nOH^- = (0,2 + 0,1.2)V = 0,4V; nH⁺ = (0,25.2 + 0,75).0,04 = 0,05

Do trung hòa nên nOH^- = nH⁺  → 0,4V = 0,05 →  V = 0,125 lít 

Đáp án B

a, PT: \(HCl+KOH\rightarrow KCl+H_2O\)

\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

Gọi: \(\left\{{}\begin{matrix}n_{HCl}=x\left(mol\right)\\n_{CH_3COOH}=y\left(mol\right)\end{matrix}\right.\)

Theo PT: \(n_{KOH}=n_{HCl}+n_{CH_3COOH}=x+y=0,003.1=0,003\left(mol\right)\left(1\right)\)

\(\left\{{}\begin{matrix}n_{KCl}=n_{HCl}=x\left(mol\right)\\n_{CH_3COOK}=n_{CH_3COOH}=y\left(mol\right)\end{matrix}\right.\) ⇒ 74,5x + 98y = 0,235 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x\approx0,0025\left(mol\right)\\y\approx0,0005\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{0,0025}{0,01}=0,25\left(M\right)\\C_{M_{CH_3COOH}}=\dfrac{0,0005}{0,01}=0,05\left(M\right)\end{matrix}\right.\)

b, Ta có: \(n_{H^+}=n_{HCl}+n_{CH_3COOH}=0,003\left(mol\right)\)

\(n_{OH^-}=2n_{Ba\left(OH\right)_2}+n_{NaOH}=2.\dfrac{V}{1000}.0,02+\dfrac{V}{1000}.0,01\left(mol\right)\)

PT: \(H^++OH^-\rightarrow H_2O\)

Theo PT: \(n_{H^+}=n_{OH^-}\) 

\(\Rightarrow0,003=2.\dfrac{V}{1000}.0,02+\dfrac{V}{1000}.0,01\) \(\Rightarrow V=60\left(ml\right)\)

Đáp án: D

n_H+ = 0,002+0,02a

n_OH- = 0,0033

Vì n_H+= n_OH-

ð a= 0,065

a, Ta có: \(\left[H^+\right]=\left[HCl\right]+2\left[H_2SO_4\right]=0,003+2.0,002=0,007\left(M\right)\)

\(\Rightarrow pH=-log\left(0,007\right)\approx2,155\)

b, Ta có: \(\left[OH^-\right]=\left[NaOH\right]+2\left[Ba\left(OH\right)_2\right]=0,0001+2.0,0001=0,0003\left(M\right)\)

\(\Rightarrow pH=14-\left[-log\left(0,0003\right)\right]\approx10,477\)

nOH = nNaOH + 2nBa(OH)2 = 0,15 + 0,175 . 2 = 0,5 (mol)

nHCl = 2a (mol)

nH2SO4 = 0,1 . 2 = 0,2 (mol)

nH = nHCl + 2nH2SO4 = 2a + 2 . 0,2 = 2a + 0,4 (mol)

Để phản ứng trung hòa được thì nH = nOH

=> 0,5 = 0,4 + 2a

=> a = 0,05M

Đáp án là D