.

a.250ml=0,25l ; nHCl=0,25.1,5=0,375mol

KOH+HCl->KCl+H2O

1mol 1mol 1mol

0,375 0,375 0,375

VKOh=0,375/2=0,1875l

b.CM KCL=0,375/0,25=1,5M

c.NaOH+HCL=NaCl+H2O

1mol 1mol

0,375 0,375

mdd NaOH=0,375.40.100/10=150g

n_HCl = C_M . V = 1,5 . 0,25 = 0,375 mol

PTHH: KOH + HCl -------> KCl + H₂O

Pt: 1 1 1 1 (mol)

Pư 0,375 <-0,375 -----> 0,375-> 0,375 (mol)

a) V_KOH = \(\dfrac{n}{C_M}\)= 0,1875 l

b) C_M KCl = \(\dfrac{n}{V}\)= \(\dfrac{0,375}{0,25+0,1875}\)\(\approx\)0,86 M

c) PTHH: NaOH + HCL ----> NaCl + H₂O

Pt: 1 1 1 1 (mol)

Pư 0,375 <- 0,375 ------>0,375 --> 0,375 (mol)

m_ctNaOH = n . M = 15 g

m_{ddNaOH = \(\dfrac{15.100\%}{10\%}\)=} 150 g

:3

\(a/KOH+HCl\rightarrow KCl+H_2O\\ n_{HCl}=0,25.1,5=0,375mol\\ n_{KOH}=n_{KCl}=n_{HCl}=0,375mol\\ V_{KOH}=\dfrac{0,375}{2}=0,1875l\\ b/C_{M_{KCl}}=\dfrac{0,375}{0,1875+0,25}=\dfrac{6}{7}M\)

Bài 1:

Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)

BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)

Theo ĐL BTKL, có: m _oxit + m_HCl = m_muối + m_H2O

⇒ m_muối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)

Bài 2:

\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)

Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)

\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)

Bài 3:

Ta có: \(C\%_{NaCl}=\dfrac{m_{NaCl}}{m_{NaCl}+m_{H_2O}}.100\%=32\%\)

\(\Rightarrow\dfrac{m_{NaCl}}{m_{NaCl}+200}=0,32\)

\(\Rightarrow m_{NaCl}\approx94,12\left(g\right)\)

Bài 4:

Ta có: \(n_{CaCO_3}=\dfrac{15}{100}=0,15\left(mol\right)\)

PT: \(CaCO_3\underrightarrow{t^o}CaO+CO_2\)

Theo PT: \(n_{CaO\left(LT\right)}=n_{CaCO_3}=0,15\left(mol\right)\)

\(\Rightarrow m_{CaO\left(LT\right)}=0,15.56=8,4\left(g\right)\)

\(\Rightarrow H=\dfrac{6,72}{8,4}.100\%=80\%\)

\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)

\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)

\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)

\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)