\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\) 
          0,1           0,2            0,1      0,1 
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\ V_{H_2}=0,1.22,4=2,24l\\ m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)  
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ pthh:Mg+2HCl\rightarrow MgCl_2+H_2\) 
          0,2             0,4       0,2              0,2 
\(m_{HCl}=0,4.36,5=14,6g\\ V_{H_2}=0,2.22,4=4,48l\\ m\text{dd}=4,8+200-0,4=204,4g\\ C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)

Gọi x là số mol của Al, Zn

n_H2 = \(\dfrac{13,44}{22,4}=0,6\) mol

Pt: 2Al + 6HCl --> 2AlCl₃ + 3H₂

......x........................................1,5x

.....Zn + 2HCl --> ZnCl₂ + H₂

......x....................................x

Ta có: 1,5x + x = 0,6

=> x = 0,24

m_hh = 0,24 . (27 + 65) = 22,08 (g)

Theo pt ta có: n_HCl = 2n_H2 = 2 . 0,6 = 1,2 mol

m_HCl = 1,2 . 36,5 = 43,8 (g)

a) Sửa đề: dd H₂SO₄ 9,8%

Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)

Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)

\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)

b) Tương tự câu a

\(Zn+2HCl->ZnCl_2+H_2\\ Mg+2HCl->MgCl_2+H_2\\ n_{Zn}=a\\ n_{Mg}=b\\ 65a+24b=11,3g\\ n_{H_2}=a+b=\dfrac{6,72}{22,4}=0,3\\ a=0,1\\ m_{Zn}=65.0,1=6,5g\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

Ta có: \(n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=1\left(mol\right)\\n_{H_2}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{1\cdot36,5}{20\%}=182,5\left(g\right)\\V_{H_2}=0,5\cdot22,4=11,2\left(l\right)\end{matrix}\right.\)

a) n H2 = 15,68/22,4 = 0,7(mol)

$Zn + 2HCl \to ZnCl_2 + H_2$
$Fe + 2HCl \to FeCl_2 + H_2$

Theo PTHH : nHCl = 2n H2 = 1,4(mol)

=> CM HCl = 1,4/2 = 0,7M

b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)

n H2 = a + b = 0,7(2)

Từ (1)(2) suy ra a = 0,5 ; b = 0,2

Suy ra:

m Zn = 0,5.65 = 32,5 gam

m Fe = 0,2.56 = 11,2 gam

a) n H2 = 15,68/22,4 = 0,7(mol)

Theo PTHH : nHCl = 2n H2 = 1,4(mol)

=> CM HCl = 1,4/2 = 0,7M

b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)

n H2 = a + b = 0,7(2)

Từ (1)(2) suy ra a = 0,5 ; b = 0,2

Suy ra:

m Zn = 0,5.65 = 32,5 gam

m Fe = 0,2.56 = 11,2 gam

Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)

\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)

\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)

Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow ka+kb+kc=0,2\)

\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)

\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)

\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)

Xét thương:

 \(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)

\(\Rightarrow3a-b-c=0\left(3\right)\)

Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl ---> ZnCl₂ + H₂

           0,2<--0,4<------0,2<-----0,2

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,2.65}{21,1}.100\%=61,61\%\\\%m_{ZnO}=100\%-61,61\%=38,39\%\end{matrix}\right.\)

\(n_{ZnO}=\dfrac{21,1-0,2.65}{81}=0,1\left(mol\right)\)

PTHH: ZnO + 2HCl ---> ZnCl₂ + H₂O

            0,1---->0,2------>0,1

=> \(C\%_{HCl}=\dfrac{\left(0,2+0,4\right).36,5}{200}.100\%=10,95\%\)

\(m_{mu\text{ố}i}=m_{ZnCl_2}=\left(0,1+0,2\right).136=40,8\left(g\right)\)