Chọn C

Chọn đáp án D

- Theo bài ra \(\Rightarrow\left\{{}\begin{matrix}n_{KMnO_4}=0,1\\n_{KClO_3}=0,15\end{matrix}\right.\) ( mol )

\(2KMnO_4+16HCl\rightarrow2KCl+2MnCl_2+5Cl_2+8H_2O\)

.......0,1..........................................................0,25...........

\(KClO_3+6HCl\rightarrow KCl+3Cl_2+3H_2O\)

....0,15................................0,45....................

\(\Rightarrow n_{HCl}=0,7\left(mol\right)\)

\(6KOH+3Cl_2\rightarrow KClO_3+5KCl+3H_2O\)

Ta có : \(m=m_{KOH}+m_{Cl_2}=139,3\left(g\right)\)

Vậy ...

\(a,2KMnO_4+16HCl_{đặc}\rightarrow\left(t^o\right)2KCl+2MnCl_2+5Cl_2+8H_2O\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ Ta.có:n_{FeCl_3}=\dfrac{39}{162,5}=0,24\left(mol\right)\\ n_{Fe}=n_{FeCl_3}=0,24\left(mol\right)\\ n_{Cl_2}=\dfrac{3}{2}.0,24=0,36\left(mol\right)\\ n_{K_2MnO_4}=\dfrac{2}{5}.0,36=0,144\left(mol\right)\\ n_{HCl}=\dfrac{16}{5}.0.36=1,152\left(mol\right)\\ \Rightarrow a=m_{KMnO_4}=0,144.158=22,752\left(g\right)\\ b=C_{MddHCl}=\dfrac{1,152}{0,1}=11,52\left(M\right)\\ x=m_{Fe}=0,24.56=13,44\left(g\right)\\ V=V_{Cl_2\left(đktc\right)}=0,36.22,4=8,064\left(l\right) \)

\(b,n_{KCl}=n_{MnCl_2}=\dfrac{2}{5}.0,36=0,144\left(mol\right)\\ KCl+AgNO_3\rightarrow AgCl\downarrow\left(trắng\right)+KNO_3\\ MnCl_2+2AgNO_3\rightarrow2AgCl\downarrow\left(trắng\right)+Mn\left(NO_3\right)_2\\ n_{AgNO_3}=n_{AgCl}=n_{KCl}+2.n_{MnCl_2}=0,144+2.0,144=0,432\left(mol\right)\\ \Rightarrow m_{AgCl\downarrow\left(trắng\right)}=143,5.0,432=61,992\left(g\right)\\ m_{AgNO_3}=0,432.170=73,44\left(g\right)\\ \Rightarrow m_{ddAgNO_3}=\dfrac{73,44.100}{5}=1468,8\left(g\right)\)

\(Fe^{2+} \to Fe^{3+} + 1e\\ Mn^{+7} + 5e \to Mn^{2+}\\ \Rightarrow n_{Fe^{2+}} = 5n_{KMnO_4} = 0,18.5 =0,9(mol)\\ 2FeCl_3 + Fe \to 3FeCl_2\\ n_{FeCl_3} = \dfrac{2}{3}n_{FeCl_2} = 0,6(mol)\\ n_{Fe\ pư} = \dfrac{1}{3}n_{Fe} = 0,3(mol)\\ \Rightarrow m_{Fe\ trong\ A} = 2,8 + 0,3.56 = 19,6(gam)\\ 2Fe + 3Cl_2 \xrightarrow{t^o} 2FeCl_3\\ n_{Fe} = n_{FeCl_3} = 0,6(mol)\\\)

Phần trăm khối lượng Fe tham gia phản ứng là : \(\dfrac{0,6.56}{0,6.56 + 19,6}.100\% = 63,15\%\)

Đáp án B

Khi cho hỗn hợp Y phản ứng với HCl đặc sẽ xảy ra phản ứng oxi hóa – khử tạo ra Cl₂

Chọn đáp án D