a) 

C₂H₄ + Br₂ --> C₂H₄Br₂

C₂H₂ + 2Br₂ --> C₂H₂Br₄

b) Gọi số mol C₂H₄, C₂H₂ là a, b (mol)

=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)

PTHH: C₂H₄ + Br₂ --> C₂H₄Br₂

                a---->a

             C₂H₂ + 2Br₂ --> C₂H₂Br₄

                b---->2b

=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)

(1)(2) => a = 0,3 (mol); b = 0,2 (mol)

\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)

a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

             0,04<--0,04

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)

b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)

PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)

              0,56----------->0,56

            \(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)

              0,04----------->0,08

\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)

a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\left(1\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{48}{160}=0,3\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,2.22,4}{5,6}.100\%=80\%\\\%V_{C_2H_2}=20\%\end{matrix}\right.\)

b, \(V_{ddBr_2}=\dfrac{0,3}{0,25}=1,2\left(M\right)\)

Đáp án: B

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{8}{160}=0,05\left(mol\right)\) (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,55\\n_{C_2H_2}=-0,25\end{matrix}\right.\)

Đến đây thì ra số mol âm, bạn xem lại đề nhé.

1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)

2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)

\(\Rightarrow\%V_{CH_4}=100-80=20\%\)

\(n_{Br_2}=\dfrac{32}{160}=0,2mol\Rightarrow n_{etilen}=0,2mol\)

\(n_{hh}=\dfrac{11,2}{22,4}=0,5mol\Rightarrow n_{metan}=0,5-0,2=0,3mol\)

\(\%m_{etilen}=\dfrac{0,2\cdot28}{0,2\cdot18+0,3\cdot16}\cdot100\%=53,85\%\)

\(\%m_{metan}=100\%-53,85\%=46,15\%\)

a, \(n_{Br_2}=\dfrac{48}{160}=0,3\left(mol\right)\)

PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

_____0,15____0,3 (mol)

\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,15.22,4}{11,2}.100\%=30\%\)

\(\Rightarrow\%V_{CH_4}=100-30=70\%\)

b, - Khí thoát ra ngoài là CH₄.

\(V_{CH_4}=11,2.70\%=7,84\left(l\right)\)