n_Fe=11,2/56=0,2 mol

n_H2SO4=24,5/98=0,25

PTPƯ: Fe +       H₂SO₄ ---> FeSO₄ +        H₂

              _{0,2 mol ----> 0,2 mol --------------------> 0,2 mol}

Ta có Fe:H₂SO₄=0,2/1<0,25/1 (nên H₂SO₄ dư)

a, m_H2SO4=(0,25-0,2).98=4,9 g

b, V_H2=0,2.22,4=4,48 l

nMg = 4,8 : 24 = 0,2 mol

a) Mg  +  H₂SO₄  →  MgSO₄  +   H₂

Theo tỉ lệ phản ứng => nH₂SO₄ phản ứng = nMgSO₄ = nH₂ = 0,2 mol

=> VH₂ = 0,2.22,4 = 4,48 lít.

b)

mH₂SO₄ phản ứng = 0,2.98 = 19,6 gam

=> C% _H2SO4 = \(\dfrac{19,6}{300}.100\text{%}\) = 6,53%

c) mMgSO₄ = 0,2.120 = 24 gam.

a) Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+65b=12,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Bảo toàn electron: \(2n_{Fe}+2n_{Zn}=2n_{H_2}\) \(\Rightarrow2a+2b=0,4\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{12,1}\cdot100\%\approx46,28\%\\\%m_{Zn}=53,72\%\end{matrix}\right.\)

b)

Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=n_{Zn}=n_{ZnSO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(p.ứ\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow\Sigma n_{H_2SO_4}=0,2\cdot110\%=0,22\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1\cdot152=15,2\left(g\right)\\m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=\left(0,22-0,2\right)\cdot98=1,96\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=211,7\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{211,7}\cdot100\%\approx7,18\%\\C\%_{ZnSO_4}=\dfrac{16,1}{211,7}\cdot100\%\approx7,61\%\\C\%_{H_2SO_4}=\dfrac{1,96}{22,4}\cdot100\%\approx0,93\%\end{matrix}\right.\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{HCl}=0,5.1=0,5\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{H_2}=n_{Fe}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,4\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\)

b, Dung dịch a gồm HCl dư và FeCl₂.

PT: \(HCl+NaOH\rightarrow NaCl+H_2O\)

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_{2\downarrow}+2NaCl\)

Theo PT: \(n_{NaOH}=n_{HCl\left(dư\right)}+2n_{FeCl_2}=0,5\left(mol\right)\)

\(\Rightarrow a=C_{M_{NaOH}}=\dfrac{0,5}{0,2}=2,5M\)

c, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

Bạn tham khảo nhé!

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\n_{H_2SO_4}=\dfrac{294\cdot10\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,3}{3}\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,075\left(mol\right)=n_{H_2SO_4\left(dư\right)}\\n_{H_2}=0,225\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,225\cdot22,4=5,04\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,075\cdot342=25,65\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,075\cdot98=7,35\left(g\right)\\m_{H_2}=0,225\cdot2=0,45\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=297,6\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{25,65}{297,6}\cdot100\%\approx8,62\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{7,35}{297,6}\cdot100\%\approx4,47\%\end{matrix}\right.\)

Câu 1 :

a)  PTHH : 

 \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) (1) 

  \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)(2)

b) Ta có : \(n_{Zn}=\frac{3,5}{65}\approx0,054\left(mol\right)\)

Theo phương trình hóa học (1) :

\(n_{H_2}=n_{Zn}\approx0,054\left(mol\right)\)

\(\Rightarrow V_{H_2}\approx0,054\cdot22,4=1,2096\left(l\right)\)

c) Theo phương trình hóa học (2), ta có:

\(n_{Cu}=n_{H_2}\approx0,054\left(mol\right)\)

\(\Rightarrow m_{Cu}\approx0,054\cdot64=3,456\left(g\right)\)

Bài 2:

a) Ta có : \(n_{Al}=\frac{2,7}{27}=0,1\left(mol\right)\); \(n_{HCl}=\frac{200\cdot7,3}{100\cdot36,5}=0,4\left(mol\right)\)

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Theo phương trình hóa học : \(n_{H_2}=\frac{3}{2}n_{Al}=\frac{3}{2}.0,1=0,15\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

b) Theo phương trình hóa học , ta có : \(n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\)

Lại có: \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)

Áp dụng định luật bảo toàn khối lượng, ta có:

\(m_{Al}+m_{dd_{HCl}}=m_{dd_{AlCl_3}}+m_{H_2}\)

\(\Leftrightarrow2,7+200=m_{dd_{AlCl_3}}+0,3\)

\(\Leftrightarrow m_{dd_{AlCl_3}}=202,4\left(g\right)\)

Vậy \(C\%_{dd_{AlCl_3}}=\frac{13,35}{202,4}\cdot100\%\approx6,6\%\)

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25(mol)\\ Mg+H_2SO_4\to MgSO_4+H_2\\ MgO+H_2SO_4\to MgSO_4+H_2O\\ \Rightarrow n_{Mg}=0,25(mol)\\ a,\begin{cases} \%_{Mg}=\dfrac{0,25.24}{14}.100\%=42,86\%\\ \%_{MgO}=100\%-42,86\%=57,14\% \end{cases}\\ b,n_{MgO}=\dfrac{14-0,25.24}{40}=0,2(mol)\\ \Rightarrow \Sigma n_{H_2SO_4}=0,2+0,25=0,45(mol)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{0,45.98}{200}.100\%=22,05\%\)

\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,2.65}{25.8}.100=50,39\%\\ \%m_{Cu}=100-50,39=49,61\%\\ b.m_{ddsaupu}=0,2.65+200-0,2.2=212,6\left(g\right)\\ n_{ZnSO_4}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnSO_4}=\dfrac{0,2.161}{212,6}.100=15,15\%\)