\(n_{Fe_2O_3}=\frac{2,4}{160}=0,015\left(mol\right)\)

PTHH : Fe₂O₃ + 3H₂SO4 -----> Fe₂(SO4)₃ + 3H₂O

(mol)       0,015       0,045             0,015

\(\Rightarrow m_{Fe_2\left(SO_4\right)_3}=0,045\times400=18\left(g\right)\)

\(\Rightarrow\%Fe_2\left(SO_4\right)_3=\frac{18}{300}\times100=6\%\)

Câu 1 : 

\(n_{HCl}=\dfrac{73\cdot20\%}{36.5}=0.4\left(mol\right)\)

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

\(..........0.4.......0.2\)

\(m_{CuCl_2}=0.2\cdot135=27\left(g\right)\)

Câu 2 : 

\(n_{Fe_2O_3}=\dfrac{2.4}{160}=0.015\left(mol\right)\)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

\(0.015...........................0.015\)

\(m_{dd}=2.4+300=302.4\left(g\right)\)

\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.015\cdot400}{302.4}\cdot100\%=1.98\%\)

Ta có: \(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)

\(m_{H_2SO_4}=300.78,4\%=235,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{235,2}{98}=2,4\left(mol\right)\)

PT: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)

____0,5____1,5________0,25______0,75 (mol)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=2,4-1,5=0,9\left(mol\right)\)

Ta có: m _{dd sau pư} = m_Fe + m _{dd H2SO4} - m_SO2 

                             = 0,5.56 + 300 - 0,75.64 = 280 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,9.98}{280}.100\%=31,5\%\\C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,25.400}{280}.100\%\approx35,7\%\end{matrix}\right.\)

Bạn tham khảo nhé!

a) Fe + H2SO4 -----------> FeSO4 + H2

\(n_{Fe}=n_{H_2}=0,75\left(mol\right)\)

=> \(m_{Fe}=0,75.56=42\left(g\right)\)

b) \(CM_{H_2SO_4}=\dfrac{0,75}{0,25}=3M\)

c) \(m_{ddsaupu}=42+250.1,1-0,75.2=315,5\left(g\right)\)

=> \(C\%_{FeSO_4}=\dfrac{0,75.152}{315,5}.100=36,13\%\)

\(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)

\(PTHH:2Fe+6H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)

 Mol:         0,5           1,5                   0,25          0,75       1,5

a)m_Fe=0,5.56=28 (g)

b)\(C_{MddH_2SO_4}=\dfrac{1,5}{0,25}=6\left(mol/l\right)\)

c)\(m_{Fe_2\left(SO_4\right)_3}=0,25.400=100\left(g\right)\)

  \(m_{H_2O}=1,5.18=27\left(g\right)\)

\(C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{100.100}{100+27}=78,74\%\)

1. Ta có: m _{dd A} = m_{Fe2O3 (pư)} + m _{dd H2SO4} 

⇒ m_{Fe2O3 (pư)} = 474 - m (g) \(\Rightarrow n_{Fe_2O_3\left(pư\right)}=\dfrac{474-m}{160}\left(mol\right)\)

\(n_{H_2SO_4}=\dfrac{m.9,8\%}{98}\left(mol\right)\)

PT: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

Theo PT: \(n_{H_2SO_4}=3n_{Fe_2O_3}\)

\(\Rightarrow\dfrac{9,8\%m}{98}=3.\dfrac{474-m}{160}\) \(\Rightarrow m=450\left(g\right)\)

\(\Rightarrow n_{H_2SO_4}=0,45\left(mol\right)\)

Theo PT: \(n_{Fe_2O_3}=\dfrac{48}{160}=0,3\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,45}{3}\), ta được Fe₂O₃ dư.

\(\Rightarrow n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}=0,15\left(mol\right)\)

\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,15.400}{474}.100\%\approx12,66\%\)

2. Sau khi cho 48 (g) Fe₂O₃ vào 450 (g) dd H₂SO₄ thu được thì trong bình chứa dd A: 0,15 (mol) Fe₂(SO₄)₃ và 0,15 (mol) Fe₂O₃ dư.

\(SO_2+Fe_2\left(SO_4\right)_3+2H_2O\rightarrow2H_2SO_4+2FeSO_4\)

0,15________0,15_______________0,3________0,3 (mol)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

0,1___________0,3________0,1 (mol)

\(SO_2+Fe_2\left(SO_4\right)_3+2H_2O\rightarrow2H_2SO_4+2FeSO_4\)

0,1___________0,1______________0,2_________0,2 (mol)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

0,05_________0,15________0,05 (mol)

\(SO_2+Fe_2\left(SO_4\right)_3+2H_2O\rightarrow2H_2SO_4+2FeSO_4\)

_0,05________0,05______________0,1_______0,1 (mol)

⇒ n_SO2 = 0,15 + 0,1 + 0,05 = 0,3 (mol)

⇒ m _{dd B} = 48 + 450 + 0,3.64 = 517,2 (g)

Dd B gồm: FeSO₄: 0,6 (mol) và H₂SO₄: 0,15 (mol)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{0,6.152}{517,2}.100\%\approx17,63\%\\C\%_{H_2SO_4}=\dfrac{0,15.98}{517,2}.100\%\approx2,84\%\end{matrix}\right.\)

PTHH: \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{MgO}=\dfrac{40}{40}=1\left(mol\right)\\n_{H_2SO_4}=\dfrac{300\cdot98\%}{98}=3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{MgSO_4}=1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{120}{300+40}\cdot100\%\approx35,3\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{2\cdot98}{300+40}\cdot100\%\approx57,65\%\end{matrix}\right.\)