Bảo toàn KL: \(m_{O_2}=m_Y-m_X=5,6-3,68=1,92(g)\)

\(\Rightarrow n_{O_2}=\dfrac{1,92}{32}=0,06(mol)\\ \Rightarrow n_{O(O_2)}=0,12(mol)\\ \Rightarrow n_{oxit}=n_{O(O_2)}=0,012(mol)\\ \Rightarrow n_{H^+}=n_{HCl}=2n_{O(oxit)}=0,24(mol)\\ \Rightarrow V=\dfrac{0,24}{0,5}=0,48(l)\)

Chọn B

B

Đáp án C

• m gam Na + 0,01 mol Al₂(SO₄)₃ → 0,01 mol ↓ Al(OH)₃

• TH1: NaOH hết

2Na + 2H₂O → 2NaOH + H₂↑

6NaOH + Al₂(SO₄)₃ → 2Al(OH)₃↓ + 3Na₂SO₄

n_Na = n_NaOH = 0,01 × 3 = 0,03 mol → m_NaOH = 0,03 × 23 = 0,69 gam.

• TH2: NaOH dư

2Na + 2H₂O → 2NaOH + H₂↑ (*)

6NaOH + Al₂(SO₄)₃ → 2Al(OH)₃↓ + 3Na₂SO₄ (**)

NaOH + Al(OH)₃ → NaAlO₂ + 2H₂O (***)

Theo (**) n_NaOH = 0,01 × 6 = 0,06 mol; n_Al(OH)3 = 0,01 × 2 = 0,02 mol.

Theo (***) n_{Al(OH)3 phản ứng} = 0,02 - 0,01 = 0,01 mol

→ n_NaOH = 0,01 mol

→ ∑n_NaOH = 0,06 + 0,01 = 0,07 mol

→ m_Na = 0,07 × 23 = 1,61 gam 

Đáp án C

a) \(n_{SO_3}=\dfrac{3,2}{80}=0,04\left(mol\right)\)

PTHH: SO₃ + H₂O --> H₂SO₄

          0,04------------->0,04

=> \(m_{H_2SO_4}=0,04.98=3,92\left(g\right)\)

b) \(n_{Na}=\dfrac{0,69}{23}=0,03\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂

            0,03------------>0,03

           2NaOH + H₂SO₄ --> Na₂SO₄ + 2H₂O

Xét tỉ lệ: \(\dfrac{0,03}{2}< \dfrac{0,04}{1}\)=> NaOH hết, H₂SO₄ dư

2NaOH + H₂SO₄ --> Na₂SO₄ + 2H₂O

0,03------>0,015---->0,015

\(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,015\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,025\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{Na_2SO_4}=0,015.142=2,13\left(g\right)\\m_{H_2SO_4}=0,025.98=2,45\left(g\right)\end{matrix}\right.\)

c) \(n_{Na}=\dfrac{2,07}{23}=0,09\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂

          0,09-------------->0,09

Xét tỉ lệ: \(\dfrac{0,09}{2}>\dfrac{0,04}{1}\) => NaOH dư, H₂SO₄ hết

2NaOH + H₂SO₄ --> Na₂SO₄ + 2H₂O

0,08<-----0,04------>0,04

=> \(\left\{{}\begin{matrix}n_{NaOH\left(dư\right)}=0,01\left(mol\right)\\n_{Na_2SO_4}=0,04\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{NaOH\left(dư\right)}=0,01.40=0,4\left(g\right)\\m_{Na_2SO_4}=0,04.142=5,68\left(g\right)\end{matrix}\right.\)

Al2(SO4)3 +6NaOH---->2Al(OH)3 +3Na2SO4(1)

Al(OH)3 +NaOH----->NaAlO2 +2H2O(2)

Ta có

n\(_{Al2\left(SO4\right)3}=0,05.0,1=0,005\left(mol\right)\)

Theo pthh1

n\(_{Al\left(OH\right)3}=2n_{Al2\left(SO4\right)3}=0,01\left(mol\right)\)

Mà n\(_{Al\left(OH\right)3}=\frac{0,78}{78}=0,01\left(mol\right)\)

=> NaOH dư

Theo pthh

n\(_{NaOH}=6n_{Al2\left(SO4\right)3}=0,06\left(mol\right)\)

V\(_{NaOH}=\frac{0,06}{0,2}=0,3\left(M\right)\)

Chúc bạn học tốt

Chọn đáp án D

Đáp án B