a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Cu}=24-m_{Fe}=12,8\left(g\right)\) \(\Rightarrow n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)

Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu}=0,2\left(mol\right)\\n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

⇒ m = m_CuO + m_Fe2O3 = 0,2.80 + 0,1.160 = 32 (g)

b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,2.80}{32}.100\%=50\%\\\%m_{Fe_2O_3}=50\%\end{matrix}\right.\)

c, Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)

\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\) \(\Rightarrow y=0,03\left(mol\right)\)

\(Fe_xO_y+yH_2\rightarrow\left(t^o\right)xFe+yH_2O\)

\(n_{H_2}=\dfrac{0,448}{22,4}=0,02mol\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

0,02                                  0,02   ( mol )

\(\Rightarrow x=0,02\left(mol\right)\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\)

\(\Rightarrow CTHH:Fe_2O_3\)

\(n_{H_2\left(thu\right)}=\dfrac{V}{22,4}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

1                                 :    1    (mol)

0,02                            :  0,02 (mol)

\(n_{H_2\left(dùng\right)}=\dfrac{V}{22,4}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)

\(yH_2+Fe_xO_y\rightarrow^{t^0}xFe+yH_2O\)

y                      :       x  (mol)

0,03                 :      0,02 (mol)

\(\Rightarrow\dfrac{0,03}{y}=\dfrac{0,02}{x}\)

\(\Rightarrow\dfrac{x}{y}=\dfrac{0,02}{0,03}=\dfrac{2}{3}\Rightarrow x=2;y=3\)

-Vậy CTHH của oxit sắt là Fe₂O₃.

\(n_{Al}=\dfrac{0,54}{27}=0,02mol\\ n_{H_2SO_4}=0,07.0,5=0,035mol\\ 2Al+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow H_2SO_4:dư\\ V=\dfrac{3}{2}.0,02.22,4=0,672L\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,005}{0,07}=0,071M\\ C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,01}{0,07}=\dfrac{1}{7}\left(M\right)\\ CuO+H_2-t^{^0}->Cu+H_2O\\ n_{H_2}=0,03mol\\ n_{CuO}=\dfrac{6,4}{80}=0,08\Rightarrow CuO:dư\\ m_{rắn}=6,4-16.0,03=5,92g\)

n hh khí = 0.5 mol 
nCO: x mol 
nCO2: y mol 
=> x + y = 0.5 
28x + 44y = 17.2 g 
=> x = 0.3 mol 
y = 0.2 mol 
Khối lượng oxi tham gia pứ oxh khử oxit KL: 0.2 * 16 = 3.2g => m KL = 11.6 - 3.2 = 8.4g 
TH: KL hóa trị I => nKL = 2*nH2 = 0.3 mol => KL: 28!! 
KL hóa trị III => nKL = 2/3 *nH2 = 0.1 mol => KL: 84!! 
KL hóa trị II => nKL = nH2 = 0.15 mol => KL: 56 => Fe. 
nFe / Oxit = 0.15 mol 
nO/Oxit = 0.2 mol 
=> nFe/nO = 3/4 => Fe3O4 
Fe3O4 + 4CO = 3Fe + 4CO2 
Fe + H2SO4 = FeSO4 + H2 
0.15.....0.15.......0.15.....0.15 
=> mH2SO4 pứ = 14.7 g => mdd = 147 g 
m dd sau khi cho KL vào = m KL + m dd - mH2 thoát ra = 0.15 * 56 + 147 - 0.15*2 = 155.1g 
=> C% FeSO4 = 14.7% 

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

BTNT, có: \(n_{SO_4}=n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\)

Mà: m _muối = m_KL + m_SO4

⇒ m = m_KL = 93,6 - 0,6.96 = 36 (g)

Bạn tham khảo nhé!

a) CuO + H2 → Cu + H2O (1)

FexOy + yH2 → xFe + yH2O (2)

Fe + H2SO4 → FeSO4 + H2↑ (3)

nH2 = \(\frac{0,672}{22,4}\)= 0,03 mol

Theo (3): nH2SO4 = nH2 = 0,03 mol

CM (H2SO4) =\(\frac{0,03}{0,2}\) = 0,15(M)

b)

Theo (3): nFe = nH2 = 0,03 mol

mCu + mFe = 2,32 (g)

→ mCu = 2,32 - 0,03 . 56 = 0,64 (g)

nCu =\(\frac{0,64}{64}\) = 0,01 (mol)

Theo (1): nCuO = nCu = 0,01 mol

mCuO + mFexOy = 3,12

→ mFexOy = 2,32(g)

Theo (2): \(n_{FexOy}=\frac{nFe}{x}=\frac{0,03}{x}\left(mol\right)\)

\(M_{FexOy}=\frac{2,32}{\frac{0,03}{x}}=\frac{232x}{3}\)

\(56x+16y=\frac{232x}{3}\)

\(\rightarrow\frac{x}{y}=\frac{3}{4}\)

Oxit :\(Fe3O4\)

Td với H₂SO₄:

\(n_{H_2}=\dfrac{2,9748}{24,79}=0,12mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{Al}=\dfrac{0,12.2}{3}=0,08mol\)

Td với HNO₃:

\(n_{Al}=a=0,08mol\\ n_{Cu}=b\)

Khí hoá nâu trong không khí → NO

\(n_{NO}=\dfrac{3,664}{24,79}=0,16mol\\ 3Cu+8HNO_3\rightarrow3Cu\left(NO_3\right)_2+2NO+4H_2O\\ Al+4HNO_3\rightarrow Al\left(NO_3\right)_3+NO+2H_2O\)

\(\Rightarrow a+\dfrac{2}{3}b=0,16\\ \Leftrightarrow0,08+\dfrac{2}{3}b=0,16\\ \Leftrightarrow b=0,12mol\\ \Rightarrow m=0,08.27+0,12.64=9,84g\)

a) \(CuO+CO\underrightarrow{t^o}Cu+CO2\)

\(FexOy+yCO\underrightarrow{t^o}xFe+yCO2\)

\(Fe+2HCl\rightarrow FeCl2+H2\)

Ta có:

\(n_{H2}=\dfrac{4,704}{22,4}=0,21\left(mol\right)\)

\(\Rightarrow n_{Fe}=0,21\left(mol\right)\Rightarrow m_{Fe}=11,76\left(g\right)\)

\(\Rightarrow m_{Cu}=14,32-11,76=2,56\left(g\right)\)

\(\Rightarrow n_{Cu}=\dfrac{2,56}{64}=0,04\left(mol\right)\)

\(\Rightarrow n_{CuO}=0,04\left(mol\right)\)

\(\Rightarrow\%m_{CuO}=\dfrac{0,04.80}{19,44}.100\%=16,46\%\)

\(\Rightarrow\%m_{FexOy}=100-16,46=83,54\%\)

b) \(m_{FexOy}=19,44-0,04.80=16,24\left(g\right)\)

\(n_{Fe}=0,21\left(mol\right)\)

\(\Rightarrow n_{FexOy}=\dfrac{1}{x}n_{Fe}=\dfrac{0,21}{x}\left(mol\right)\)

\(M_{FexOy}=\dfrac{16,24}{\dfrac{0,21}{x}}=\dfrac{232}{3}x\)

\(\Rightarrow FexOy\) là \(Fe3O4\)

Chúc bạn học tốt ^^

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