PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Theo bài ra, ta có: \(\dfrac{1}{2}\Sigma m_{Cu}=3,2\left(g\right)\) \(\Rightarrow m_{Cu}=6,4\left(g\right)\)

\(\Rightarrow\%m_{Cu}=\dfrac{6,4}{17,2}\cdot100\%\approx37,21\%\) \(\Rightarrow\%m_{Al}=62,79\%\)

Theo PTHH: \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot\dfrac{\dfrac{17,2-6,4}{2}}{27}=0,3\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)

a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

b) Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\) \(\Rightarrow n_{Al}=0,1mol\)

\(\Rightarrow\%m_{Al}=\dfrac{0,1\cdot27}{5}\cdot100\%=54\%\) \(\Rightarrow\%m_{Cu}=46\%\)

a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{4}{15}\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{\dfrac{4}{15}.27}{10}.100\%=72\%\\\%m_{Cu}=28\%\end{matrix}\right.\)

c, Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)

\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{300}.100\%\approx13,067\%\)

Theo đề bài cho, bột S dư nên Fe và Zn tác dụng hết với S.

Phương trình hóa học của phản ứng:

Zn + S → ZnS

Fe + S → FeS

ZnS + H2SO4 → ZnSO4 + H2S

FeS + H2SO4 → H2S + FeSO4

Câu 1:

Đặt \(n_{Al}=x(mol);n_{Fe}=y(mol)\Rightarrow 27x+56y=0,83(1)\)

\(n_{H_2}=\dfrac{0,56}{22,4}=0,025(mol)\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow 1,5x+y=0,025(2)\\ (1)(2)\Rightarrow x=y=0,01(mol)\\ \Rightarrow \%_{Al}=\dfrac{0,01.27}{0,83}.100\%=32,53\%\\ \Rightarrow \%_{Fe}=100\%-32,53\%=67,47\%\)

Câu 2:

Đặt \(n_{Al}=x(mol);n_{Mg}=y(mol)\Rightarrow 27x+24y=4,5(1)\)

\(n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Mg+H_2SO_4\to MgSO_4+H_2\\ \Rightarrow 1,5x+y=0,225(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,075(mol)\\ \Rightarrow \%_{Al}=\dfrac{0,1.27}{4,5}.100\%=60\%\\ \Rightarrow \%_{Mg}=100\%-60\%=40\%\)

Dạng PP hai dòng:

\(PTHH:2A+Cl_2\to 2ACl\\ \Rightarrow n_A=n_{ACl}\\ \Rightarrow \dfrac{9,2}{M_A}=\dfrac{23,4}{M_A+35,5}\\ \Rightarrow M_A=23(g/mol)\)

Vậy A là natri

a) PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2

x___________3x______________1,5x(mol)

Fe +2 HCl -> FeCl2 + H2

y___2y____y______y(mol)

b) Ta có: m(rắn)= mCu=0,4(g)

=> m(Al, Fe)=1,5-mCu=1,5-0,4=1,1(g)

nH2= 0,04(mol)

Ta lập hpt:

\(\left\{{}\begin{matrix}27x+56y=1,1\\1,5x+y=0,04\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

=> mAl=27.0,02=0,54(g)

mFe=56.0,01=0,56(g)

TN1: Gọi (n_Cu, n_Al, n_Fe) = (a,b,c)

=> 64a + 27b + 56c = 14,3 (1)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

             b----------------------->1,5b

            Fe + 2HCl --> FeCl₂ + H₂

              c----------------------->c

=> 1,5b + c = 0,3 (2)

TN2: Gọi (n_Cu, n_Al, n_Fe) = (ak,bk,ck)

=> ak + bk + ck = 0,6 (3)

\(n_{O_2}=\dfrac{44,8}{22,4}.20\%=0,4\left(mol\right)\)

PTHH: 2Cu + O₂ --t^o--> 2CuO

            ak--->0,5ak

            4Al + 3O₂ --t^o--> 2Al₂O₃

           bk--->0,75bk

            3Fe + 2O₂ --t^o--> Fe₃O₄

           ck-->\(\dfrac{2}{3}ck\)

=> 0,5ak + 0,75bk + \(\dfrac{2}{3}ck\) = 0,4 (4)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,05\left(mol\right)\\b=0,1\left(mol\right)\\c=0,15\left(mol\right)\\k=2\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,05.64}{14,3}.100\%=22,38\%\\\%m_{Al}=\dfrac{0,1.27}{14,3}.100\%=18,88\%\\\%m_{Fe}=\dfrac{0,15.56}{14,3}.100\%=58,74\%\end{matrix}\right.\)