C2H2 + 2Br2 => C2H2Br4 

CH4 + 2O2 -to-> CO2 + 2H2O

m bình tăng = mC2H2 = 5.2 (g) 

nC2H2 = 5.2/26 = 0.2 (mol) 

nCO2 = 13.2/44 = 0.3 (mol) => nCH4 = 0.3 (mol) 

Vì : tỉ lệ thể tích tương ứng với tỉ lệ số mol 

%C2H2 = 0.2/(0.2+0.3) * 100% = 40%

%CH4 = 100 - 40 = 60% 

nBr2 = 2nC2H2 = 0.2*2 = 0.4 (mol) 

CM Br2 = 0.4/0.4 = 1M

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

a) Ta có: \(n_{C_2H_4}=\dfrac{9,1}{28}=0,325\left(mol\right)=n_{Br_2}\) \(\Rightarrow V_{Br_2}=\dfrac{0,325}{2}=0,1625\left(l\right)=162,5\left(ml\right)\)

b) Ta có: \(\left\{{}\begin{matrix}n_{C_2H_4}=0,325\left(mol\right)\\n_{CH_4}=\dfrac{13,44}{22,4}-0,325=0,275\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{hh}=9,1+0,275\cdot16=13,5\left(g\right)\)

c) PTHH: \(CH_4+2O_2 \underrightarrow{t^o} CO_2+2H_2O\)

                \(C_2H_4+3O_2 \underrightarrow{t^o} 2CO_2+ 2H_2O\)

Theo các PTHH: \(\Sigma n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=1,525\left(mol\right)\)

\(\Rightarrow V_{O_2}=1,525\cdot22,4=34,16\left(l\right)\)

\(a,n_{Br_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\)

PTHH: C₂H₄ + Br₂ ---> C₂H₄Br₂

           0,04<---0,04

\(\rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,04.22,4=0,896\left(l\right)\\V_{CH_4}=2,24-0,896=1,344\left(l\right)\end{matrix}\right.\\ b,\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,896}{2,24}.100\%=40\%\\\%V_{CH_4}=100\%-40\%=60\%\end{matrix}\right.\)

a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

b, - Khí thoát ra là CH₄ ⇒ V_CH4 = 6,72 (l)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{6,72}{13,44}.100\%=50\%\\\%V_{C_2H_2}=50\%\end{matrix}\right.\)

a. PTHH: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

a. Vì CH₄ không phản ứng với dd Br₂ nên

       \(V_{CH_4}=6,72\left(l\right)\)

\(\%V_{CH_4}=\dfrac{6,72}{13,44}x100\%=50\%\)

\(\%V_{C_2H_2}=100\%-50\%=50\%\)

\(m_{tăng}=m_{C_2H_2}=1,3\left(g\right)\\ \Rightarrow n_{C_2H_2}=\dfrac{1,3}{26}=0,05\left(mol\right)\\ \Rightarrow\%V_{\dfrac{C_2H_2}{A}}=\dfrac{0,05.22,4}{4,48}.100=25\%\\ \Rightarrow\%V_{\dfrac{CH_4}{A}}=100\%-25\%=75\%\)

\(m_{tăng}=m_{C_2H_2}=0,78\left(g\right)\\PTHH:C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ n_{C_2H_2}=\dfrac{0,78}{26}=0,03\left(mol\right)\\ n_{hh.khí}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\\Rightarrow n_{CH_4}=0,1-0,03=0,07\left(mol\right)\\ n.tỉ.lệ.thuận.với.V\\ \%V_{CH_4}=\dfrac{0,07}{0,1}.100\%=70\%;\%V_{C_2H_2}=100\%-70\%=30\%\)

\(m_{bìnhtăng}=m_{anken}=m_{etilen}=1,4g\)

\(\Rightarrow n_{C_2H_4}=\dfrac{1,4}{28}=0,05mol\)

\(n_{hh}=\dfrac{4,48}{22,4}=0,2mol\)

\(\Rightarrow n_{metan}=n_{hh}-n_{eilen}=0,2-0,05=0,15mol\)

\(\%V_{metan}=\dfrac{0,15}{0,2}\cdot100\%=75\%\)

\(\%V_{etilen}=100\%-75\%=25\%\)