b, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

\(n_P=\dfrac{6,2}{31}=0,2mol\\n_{O_2}=\dfrac{0,2.5}{4}=0,25mol \)

\(S+O_2\underrightarrow{t^o}SO_2\)

\(n_S=\dfrac{3,2}{32}=0,1mol\\ n_{O_2}=0,1mol\)

\(C+O_2\underrightarrow{t^o}CO_2\)

\(n_C=\dfrac{2,4}{12}=0,2mol\\ n_{O_2}=0,2mol\\ n_{O_2}\left(tổng\right)=\)

\(0,25+0,1+0,2=0,55mol\\ m_{O_2}\left(trong.hh.B\right)=0,55.32=17,6g\)

a, \(m_{Fe}=0,25.56=14g\)

\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

\(\Rightarrow n_{O_2}=\dfrac{0,25.2}{3}=0,16mol\\ m_{O_2}=0,16.32=5,12g\)

\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

\(n_{O_2}=\dfrac{0,25.3}{4}=0,1875mol\\ m_{O_2}=0,1875.32=6g\)

\(2Zn+O_2\underrightarrow{t^o}2ZnO\)

\(n_{O_2}=\dfrac{0,5.1}{2}=0,25mol\\ m_{O_2}=0,25.32=8g\)

\(\Rightarrow m_{O_2}\left(trong.hỗn.hợp.A\right)=\) \(5,12+6+8=19,12g\)

help mi

nH2 = 8 : 2 = 4 (mol) 
nCH4 = 2 : 16 = 0,125 (mol) 
pthh : 2H2 + O2-t--> 2H2O 
         4------->2 (mol) 
       CH4 + 2O2 ----> CO2 + 2H2O 
        0,125->0,25 (MOL) 
=> nO2= 2 + 0,25 = 2,25 (mol) 
   => mO2 = 2,25 . 32 = 72 (g) 

C  +  O2 --t--> CO2 
0,15->0,15 (mol) 
S  +   O2 -t--> SO2 
0,125->0,125 (mol) 
=> nO2 = 0,15 + 0,125 = 0,275 (mol) 
=> mO2 = 0,275 . 32 = 8,8 (G)

\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{O_2} = \dfrac{1}{2}n_{H_2} = 2,5(mol)\\ m_{O_2} = 2,5.32 = 80(gam)\)

\(2H_2+O_2\underrightarrow{^{t^0}}2H_2O\)

\(5......2.5\)

\(m_{O_2}=2.5\cdot32=80\left(g\right)\)

a) \(n_{KMnO_4}=\dfrac{15,8}{158}=0,1\left(mol\right)\)

\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

(mol)..........0,1................0,05..........0,05......0,05

\(V_{O_2}=0,05.22,4=1,12\left(l\right)\)

b) \(n_{Fe}=\dfrac{1.68}{56}=0,03\left(mol\right)\)

\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

(mol).......0,03....0,02.......0,1

\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

(mol)..........0,04..............0,02............0,02....0,02

\(m_{KMnO_4}=0,04.158=6,32\left(g\right)\)

\(m_{KMnO_4\left(thựctế\right)}=6,32:95\%\approx6,65\left(g\right)\)

\(n_{Fe}=\dfrac{1,68}{56}=0,03\left(mol\right)\)

\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)

 0,03   0,02               0,01  ( mol )

\(m_{Fe_3O_4}=0,01.232=2,32\left(g\right)\)

\(V_{kk}=0,02.22,4.5=2,24\left(l\right)\)

\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)

   \(\dfrac{1}{75}\)                               0,02   ( mol )

\(m_{KClO_3}=\dfrac{1}{75}.122,5=1,63\left(g\right)\)

a,nFe=1,68/56=0,03 mol

Ta có PTHH : 3Fe + 2O2 --> Fe3O4 (1) ( ở trên dấu --> có to nha )

Theo PTHH ta có :

nFe3O4=1/3nFe=1/3.0,03=0,01 mol

nO2=2/3nFe=2/3.0,03=0,02 mol

=>mFe3O4= 0,01.232=2,32g

=>Vkk=5.(0,02.22,4)=2,24 l

b, Ta có PTHH: 2KClO3 --> 2KCl + 3O2 (2) ( trên dấu --> vẫn có to )

Gọi x là số mol KClO3 cần dùng ( x > 0 )

Theo PTHH (3) và theo bài ra ta có PTHH sau:

2/3x=0,02 

=> x=0,03 mol

=> mKClO3= 0,03.122,5= 3,675g

$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)$

\(2CO+O_2\xrightarrow[]{t^o}2CO_2\)

0,2       0,1       0,2                 (mol)

$n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)$

\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)

0,4     0,2         0,2              (mol)

\(\%m_{CO}=\dfrac{0,2.44}{0,2.44+0,4.2}.100\%=91,67\%\\ \%m_{H_2}=100\%-91,67\%=8,33\%\)

\(\%n_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\ \%n_{H_2}=100\%-33,33\%=66,67\%\)

\(n_{hhkhí}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)

Gọi \(n_{SO_2}=a\left(mol\right)\left(0< a< 0,75\right)\)

\(\rightarrow n_{O_2\left(dư\right)}=0,75-b\left(mol\right)\)

Ta có: \(\dfrac{64a+32\left(0,75-a\right)}{0,75}=\dfrac{33,6}{1}=33,6\left(\dfrac{g}{mol}\right)\)

\(\rightarrow a=0,0375\left(mol\right)\)

\(\rightarrow\left\{{}\begin{matrix}\%V_{SO_2}=\dfrac{0,0375}{0,75}=5\%\\\%V_{O_2\left(dư\right)}=100\%-5\%=95\%\end{matrix}\right.\)

Bài 14

\(n_{O_2}=\dfrac{1.4}{22,4}=0,0625\left(mol\right)\)

\(n_P=\dfrac{2.5}{31}=0,0806451\left(mol\right)\)

4P  +  5O₂ ----t^o--->2P₂O₅

Xét tỉ lệ : \(\dfrac{0.0625}{5}< \dfrac{0.0806451}{4}\)

=> P ko cháy hết 

bài 15

\(n_{O_2}=\dfrac{3.36}{22,4}=0,15\left(mol\right)\)

Gọi n_Fe = a ( mol ) và n_S = b (mol )

PTHH : 

S + O₂ ---t^o---> SO₂

3Fe + 2O₂ ----t^o----> Fe₃O₄

Ta có 32b + 56a= 100

Theo PT : n_S = n_O2 = b (mol)

Theo PT : n_O2 = 2/3 n_Fe = 2/3a ( mol)

=> 2/3a + b = 1,5 

Từ những điều trên  \(\left[{}\begin{matrix}56a+32b=100\\\dfrac{2}{3}a+b=1,5\end{matrix}\right.\Leftrightarrow\left[{}\begin{matrix}a=1,5\left(mol\right)\\b=0,5\left(mol\right)\end{matrix}\right.\)

\(m_{Fe}=1,5.56=84\left(g\right)\)

\(m_S=0,5.32=16\left(g\right)\)

Bài 16 :

\(n_{H_2}=\dfrac{11.2}{22,4}=0,5\left(mol\right)\)

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Ta thấy : 0,5 > 0,2 => H₂ dư , CuO đủ

PTHH : CuO + H₂ -> Cu + H₂O

             0,2        0,2     0,2   

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

\(m_{H_2\left(dư\right)}=\left(0,5-0,2\right).2=0,6\left(g\right)\)