a) \(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

                 0,1-------->0,2------------->0,2

=> \(V_{dd.CH_3COOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

b) \(m_{CH_3COONa}=0,2.82=16,4\left(g\right)\)

\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ ---> 2CH₃COONa + CO₂ + H₂O

                0,6                  0,3                  0,6                  0,3 

=> V_CO2 = 0,3.22,4 = 6,72 (l)

\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)

=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)

m_CO2 = 0,3.44 = 13,2 (g)

\(m_{dd}=150+150-13,2=286,8\left(g\right)\)

\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)

a) \(n_{CH_3COOH}=0,1.0,3=0,03\left(mol\right)\)

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                  0,03---->0,03--------->0,03

=> \(V_{dd.NaOH}=\dfrac{0,03}{1,5}=0,02\left(l\right)\)

b) m_CH3COONa = 0,03.82 = 2,46 (g)

c) \(C_{M\left(CH_3COONa\right)}=\dfrac{0,03}{0,1+0,02}=0,25M\)

\(nCuO=\dfrac{80}{80}=1\left(mol\right)\)

\(CuO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Cu+H_2O\)

1             2                            1                        1

\(m_{\left(muối\right)}=1.182=182\left(g\right)\)

\(mCH_3COOH=2.60=120\left(g\right)\)

sao có 100g dd axit mà tới 120g CH3COOH ta

\(nCuO=\dfrac{80}{80}=1\left(mol\right)\)

\(2CH_3COOH+CuO\rightarrow\left(CH_3COO\right)_2Cu+H_2O\)

     2                     1                1                        1  (mol)

\(mCH_3COOH=2.60=120\left(g\right)\)

m muối = \(m\left(CH_3COO\right)_2Cu=1.182=182\left(g\right)\)

m H2O = 1.18 = 18 (g)

mdd = mddCH3COOH + m(CH3COO)2Cu + mH2O - mCuO

        = 100   + 182 + 18 - 80 = 220 (g)

\(C\%_{ddCH_3COOH}=\dfrac{120.100}{220}=54,55\%\)

a) \(n_{CuO}=\dfrac{80}{80}=1\left(mol\right)\)

PTHH: CuO + 2CH₃COOH ---> (CH₃COO)₂Cu + H₂O

              1---->2--------------------->1

=> m_muối = 1.182 = 182 (g)

b) \(C\%_{CH_3COOH}=\dfrac{60.2}{100}.100\%=120\%\) đề có sai không vậy bạn ?

$a\big)$

$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$

$CH_3COOH+NaOH\to CH_3COONa+H_2O$

Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$

$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$

$b\big)$

$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$

$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$

Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$

$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$

\(m_{CH_3COOH}=12\%.100=12\left(g\right)\\ n_{CH_3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)

PTHH: CH₃COOH + NaOH ---> CH₃COONa + H₂O

               0,2--------->0,2------------>0,2

\(m_{NaOH}=0,2.40=8\left(g\right)\\ m_{ddNaOH}=\dfrac{8}{8,4\%}=\dfrac{2000}{21}\left(g\right)\\ m_{ddCH_3COONa}=\dfrac{2000}{21}+100=\dfrac{4100}{21}\left(g\right)\\ m_{CH_3COONa}=0,2.82=16,4\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{16,4}{\dfrac{4100}{21}}.100\%=8,4\%\)

`=>` Gợi ý:

`CH3COOH + NaHCO3 => CH3COONa + CO2 + H2O`

`m<sub>CH3COOH</sub> = 100x12/100 = 12` (g)

`==> n<sub>CH3COOH</sub> = m/M = 12/60 = 0.2` (mol)

Theo pt: `=> n<sub>NaHCO3</sub> = 0.2` (mol)

`==> m<sub>NaHCO3</sub> = n.M = 0.2x84 =16.8` (g)

`==> m<sub>dd NaHCO3</sub> = 16.8x100/8.4 = 200` (g)

Ta có: `n<sub>CH3COONa</sub> = 0.2` (mol)

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)

a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)

\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)

Ta có: m _{dd sau pư} = 5,6 + 120 - 0,1.2 = 125,4 (g)

\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)

a, \(n_{KOH}=\dfrac{8,4}{56}=0,15\left(mol\right)\)

PT: \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

Theo PT: \(n_{CH_3COOH}=n_{KOH}=0,15\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\)

b, \(n_{Na_2CO_3}=0,2.0,5=0,1\left(mol\right)\)

PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)

Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,1}{1}\), ta được Na₂CO₃ dư.

Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{CH_3COOH}=0,075\left(mol\right)\Rightarrow V_{CO_2}=0,075.22,4=1,68\left(l\right)\)