nC = 4,8/12 = 0,4 mol

nS = 6,4/32 = 0,2 mol

a. C + O2 -> (nhiệt độ) CO2

S + O2 -> (nhiệt độ) SO2

nO2 = nC + nS = 0,6 mol

=> nN2 = 4 x nO2 = 2,4 mol

=> n không khí = 3 mol => V = 67,2 L

b. mB = 44 x 0,4 + 64 x 0,2 = 30,4 g

nB = 0,6 mol

=> M(trung bình của B) = 30,4/0,6 = 50,67 g/mol 

PTHH: 2CO+O2to→2CO2 (1)

                4H2+O2to→2H2O  (2)

b) Ta có:

ΣnO2=\(\dfrac{9,6}{32}\)=0,3(mol)

nCO2=\(\dfrac{8,8}{44}\)=0,2(mol)

⇒{nO2(1)=0,1mol

nO2(2)=0,2mol

⇒{mCO=0,1⋅28=2,8(g)

mH2=0,2⋅2=0,4(g)

 ⇒%mCO=\(\dfrac{2,8}{2,8+0,4}\)⋅100%=87,5%

%mH2=12,5%

\(nO_2=\dfrac{9,6}{32}=0,3\left(mol\right)\)

\(nCO_2=\dfrac{8,8}{44}=0,2\left(mol\right)\)

\(2CO+O_2\underrightarrow{t^o}2CO_2\)

  2        1         2   (mol)

0,2       0,1      0,2   (mol)

\(4H_2+O_2\underrightarrow{t^o}2H_2O\)

4         1         2     (mol)

0,8       0,2      0,4 (mol)

\(mCO=0,2.28=5,6\left(g\right)\)

\(mH_2=0,8.2=0,16\left(g\right)\)

\(\%mCO=\dfrac{5,6.100}{5,6+0,16}=97,22\%\)

\(\%mH_2=100-97,22=2,78\%\)

a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)

\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)

\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)

b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)

\(\rightarrow V_{kk}=4,48.5=11,2l\)

c. Có \(n_{Mg}=2n_{O_2}=0,2l\)

\(\rightarrow m_{Mg}=0,2.24=4,8g\)

\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)

\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)

a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\)  (1)

                \(4H_2+O_2\underrightarrow{t^o}2H_2O\)  (2)

b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)

c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)

\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)

a. \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

     a          2a      a

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

  b          3b       2b

b. \(n_{O_2}=\dfrac{25.88}{22.4}=1.155mol\)

n hỗn hợp khí \(=\dfrac{11.2}{22.4}=0.5mol\)

Ta có: \(\left\{{}\begin{matrix}a+b=0.5\\2a+3b=1.155\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.345\\b=0.155\end{matrix}\right.\)

\(\%V_{CH_4}=\dfrac{0.345\times22.4\times100}{11.2}=69\%\)

\(\%V_{C_2H_4}=100-69=31\%\)

c. \(V_{CO_2}=\left(a+2b\right)\times22.4=\left(0.345+2\times0.155\right)\times22.4=14.672l\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)

\(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,25\left(mol\right)\\n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,25.22,4}{6,72}.100\%\approx83,33\%\\\%V_{C_2H_2}\approx16,67\%\end{matrix}\right.\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,625\left(mol\right)\Rightarrow m_{O_2}=0,625.32=20\left(g\right)\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)

b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)

THAM KHẢO:

Gọi số mol Mg và Zn lần lượt là x, y

Ta có 24x + 65y=23.3

     40x + 81y=36.1

=) x=0.7

    y= 0.1

b)

c)

\(a,2Mg+O_2\rightarrow\left(t^o\right)2MgO\\ 2Zn+O_2\rightarrow\left(t^o\right)2ZnO\\ b,n_{O_2}=\dfrac{36,1-23,3}{32}=0,4\left(mol\right)\\ V_{O_2\left(\text{đ}ktc\right)}=0,4.22,4=8,96\left(l\right)\\ \text{Đ}\text{ặt}:a=n_{Mg};b=n_{Zn}\left(a,b>0\right)\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}24a+65b=23,3\\0,5a+0,5b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,7\\b=0,1\end{matrix}\right.\\ c,m_{Mg}=24a=24.0,7=16,8\left(g\right)\\ m_{Zn}=65b=65.0,1=6,5\left(g\right)\)