Đáp án A

Bài 1:

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b, Giả sử: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

⇒ 65x + 27y = 21,1 (1)

Ta có: \(n_{H_2}=0,65\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y\left(mol\right)\)

\(\Rightarrow x+\dfrac{3}{2}y=0,65\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,2.65}{21,1}.100\%\approx61,6\text{% }\\\%m_{Al}\approx38,4\%\end{matrix}\right.\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,3\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\m_{AlCl_3}=0,3.133,5=40,05\left(g\right)\end{matrix}\right.\)

Bạn tham khảo nhé!

Bài 2: Cu không tác dụng với dd HCl nên cr thu được là Cu.

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)

\(\Rightarrow m_{cr}=m_{Cu}=10-5,6=4,4\left(g\right)\)

Bạn tham khảo nhé!

Bài 3:

PT: \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)

\(2Al+3Cl_2\underrightarrow{t^o}2AlCl_3\)

a, Giả sử: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

⇒ 56x + 27y = 2,2 (1)

Ta có: \(n_{Cl_2}=0,09\left(mol\right)\)

Theo PT: \(n_{Cl_2}=\dfrac{3}{2}n_{Fe}+\dfrac{3}{2}n_{Al}=\dfrac{3}{2}x+\dfrac{3}{2}y\left(mol\right)\)

\(\Rightarrow\dfrac{3}{2}x+\dfrac{3}{2}y=0,09\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,02.56}{2,2}.100\%\approx50,91\%\\\%m_{Al}\approx49,09\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_3}=n_{Fe}=0,02\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,04\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{FeCl_3}=0,02.162,5=3,25\left(g\right)\\m_{AlCl_3}=0,04.133,5=5,34\left(g\right)\end{matrix}\right.\)

Bạn tham khảo nhé!

Thiếu đề bài 

n Fe = 5,6/56 = 0,1 mol

Fe + 2HCl → FeCl2 +  H2

Theo PTHH :

n HCl = 2n Fe = 0,1.2 = 0,2(mol)

=> V dd = V dd HCl = 0,2/2 = 0,1(lít)

n FeCl2 = n Fe = 0,1(mol)

=> CM FeCl2 = 0,1/0,1 = 1M

a) m_hh = 0,2.56+0,3.64 = 30,4 (g)

b) \(m_{H_2SO_4}=0,5.98=49\left(g\right)\)

Bảo toàn e : 

\(n_{Fe}=\dfrac{3n_{NO}+n_{NO_2}}{3}=\dfrac{3\cdot0.1+0.3}{3}=0.2\left(mol\right)\)

\(m_{Fe}=0.2\cdot56=11.2\left(g\right)\rightarrow C\)

a)\(\left\{{}\begin{matrix}Fe:a\left(mol\right)\\Al:b\left(mol\right)\end{matrix}\right.\)⇒ 56a + 27b = 1,93(1)

\(Fe + 2HCl \to FeCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\)

Theo PTHH : a + 1,5b = \(\dfrac{1,456}{22,4} = 0,065\)(2)

Từ (1)(2) suy ra : a = 0,02 ; b = 0,03

Vậy  :

\(\%m_{Fe} = \dfrac{0,02.56}{1,93}.100\% = 58,03\%\\ \%m_{Al} = 100\% - 58,03\% = 41,97\%\)

b) 

\(C_{M_{FeCl_2}} = \dfrac{0,02}{0,2} = 0,1M\\ C_{M_{AlCl_3}} = \dfrac{0,03}{0,2} = 0,15M\)

c)

\(n_{HCl} = 2n_{H_2} = 0,065.2 = 0,13(mol)\\ a = \dfrac{0,13}{0,2} = 0,65(M)\)

mn thêm vào đề bài giúp mình là hỗn hợp gồm 1,93g Fe,Al nha