Ta có:

n H 2 SO 4 =   0 , 2   x   2 , 5   +   0 , 1   x   1   =   0 , 6   ( mol )

→ C M  sau khi trộn = 0,6/0,3 = 2M.

\(V_{\text{dd}}=200+250=450ml=0,45l\\ n_{H_2SO_4}=\left(0,2.1\right)+\left(2.0,25\right)=0,7\left(mol\right)\\ C_M=\dfrac{0,7}{0,45}=1,5M\)

n H2SO4=0,2+0,2=0,4 mol

CM=\(\dfrac{0,4}{0,3}\)=1,33M

Câu 1:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,6\cdot0,4+0,6\cdot0,3\cdot2=0,6\left(mol\right)\\n_{H^+}=0,2\cdot2,6=0,52\left(mol\right)\end{matrix}\right.\) 

\(\Rightarrow\) H⁺ hết, OH^- còn dư \(\Rightarrow n_{OH^-\left(dư\right)}=0,08\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]=\dfrac{0,08}{0,6+0,2}=0,1\left(M\right)\) \(\Rightarrow pH=14+log\left(0,1\right)=13\)

Bài 2:

PT ion: \(H^++OH^-\rightarrow H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{OH^-}=0,3\cdot1,6=0,48\left(mol\right)\\n_{H^+}=0,2\cdot1\cdot2+0,2\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\) OH^- hết, H⁺ còn dư \(\Rightarrow n_{H^+\left(dư\right)}=0,32\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,32}{0,2+0,3}=0,64\left(M\right)\) \(\Rightarrow pH=-log\left(0,64\right)\approx0,19\)

Ta có: n H 2 SO 4 =   0 , 2   x   2 , 5   +   0 , 1   x   1   =   0 , 6   ( mol )

→ C M   sau   khi   trộn   =   0 , 6 / 0 , 3   =   2 M .

1. \(n_{H_2SO_4\left(98\%\right)}=\dfrac{30.1,84.98\%}{98}=0,552\left(mol\right)\)

=>\(V_{H_2SO_4\left(1M\right)}=\dfrac{0,552}{1}=0,552\left(l\right)\)

Ta có: \(m_{ddH_2SO_4\left(60\%\right)}=700.1,503=1052,1\left(g\right)\Rightarrow m_{H_2SO_4}=1052,1.60\%=631,26\left(g\right)\)

\(m_{ddH_2SO_4\left(20\%\right)}=500.1,1476=573,8\left(g\right)\Rightarrow m_{H_2SO_4}=573,8.20\%=114,76\left(g\right)\)

Σm_H2SO4 = 631,26 + 114,76 = 746,02 (g)

\(n_{H_2}=\dfrac{1,792}{22,4}=0,08\left(mol\right)\)

PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,08\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,08.98=7,84\left(g\right)\)

\(\Rightarrow\dfrac{746,02}{V}=\dfrac{7,84}{0,2}\Rightarrow V\approx19,03\left(l\right)\)