nCaCl2=0.02(mol)

nAgNO3=0.01(mol)

CaCl2+2AgNO3->Ca(NO3)2+2AgCl

Theo pthh nAgNO3=2nCaCl2

Theo bài ra nAgNO3=0.5 nCaCl2

->CaCl2 dư tính theo AgNO3

nAgCl=nAgNO3->nAgCl2=0.01(mol)

mAgCl2=1.435(g)

nCaCl2 phản ứng:0.005(mol)

nCaCl2 dư=0.02-0.005=0.015(mol)->CM=0.015:(0.03+0.07)=0.15M

nCa(NO3)2=0.005(mol)->CM=0.005:(0.03+0.07)=0.05M

a)PTHH:     AgNO₃  + HCl → AgCl↓ + HNO₃ 

nHCl = 0,2.0,5 = 0,1 mol 

=> nAgCl = 0,1 mol  = nAgNO₃ = 0,1 mol  = nHCl phản ứng 

<=> mAgCl = 0,1.143,5 = 14,35 gam

mAgNO₃ = 0,1.170  = 17 gam

=> mdd AgNO₃  = \(\dfrac{17}{6,8\%}\)= 250 gam

b)    X +    2HCl --> XCl₂   + H₂ 

1,2 gam X tác dụng vừa đủ với 0,1 mol HCl

=> Số mol của 1,2 gam X = 0,05 mol

<=> M_x = \(\dfrac{1,2}{0,05}\)= 24  (g/mol)   =>   X là magie ( Mg )

PTHH: \(HCl+AgNO_3\rightarrow HNO_3+AgCl\downarrow\)

Hiện tượng: Xuất hiện kết tủa trắng

Ta có: \(n_{AgNO_3}=\dfrac{170\cdot10\%}{170}=0,1\left(mol\right)=n_{HCl}=n_{HNO_3}=n_{AgCl}\)

\(\Rightarrow\left\{{}\begin{matrix}V_{ddHCl}=\dfrac{0,1}{1}=0,1\left(l\right)=100\left(ml\right)\\m_{ddHCl}=100\cdot1,05=105\left(g\right)\\m_{AgCl}=0,1\cdot143,5=14,35\left(g\right)\\m_{HNO_3}=0,1\cdot63=6,3\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddHCl}+m_{ddAgNO_3}-m_{AgCl}=260,65\left(g\right)\) \(\Rightarrow C\%_{HNO_3}=\dfrac{6,3}{260,65}\cdot100\%\approx2,42\%\)

a.

b. 

\(a,PTHH:CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\\ Cu\left(OH\right)_2\rightarrow^{t^0}CuO+H_2O\\ b,n_{CuCl_2}=n_{Cu\left(OH\right)_2}=n_{CuO}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\\ c,n_{NaCl}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{23,4}{200}\cdot100\%=11,7\%\)

PTHH: \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl\downarrow\)

Ta có: \(n_{NaCl}=0,2\cdot0,5=0,1\left(mol\right)=n_{AgNO_3}=n_{AgCl}\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{AgNO_3}}=\dfrac{0,1}{0,4}=0,25\left(M\right)\\m_{AgCl}=0,1\cdot143,5=14,35\left(g\right)\end{matrix}\right.\)

PTHH: \(Na_2SO_4+CaCl_2\rightarrow2NaCl+CaSO_4\downarrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Na_2SO_4}=0,1\cdot0,5=0,05\left(mol\right)\\n_{CaCl_2}=0,1\cdot0,4=0,04\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Na₂SO₄ dư

\(\Rightarrow\left\{{}\begin{matrix}n_{CaSO_4}=0,04\left(mol\right)\\n_{NaCl}=0,08\left(mol\right)\\n_{Na_2SO_4\left(dư\right)}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaSO_4}=0,04\cdot136=5,44\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,08}{0,1+0,1}=0,4\left(M\right)\\C_{M_{Na_2SO_4\left(dư\right)}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)