a)

Gọi $n_{CaCO_3} = a ; n_{MgCO_3} = b$
$\Rightarrow 100a + 84b = 4,68(1)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$MgCO_3 + 2HCl \to MgCl_2 +C O_2 + H_2O$

$n_{CO_2} = a + b = 0,05(2)$

Từ (1)(2) suy ra a = 0,03 ; b = 0,02

$\%m_{CaCO_3} = \dfrac{0,03.100}{4,68}.100\% = 64,1\%$
$\%m_{MgCO_3} = 35,9\%$

$m_{CaCl_2} = 0,03.111 = 3,33(gam)$
$m_{MgCl_2} = 0,02.95 = 1,9(gam)$
b)

$n_{HCl} = 2n_{CO_2} = 0,1(mol)$
$C_{M_{HCl}} = \dfrac{0,1}{0,25} = 0,4M$

Bài 1 :

Gọi 

\(n_{Fe} = a(mol) ; n_{Zn} = b(mol)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Zn + 2HCl \to ZnCl_2 + H_2\\ \)

Ta có : 

\(\hept{\begin{cases}n_{H_2}=a+b=\frac{3,36}{22,4}=0,15\left(mol\right)\\m_{muoi}=127a+136b=19,5\left(gam\right)\end{cases}}\)

\(\Rightarrow\hept{\begin{cases}a=0,1\\b=0,05\end{cases}}\)\(\Rightarrow\hept{\begin{cases}m_{Fe}=0,1.56=5,6\left(gam\right)\\m_{Zn}=0,05.65=3,25\left(gam\right)\end{cases}}\)

Bài 2 : 

\(\hept{\begin{cases}n_{BaCO_3}=a\left(mol\right)\\n_{BaSO_3}=b\left(mol\right)\end{cases}}\)

\(BaCO_3 + 2HCl \to BaCl_2 + CO_2 + H_2O\\ BaSO_3 + 2HCl \to BaCl_2 + SO_2 + H_2O\)

Ta có : 

\(\hept{\begin{cases}m_{hh}=197a+217b=20,5\left(gam\right)\\n_{khí}=n_{CO_2}+n_{SO_2}=a+b=\frac{2,24}{22,4}=0,1\left(mol\right)\end{cases}}\)

Suy ra:  a = 0,06 ; b = 0,04

\(\%m_{BaCO_3} = \dfrac{0,06.197}{20,5}.100\% =57,66\%\\ \%m_{BaSO_3} = 100\%- 57,66\%=42,34\%\)

a) nBaSO4=0,1(mol)

PTHH: Ba(OH)2 + H2SO4 -> BaSO4 + 2 H2O

2 NaOH + H2SO4 -> Na2SO4 + 2 H2O

=> nBa(OH)2= 0,1(mol) => mBa(OH)2=171.0,1=17,1(g)

%mBa(OH)2= (17,1/40).100=42,75%

=>%mNaOH=57,25%

b) mNaOH=22,9(g) => nNaOH= 22,9/40=0,5725(mol)

=> nH2SO4= 0,1+ 0,5725:2= 309/800(mol)

=>mH2SO4=309/800. 98=37,8525(g)

=>C%ddH2SO4= (37,8525/100).100=37,8525%

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35mol\)

Gọi \(\left\{{}\begin{matrix}n_{Fe}=x\\n_{Zn}=y\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

 x                                     x ( mol )

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

 y                                     y      ( mol )

Ta có:

\(\left\{{}\begin{matrix}56x+65y=21,4\\x+y=0,35\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,15\\y=0,2\end{matrix}\right.\)

\(\Rightarrow m_{Fe}=0,15.56=8,4g\)

\(\Rightarrow m_{Zn}=0,2.65=13g\)

\(\%m_{Fe}=\dfrac{8,4}{21,4}.100=39,25\%\)

\(\%m_{Zn}=100\%-39,25\%=60,75\%\)

\(m_{FeCl_2}=0,15.127=19,05g\)

\(m_{ZnCl_2}=0,2.136=27,2g\)

Đặt \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Fe}=y\end{matrix}\right.\) ( mol ) \(\rightarrow m_{hh}=27x+56y=5,54\left(g\right)\)  (1)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

 x                                                   1,5x    ( mol )

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

 y                                           y       ( mol )

\(n_{H_2}=1,5x+y=\dfrac{3,584}{22,4}=0,16\left(mol\right)\)   (1)

\(\left(1\right);\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,06\\y=0,07\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,06.27}{5,54}.100=29,24\%\\\%m_{Fe}=100-29,24=70,76\%\end{matrix}\right.\)

a) n Fe = a(mol) ; n Cu = b(mol)

=> 56a + 64b = 4,8(1)

n SO2 = 2,24/22,4 = 0,1(mol)

Bảo toàn e :

3n Fe + 2n Cu = 2n SO2

<=> 3a + 2b = 0,2(2)

Từ (1)(2) suy ra a = b = 0,04

%m Fe = 0,04.56/4,8  .100% = 46,67%

%m Cu = 100% -46,67% = 53,33%

b)

n KOH = 0,15

Ta có :

1 < n KOH / n SO2 = 0,15/0,1 = 1,5 < 2 nên muối sinh ra là Na2SO3(x mol) và NaHSO3(y mol)

2NaOH + SO2 $\to$ Na2SO3 + H2O

NaOH + SO2 $\to$ NaHSO3

Theo PTHH :

n SO2 = a + b = 0,1

n NaOH = 2a + b = 0,15

Suy ra a= 0,05 ; b = 0,05

m muối = 0,05.126 + 0,05.104 = 11,5 gam

Bài 2 :

- Gọi số mol Fe và Cu lần lượt là a, b mol

Ta có : mhh = mFe + mCu = 56a + 64b = 4,8

Bte : 3a + 2b = 0,2 

=> a = b =0,04mol

a, Ta có : mFe =n.M = 2,24g ( 46,7% )

=> %Cu = 53,3%

b, Ta thấy sau phản ứng thu được K+, SO3-2 xmol, HSO3- y mol

BtS : x + y = 0,1 

BTĐT : 2x + y = 0,15 

=> x =y = 0,05 mol

=> mM = mK2SO3 + mKHSO3 = 13,9g