a) ko bik ....

b) 13,5

c)2

d)2,4

Đáp án B

Đáp án B

Dung dịch sau khi trộn có pH =7 ⇒ n_OH- = n_H+

⇒ 2a.0,1 + 0,2.0,1 = 0,5.0,12 + 0,25.2.0,12

⇒ a = 0,5

Đáp án B.

HCl+NaOH->NaCl+H2O

n HCl=0,02 mol

n NaOH=0,01 mol

=>HCl dư

=>ph=-log0,01=2 

$n_{Ba^{2+}} = 0,1.0,5 = 0,05 < n_{SO_4^{2-}} = 0,1$ nên $SO_4^{2-}$ dư

$n_{BaSO_4} = n_{Ba^{2+}} = 0,05(mol)$
$m_{BaSO_4} = 0,05.233 = 11,65(gam)$

$n_{OH^-} = 0,1.0,5.2 + 0,1.0,5 = 0,15(mol)$
$n_{H^+} = 0,1.2 = 0,2(mol)$

$H^+ + OH^- \to H_2O$

$n_{H^+\ dư} = 0,2 - 0,15 = 0,05(mol)$

$V_{dd} = 0,1 + 0,1 + 0,1 = 0,3(lít)$

$[H^+] = \dfrac{0,05}{0,3} = \dfrac{1}{6}M$
$pH = -log( \dfrac{1}{6} ) = 0,778$

\(n_{Ba^{2+}}=0.1\cdot0.5=0.05\left(mol\right)\)

\(n_{OH^-}=0.1\cdot0.5\cdot2+0.1\cdot0.5=0.15\left(mol\right)\)

\(n_{H^+}=2\cdot0.1\cdot1=0.2\left(mol\right)\)

\(n_{SO_4^{2-}}=0.1\left(mol\right)\)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

\(0.05.........0.05.............0.05\)

\(SO_4^{2-}dư\)

\(m_{\downarrow}=0.05\cdot233=11.65\left(g\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(0.15.......0.15\)

\(n_{H^+\left(dư\right)}=0.2-0.15=0.05\left(mol\right)\)

\(\left[H^+\right]=\dfrac{0.05}{0.1+0.1+0.1}=\dfrac{1}{6}\)

\(pH=-log\left(\dfrac{1}{6}\right)=0.77\)

\(H^++OH^-\rightarrow H_2O\\ n_{H^+}=0,05\left(mol\right);n_{OH^-}=0,07\left(mol\right)\\ Lậptỉlệ:\dfrac{0,05}{1}< \dfrac{0,07}{1}\\ \Rightarrow OH^-dư\\ \left[OH^-_{dư}\right]=\dfrac{0,07-0,05}{0,2}=0,1M\\ \Rightarrow pOH=-log\left(0,1\right)=1\\ \Rightarrow pH=14-1=13\)

a)

$NaOH  + HCl \to NaCl + H_2O$
$OH^- + H^+ \to H_2O$

b)

$n_{HCl} = 0,1.0,01 = 0,001(mol)$
$n_{NaOH} = 0,2.0,5= 0,1(mol)$

$\Rightarrow$ NaOH dư, HCl hết

$n_{NaOH\ pư} = 0,001 \Rightarrow n_{NaOH\ dư} = 0,1 - 0,001 = 0,099(mol)$

$\Rightarrow [OH^-] = \dfrac{0,099}{0,1 + 0,2} = 0,33M$
$\Rightarrow pOH = -log(0,33) = 0,48 $

$pH = 14 - pOH = 14 - 0,48 = 13,52$