a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ 2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)

Cho hỗn hợp tác dụng với NaOH, chất rắn không tan là Fe

=> m_Fe= 1,12 (g) \(\Rightarrow n_{Fe}=0,02\left(mol\right)\)

Ta có: \(n_{H_2\left(2\right)}=n_{Fe}=0,02\left(mol\right)\)

=> \(n_{H_2\left(1\right)}=\Sigma n_{H_2}-n_{H_2\left(2\right)}=0,065-0,02=0,045\left(mol\right)\)

\(\Rightarrow n_{Al}=\dfrac{2}{3}n_{H_2\left(1\right)}=0,03\left(mol\right)\)

\(\Rightarrow m_{Al}=0,03.27=0,81\left(g\right)\)

\(\Rightarrow\%m_{Al}=41,97\%,\%m_{Fe}=58,03\%\)

b) \(m_{FeCl_2}=0,02.127=2,54\left(g\right)\\ m_{AlCl_3}=0,03.133,5=4,005\left(g\right)\)

\(a,Fe+2HCl\rightarrow FeCl_2+H_2\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\Rightarrow n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\%\approx41,176\%\\ \Rightarrow\%m_{CuO}\approx58,824\%\\ b,n_{CuO}=\dfrac{13,6-0,1.56}{80}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.\left(n_{Fe}+n_{CuO}\right)=2.\left(0,1+0,1\right)=0,4\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)

a/ Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

n_H2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PTHH: n_H2 = n_Fe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)

\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)

\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)

b/ Theo PTHH ta có: n_HCl = 2n_Fe = 2.0,15 = 0,3 (mol)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)

c/ m_HCl = 36,5 . 0,3 = 10,95(g)

\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)

b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)

c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)

\(n_{Al}=a;n_{Al_2O_3}=b\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\\ \Rightarrow\left\{{}\begin{matrix}27a+102b=23,1\\(a+2b)133,5=66,75\end{matrix}\right.\\ \Rightarrow a=0,1;b=0,2\\ \%m_{Al}=\dfrac{0,1.27}{23,1}\cdot100=11,7\%\\ \%m_{Al_2O_3}=100-11,7=88,3\%\)