Đáp án A.

0,95m (g) → hh (PbO và PbS dư) + SO₂

Áp dụng ĐLBTKH ta có:

m_O = m – 0,95m = 0,05m (g) → n_O = 3,125.10^-3 m (mol)

Ta có: n_PbS  phản ứng = n_PbO = n_O = 3,125.10^-3 m (mol)

→ %PbS (đã bị đốt cháy) = (3,125. 10^-3 m.239.100% )/m = 74,69%

PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)  (1)

            \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)  (2)

Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\\n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\Rightarrow n_{O_2\left(2\right)}=0,075\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{O_2\left(1\right)}=1,425\left(mol\right)\) \(\Rightarrow n_{Mg}=2,85\left(mol\right)\)

\(\Rightarrow\%m_{Mg}=\dfrac{2,85\cdot24}{2,85\cdot24+2,7}\cdot100\%\approx96,2\%\)

\(\Rightarrow\%m_{Al}=3,8\%\) 

\(n_{O_2} =\dfrac{33,6}{22,4} = 1,5(mol)\\ n_{Al} = \dfrac{2,7}{27} = 0,1(mol)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ n_{O_2} = \dfrac{1}{2}n_{Mg} + \dfrac{3}{4}n_{Al}\\ \Rightarrow n_{Mg} = 2,85(mol)\)

Vậy :

\(\%m_{Mg} = \dfrac{2,85.24}{2,85.24 + 2,7}.100\% = 96,2\%\\ \%m_{Al} = 100\% - 96,2\% = 3,8\%\)

n Al = a(mol) ; n Fe = b(mol)

=> 27a + 56b = 20,65(1)

2Al + 3H2SO4 → Al2(SO4)3 + 3H2

a...........1,5a............0,5a............1.5a..(mol)

Fe + H2SO4 → FeSO4 + H2

b...........b..............b............b......(mol)

=> n H2 = 1,5a + b = 0,725(2)

Từ 1,2 suy ra a = 0,35 ; b = 0,2

Suy ra :

%m Al = 0,35.27/20,65  .100% = 45,76%
%m Fe = 100% -45,76% = 54,24%

m H2SO4 = (1,5a + b).98 = 71,05 gam

m muối = m kim loại + m H2SO4 -m H2 = 20,65 + 71,05 -0,725.2 = 90,25 gam

\(a.Al,Ag+H_2SO_4\rightarrow ChỉcóAlphảnứng,chấtrắnsauphảnứnglàAg\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ TheoPT:n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\\ \Rightarrow m_{rắnsaupu}=m_{Ag}=15,4-2,7=12,7\left(g\right)\\ b.\%m_{Al}=\dfrac{2,7}{15,4}.100=17,53\%,\%m_{Ag}=100-17,53=82,47\%\)

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Theo bài ra, ta có: \(\dfrac{1}{2}\Sigma m_{Cu}=3,2\left(g\right)\) \(\Rightarrow m_{Cu}=6,4\left(g\right)\)

\(\Rightarrow\%m_{Cu}=\dfrac{6,4}{17,2}\cdot100\%\approx37,21\%\) \(\Rightarrow\%m_{Al}=62,79\%\)

Theo PTHH: \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot\dfrac{\dfrac{17,2-6,4}{2}}{27}=0,3\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)

Đáp án :B