)

b) n_ZnO = 16,2/81=0,2(mol)

Theo PTHH (2): nHCl = 2nZnO=2.0,2=0,4(mol)

Theo PTHH (1) : nHCl=2nH₂=2.0,6=1,2(mol)

-> \(\Sigma\)nHCl = 0,4+1,2=1,6(mol)

-> mHCl = 1,6.36,5= 58,4(g)

-> mdd_HCl = 58,4.100/29,2= 200(g)

c) Theo PTHH (1): nAlCl₃ = 2/3 nH₂ = 2/3 . 0,6=0,4(mol)                                         -> mAlCl3=0,4.133,5=53,4(g)

mdd sau phản ứng= m_A + mddHCl - mH2 =27+200-1,2 =225,8(g)

-> C% AlCl3 = 53,4.100%/225,8 = 20,88%

Theo PTHH (2) nZnCl2 =nZnO= 0,2(mol)-> mZnCl2=0,2.136=27,2(g)

-> C% ZnCl2= 27,2.100%/255,8=10,63%

\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)

 \(x\)                  2x          2x            x           x

\(NaHCO_3+HCl\rightarrow NaCl+H_2O+CO_2\)

 \(y\)                  y            y            y           y

Ta có hệ:

\(\left\{{}\begin{matrix}106x+84y=19\\x+y=\dfrac{4,48}{22,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

\(m_{Na_2CO_3}=0,1\cdot106=10,6g\)

\(m_{NaHCO_3}=0,1\cdot84=8,4g\)

\(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ NaHCO_3+HCl\rightarrow NaCl+CO_2+H_2O\\ Đặt:n_{Na_2CO_3}=a\left(mol\right);n_{NaHCO_3}=b\left(mol\right)\left(a,b>0\right)\\ m_{hh.muối.ban.đầu}=19\left(g\right)\\ \Leftrightarrow106a+84b=19\left(1\right)\\ Mặt.khác:V_{CO_2\left(tổng\right)}=22,4a+22,4b=4,48\left(2\right)\\ \left(1\right),\left(2\right)\Rightarrow\left\{{}\begin{matrix}106a+84b=19\\22,4a+22,4b=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow m_{NaHCO_3}=84.0,1=8,4\left(g\right)\\ m_{Na_2CO_3}=106.0,1=10,6\left(g\right)\)

a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%

PTHH\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)

tl............1................2.............2.............1.............1..(mol

br     0,1.................0,2......................................0,1(mol)

NaCl không phản ứng đc vsHCl

b)\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(C_{MHCl}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)(đổi 400ml=0,4(l))

c)\(Tacom_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)

\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{10,6}{20}.100=53\%\)

\(\Rightarrow\%mNaCl=100\%-53\%=47\%\)

a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{14,8}.100\%\approx72,97\%\\\%m_{MgO}\approx27,03\%\end{matrix}\right.\)

b, Ta có: \(n_{MgO}=\dfrac{14,8-0,4.27}{40}=0,1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}+n_{MgO}=0,7\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,7.98=68,6\left(g\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{68,6}{10\%}=686\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\\n_{MgSO_4}=n_{MgO}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có: m _{dd sau pư} = 14,8 + 686 - 0,6.2 = 699,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{699,6}.100\%\approx9,78\%\\C\%_{MgSO_4}=\dfrac{0,1.120}{699,6}.100\%\approx1,72\%\end{matrix}\right.\)