Đáp án : C.

Xét Na : n H 2 = 1 2 n N a = a 46 m o l

Bảo toàn khối lượng :

m_{dd sau} = m_Na + m H 2 O – m H 2  = a + p – 2.  a 46 (g)

=> C%_NaOH = x %

Xét Na₂O

=> m_{dd sau} = m N a 2 O + m H 2 O = b + p

\(a.Na_2O+H_2O\rightarrow2NaOH\\ b.n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\\ \Rightarrow CM_{NaOH}=\dfrac{0,2}{0,5}=0,4M\\ c.H_2SO_4+2NaOH\rightarrow Na_2SO_4+H_2O\\ n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,1\left(mol\right)\\ m_{ddH_2SO_4}=\dfrac{0,1.98}{9,8\%}=100\left(g\right)\)

\(m_{H_2} = 8,5 + 50 - 58,4 = 0,1(gam)\\ n_{H_2} = \dfrac{0,1}{2} = 0,05(mol)\\ 2Na + 2H_2O \to 2NaOH + H_2\\ Na_2O + H_2O \to 2NaOH\\ n_{Na} = 2n_{H_2} = 0,05.2 = 0,1(mol)\\ \Rightarrow n_{Na_2O} = \dfrac{8,5-0,1.23}{62}=0,1(mol)\\ n_{NaOH} = 2n_{Na_2O} + n_{Na} = 0,3(mol)\\ C\%_{NaOH} = \dfrac{0,3.40}{58,4}.100\% = 20,55\%\)

Bài 6:

\(n_{Fe\left(OH\right)_3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)

PT: \(Fe\left(OH\right)_3+3HCl\rightarrow FeCl_3+3H_2O\)

_______0,2________0,6______0,2 (mol)

a, \(C\%_{HCl}=\dfrac{0,6.36,5}{200}.100\%=10,95\%\)

b, \(C\%_{FeCl_3}=\dfrac{0,2.162,5}{21,4+200}.100\%\approx14,68\%\)

Bài 7:

\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)

PT: \(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)

______0,1______0,1_______0,1 (mol)

a, \(m_{ZnO}=0,1.81=8,1\left(g\right)\)

b, \(C\%_{ZnSO_4}=\dfrac{0,1.161}{8,1+100}.100\%\approx14,89\%\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)

\(n_{Na_2O}=\dfrac{6.2}{62}=0.1\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

\(0.1.........................0.2\)

\(C_{M_{NaOH}}=\dfrac{0.2}{0.5}=0.4\left(M\right)\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

\(0.2.............0.2\)

\(m_{HCl}=0.2\cdot36.5=7.3\left(g\right)\)

Chúc em học tốt !!!

Theo pt: nNa2HPO4 = 2.nP2O5 = 0,1. 2 = 0,2 mol

Theo định luật bảo toàn khối lượng:

Khối lượng dung dịch sau phản ứng = khối lượng các chất tham gia phản ứng = mNaOH + mP2O5 = 50 + 0,1.142 = 64,2

a) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{HCl} =2 n_{Fe} = 0,2.2 = 0,4(mol)$
$C\%_{HCl} = \dfrac{0,4.36,5}{200}.100\% = 7,3\%$

b) $n_{H_2} = n_{FeCl_2} = n_{Fe} = 0,2(mol)

Sau phản ứng, $m_{dd} = 11,2 + 200 - 0,2.2 = 210,8(gam)$
$C\%_{FeCl_2} = \dfrac{0,2.127}{210,8}.100\% = 12,05\%$