a) 

C₂H₄ + Br₂ --> C₂H₄Br₂

C₂H₂ + 2Br₂ --> C₂H₂Br₄

b) Gọi số mol C₂H₄, C₂H₂ là a, b (mol)

=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)

PTHH: C₂H₄ + Br₂ --> C₂H₄Br₂

                a---->a

             C₂H₂ + 2Br₂ --> C₂H₂Br₄

                b---->2b

=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)

(1)(2) => a = 0,3 (mol); b = 0,2 (mol)

\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)

a, Cho hỗn hợp khí CH₄ và C₂H₄ qua dung dịch Br₂ dư chỉ có C₂H₄ tham gia phản ứng. PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{64}{160}=0,4(mol)\)

Theo PTHH: \(n_{C_2H_4}=n_{Br_2}=0,4(mol)\)

\(V_{C_2H_4}=n_{C_2H_4}.22,4=0,4.22,4=8,96(l)\)

Phần trăm của khí C₂H₄ trong hỗn hợp ban đầu là: \(\%V_{C_2H_4}=\dfrac{V_{C_2H_4}}{V_hh}.100\%=\dfrac{8,96}{11,2}.100\%=80\%\)

Phần trăm của khí CH₄ trong hỗn hợp ban đầu là: 

\(\%V_{CH_4}=100\%-\%V_{C_2H_4}=100\%-80\%=20\%\)

a, \(n_{Br_2}=\dfrac{48}{160}=0,3\left(mol\right)\)

PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

_____0,15____0,3 (mol)

\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,15.22,4}{11,2}.100\%=30\%\)

\(\Rightarrow\%V_{CH_4}=100-30=70\%\)

b, - Khí thoát ra ngoài là CH₄.

\(V_{CH_4}=11,2.70\%=7,84\left(l\right)\)

a)

C₂H₄ + Br₂ --> C₂H₄Br₂

b) \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)

PTHH: C₂H₄ + Br₂ --> C₂H₄Br₂

              0,2<---0,2

=> \(\%V_{C_2H_4}=\dfrac{0,2.22,4}{8,96}.100\%=50\%\)

=> \(\%V_{CH_4}=100\%-50\%=50\%\)

\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

0,5         0,5

\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)

\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)

\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)

\(\%V_{C_2H_4}=100\%-60\%=40\%\)

a, PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

b, \(n_{Br_2}=\dfrac{5,6}{160}=0,035\left(mol\right)\)

Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,0175\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,0175.22,4}{0,86}.100\%\approx45,58\%\)

\(\Rightarrow\%V_{CH_4}\approx54,42\%\)

Bài 14 : 

Vì metan không tác dụng với Brom nên : 

\(n_{C2H4Br2}=\dfrac{4,7}{188}=0,025\left(mol\right)\)

a) Pt : \(C_2H_4+Br_2\rightarrow C_2H_4Br_{2|}\)

              1          1                1

            0,025                    0,025

b) \(n_{C2H4}=\dfrac{0,025.1}{1}=0,025\left(mol\right)\)

\(V_{C2H4\left(dktc\right)}=0,025.22,4=0,56\left(l\right)\)

\(V_{CH4\left(dktc\right)}=1,4-0,56=0,84\left(l\right)\)

⁰/₀V_CH4 = \(\dfrac{0,84.100}{1,4}=60\)⁰/₀

⁰/₀V_C2H4 = \(\dfrac{0,56.100}{1,4}=40\)⁰/₀

 Chúc bạn học tốt

a)

$C_2H_2 + 2Br_2 \to C_2H_2Br_4$

b) $n_{Br_2} = \dfrac{40.20\%}{160} = 0,05(mol)$

Theo PTHH : $n_{C_2H_2Br_4} = n_{C_2H_2} = \dfrac{1}{2}n_{Br_2} = 0,025(mol)$

$m_{C_2H_2Br_4} = 0,025.346 = 8,65(gam)$

c) $\%V_{C_2H_2} = \dfrac{0,025}{0,5}.100\% = 5\%$

$\%V_{CH_4} = 100\% - 5\% = 95\%$

\(C_2H_2+2Br_2->C_2H_2Br_4\\ n_{hh}=\dfrac{3,36}{22,4}=0,15mol\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\\ n_{C_2H_2}=0,05mol\\ n_{Br_2}=2.0,05=0,1mol\\ m_{Br_2}=0,1.160=16g\\ \%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\ \%V_{C_2H_2}=33,33\%\)