CuO + 2HCl -> CuCl₂ + H₂O (1)

Fe₂O₃ + 6HCl -> 2FeCl₃ + 3H₂O (2)

n_HCl=0,2.3,5=0,7(mol)

Đặt n_CuO=a

n_Fe2O3=b

Ta có hệ:

80a+160b=20

2a+6b=0,7

=>a=0,05;b=0,1

m_CuO=80.0,05=4(g)

m_Fe2O3=20-4=16(g)

Theo PTHH 1 và 2 ta có:

n_CuCl2=n_CuO=0,05(mol)

n_FeCl3=2n_Fe2O3=0,2(mol)

m_CuCl2=135.0,05=6,75(g)

m_FeCl3=162,5.0,2=32,5(g)

m_dd =20+200.1,1=240(g)

C% dd CuCl₂=6,72\240 .100%=2,8125%

C% dd FeCl₃= 32,5\240 .100%=13,54%

a, PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)

Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{FeO}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 72y = 11,2 (1)

Ta có: \(n_{H_2SO_4}=0,15.1=0,15\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{CuO}+n_{FeO}=x+y=0,15\left(2\right)\)

Từ (1) và (2) ⇒ x = 0,05 (mol), y = 0,1 (mol)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,05.80}{11,2}.100\%\approx35,71\%\\\%m_{FeO}\approx64,28\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{CuSO_4}=n_{Cu}=0,05\left(mol\right)\\n_{FeSO_4}=n_{FeO}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{CuSO_4}}=\dfrac{0,05}{0,15}=\dfrac{1}{3}\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\end{matrix}\right.\)

a) Đặt nAl=a(mol) ; nFe=b(mol) (a,b>0)

nHCl= (365.12%)/36,5=1,2(mol)

PTHH: 2Al + 6 HCl -> 2AlCl3 +3 H2

a________3a_________2a____1,5a(mol)

Fe + 2 HCl -> FeCl2 + H2

b_____2b____b____b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}27a+56b=22,2\\3a+2b=1,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)

b) => %mAl= [(0,2.27)/22,2].100=24,324%

=>%mFe= 75,676%

c) mFeCl2=127. 0,3=38,1(g)

mAlCl3= 133,5. 0,2= 26,7(g)

mddsau= 22,2+365 - 1,2.2=384,8(g)

=>C%ddFeCl2= (38,1/384,8).100=9,901%

C%ddAlCl3= (26,7/384,8).100=6,939%

a/ Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

n_H2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PTHH: n_H2 = n_Fe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)

\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)

\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)

\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)

b/ Theo PTHH ta có: n_HCl = 2n_Fe = 2.0,15 = 0,3 (mol)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)

c/ m_HCl = 36,5 . 0,3 = 10,95(g)

\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)

b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)

c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)