\(nHCl=V_{HCl}\times CM_{HCl}=1.1mol\)

Bảo toàn nguyên tố: \(\dfrac{1}{2}nHCl=nH2=0.55mol\)

\(\Rightarrow V_{H2}=0.55\times22.4=12.32l\)

\(\Rightarrow m_{\left(muoi\right)}=m_{KL}+m_{Cl^-}=25.3+1.1\times35.5=64.35g\)

PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2O\)  (1)

            \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)  (2)

a) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{CaO}=0,1mol\\n_{CaCO_3}=0,2mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{hh}=20+5,6=25,6\left(g\right)\)

b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=0,2mol\\n_{HCl\left(2\right)}=0,4mol\end{matrix}\right.\)

\(\Rightarrow\Sigma n_{HCl}=0,6mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,3}=2\left(M\right)\)

PT: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\) (2)

a, Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\)

Theo PT (2): \(n_{CaCl_2}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow n_{CaCl_2\left(1\right)}=0,3-0,2=0,1\left(mol\right)\)

Theo PT (1): \(n_{CaO}=n_{CaCl_2}=0,1\left(mol\right)\)

Theo PT (2): \(n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow m_A=m_{CaO}+m_{CaCO_3}=0,1.56+0,2.100=25,6\left(g\right)\)

b, Theo PT (1) + (2): \(\Sigma n_{HCl}=2n_{CaO}+2n_{CaCO_3}=0,6\left(mol\right)\)

\(\Rightarrow C_{M_{ddHCl}}=\dfrac{0,6}{0,3}=2M\)

Bạn tham khảo nhé!

\(n_{HCl}=1,5.0,4=0,6(mol)\\ X+HCl\to muối+H_2\)

Bảo toàn H: \(n_{H_2}=\dfrac{n_{HCl}}{2}=0,3(mol)\)

\(\Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\BTKL:m_A+m_{HCl}=m_{muối}+m_{H_2}\\ \Rightarrow m_{muối}=35+0,6.36,5-0,3.2=56,3(g)\)

a) Ta có: \(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Gọi a và b lần lượt là số mol của Al và Zn

Bảo toàn mol e: \(3a+2b=1,4\)

                   Mà \(27a+65b=31,4\)

\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{31,4}\cdot100\%\approx17,2\%\\\%m_{Zn}=82,8\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=1,4mol\)

\(\Rightarrow V_{HCl}=\dfrac{1,4}{2}=0,7\left(l\right)=700\left(ml\right)\)

Đặt : 

nAl = a mol 

nZn = b mol 

mB = 27a + 65b = 31.4 (g) (1) 

2Al + 6HCl => 2AlCl3 + 3H2 

a___________________1.5a

Zn + 2HCl => ZnCl2 + H2 

b__________________b

nH2 = 1.5a + b = 15.68/22.4 = 0.7 (mol) (2) 

(1) , (2) : 

a = 0.2

b = 0.4 

%Al = 5.4/31.4 * 100% = 17.19%

%Zn = 100 - 17.19 = 82.81%

nHCl = 2nH2 = 0.7*2 = 1.4 (mol) 

Vdd HCl = 1.4 / 2 = 0.7 (l) 

a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

X là khí Hidro

b) Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Al}=0,2mol\) 

\(\Rightarrow\%m_{Al}=\dfrac{0,2\cdot27}{8,64}\cdot100\%=62,5\%\) \(\Rightarrow\%m_{Cu}=37,5\%\)

c) Theo PTHH: \(n_{HCl}=3n_{Al}=0,6mol\) 

\(\Rightarrow V_{HCl}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)

Ta có: n_N2 = 0,22 (mol)

⇒ n_NO3^- = 10n_N2 = 2,2 (mol)

⇒ m _muối = m_X + m_NO3^- = 31 + 2,2.62 = 167,4 (g)

n_HNO3 = 12n_N2 = 2,64 (mol)

\(\Rightarrow V_{HNO_3}=\dfrac{2,64}{2}=1,32\left(l\right)=1320\left(ml\right)\)

Ta có: \(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)

Gọi a và b lần lượt là số mol của Al và Fe

Bảo toàn mol e: \(3a+2b=1,4\)

                 Mà \(27a+56b=27,8\)

\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{27,8}\cdot100\approx19,42\%\\\%m_{Fe}=80,58\%\end{matrix}\right.\)

Đặt : 

nAl = a mol 

nFe = b mol 

mB = 27a + 56b = 27.8 (g) (1) 

2Al + 6HCl => 2AlCl3 + 3H2 

a___________________1.5a

Fe + 2HCl => FeCl2 + H2 

b__________________b

nH2 = 1.5a + b = 15.68/22.4 = 0.7 (mol) (2) 

(1) , (2) : 

a = 0.2

b = 0.4 

%Al = 5.4/27.8 * 100% = 19.42%

%Fe = 100 - 19.42 = 80.58%

\(4.\)

\(n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(0.15.....0.3....................0.15\)

\(m_{Fe}=0.15\cdot56=8.4\left(g\right)\)

\(C_{M_{HCl}}=\dfrac{0.3}{0.5}=0.6\left(M\right)\)

\(5.\)

\(Đặt:n_{Fe}=a\left(mol\right),n_{Al}=b\left(mol\right)\)

\(m_{hh}=56a+27b=8.3\left(g\right)\left(1\right)\)

\(n_{H_2}=\dfrac{5.6}{22.4}=0.25\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\Rightarrow a+1.5b=0.25\left(2\right)\)

\(\left(1\right),\left(2\right):a=b=0.1\)

\(\%Fe=\dfrac{5.6}{8.3}\cdot100\%=67.47\%\)

\(\%Al=32.53\%\)