a) Gọi số mol Al, Zn là 2a, a (mol)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

          2a-->1,5a---------->a

             2Zn + O₂ --t^o--> 2ZnO

            a---->0,5a------->a

=> \(102a+81a=18,3\)

=> a = 0,1 (mol)

=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,1.65}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{0,2.27+0,1.65}.100\%=54,622\%\end{matrix}\right.\)

b) \(n_{O_2}=1,5a+0,5a=0,2\left(mol\right)\)

=> \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\x_{Ca}=y\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}24x+40y=17,6\\x=2y\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,2\end{matrix}\right.\)

a)\(m_{Mg}=0,4\cdot24=9,6g\)

   \(m_{Ca}=0,2\cdot40=8g\)

b)\(2Mg+O_2\underrightarrow{t^o}2MgO\)

   \(2Ca+O_2\underrightarrow{t^o}2CaO\)

Từ hai pt: \(\Rightarrow\Sigma n_{O_2}=\dfrac{1}{2}n_{Mg}+\dfrac{1}{2}n_{Ca}=\dfrac{1}{2}\cdot0,4+\dfrac{1}{2}\cdot0,2=0,3mol\)

\(\Rightarrow m_{O_2}=0,3\cdot32=9,6g\)

\(V_{O_2}=0,3\cdot22,4=6,72l\)

\(\Rightarrow V_{kk}=5V_{O_2}=5\cdot6,72=33,6l\)

a) 

Có \(\left\{{}\begin{matrix}24.n_{Mg}+40.n_{Ca}=17,6\\n_{Mg}=2.n_{Ca}\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}n_{Ca}=0,2\left(mol\right)\\n_{Mg}=0,4\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{Ca}=0,2.40=8\left(g\right)\\m_{Mg}=0,4.24=9,6\left(g\right)\end{matrix}\right.\)

b)

PTHH: 2Ca + O₂ --t^o--> 2CaO 

            0,2-->0,1

             2Mg + O₂ --t^o--> 2MgO

            0,4--->0,2

=> \(V_{O_2}=\left(0,1+0,2\right).22,4=6,72\left(l\right)\)

\(V_{kk}=6,72.5=33,6\left(l\right)\)

Gọi số mol Al, Na trong a gam hỗn hợp là x, y (mol)

=> 27x + 23y = a (1)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

             x---------------->0,5x

            4Na + O₂ --t^o--> 2Na₂O

              y---------------->0,5y

=> 102.0,5x + 62.0,5y = 1,64.a

=> 51x + 31y = 1,64a (2)

(1)(2) => 51x + 31y = 1,64(27x + 23y)

=> 6,72x = 6,72y

=> x = y

\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{27x}{27x+23y}.100\%=54\%\\\%m_{Na}=\dfrac{23y}{27x+23y}.100\%=46\%\end{matrix}\right.\)

a)

2Mg + O₂ --t^o--> 2MgO

2Zn + O₂ --t^o--> 2ZnO

b)

Gọi số mol Mg, Zn là a, b (mol)

=> 24a + 65b = 23,3 (1)

PTHH: 2Mg + O₂ --t^o--> 2MgO

               a-->0,5a------>a

            2Zn + O₂ --t^o--> 2ZnO

               b-->0,5b------>b

=> 40a + 81b = 36,1 (2)

(1)(2) => a = 0,7 (mol); b = 0,1 (mol)

\(n_{O_2}=0,5a+0,5b=0,4\left(mol\right)\)

=> \(V_{O_2}=0,4.22,4=8,96\left(l\right)\)

c) 

m_Mg = 0,7.24 = 16,8 (g)

m_Zn = 0,1.65 = 6,5 (g)

Ta có : 

$m_{O_2\ pư} = m_{tăng} = 4(gam) \Rightarrow n_{O_2} = \dfrac{4}{32} = 0,125(mol)$
Gọi $n_{Mg} = n_{Al} = a(mol)$
$2Mg + O_2 \xrightarrow{t^o} 2MgO$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$

Theo PTHH : $n_{O_2} = 0,5a + 0,75a = 0,125 \Rightarrow a = 0,1(mol)$
$\Rightarrow m = 0,1.24 + 0,1.27 = 5,1(gam)$

THAM KHẢO:

Gọi số mol Mg và Zn lần lượt là x, y

Ta có 24x + 65y=23.3

     40x + 81y=36.1

=) x=0.7

    y= 0.1

b)

c)

\(a,2Mg+O_2\rightarrow\left(t^o\right)2MgO\\ 2Zn+O_2\rightarrow\left(t^o\right)2ZnO\\ b,n_{O_2}=\dfrac{36,1-23,3}{32}=0,4\left(mol\right)\\ V_{O_2\left(\text{đ}ktc\right)}=0,4.22,4=8,96\left(l\right)\\ \text{Đ}\text{ặt}:a=n_{Mg};b=n_{Zn}\left(a,b>0\right)\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}24a+65b=23,3\\0,5a+0,5b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,7\\b=0,1\end{matrix}\right.\\ c,m_{Mg}=24a=24.0,7=16,8\left(g\right)\\ m_{Zn}=65b=65.0,1=6,5\left(g\right)\)

Theo ĐLBT KL, có: m_KL + m_O2 = m _oxit

⇒ m_O2 = 13,1 - 1,5 = 11,6 (g)

Bài 9 : 

a) $2xM + yO_2 \xrightarrow{t^o} 2M_xO_y$

Theo PTHH : 

$\dfrac{M}{4,2}.\dfrac{1}{x} = \dfrac{5,8}{Mx + 16y}$

$\Rightarrow Mx = 42y$

Với x = 3 ; y = 4 thì M = 56(Fe)

b) Vậy oxi là $Fe_3O_4$(oxit sắt từ)

Bài 10 : 

Gọi $n_C = a(mol) ; n_S = b(mol) \Rightarrow 12a + 32b = 17(1)$

$C + O_2 \xrightarrow{t^o} CO_2$
$S + O_2 \xrightarrow{t^o} SO_2$
$n_{O_2} = a + b = \dfrac{16,8}{22,4} = 0,75(2)$

Từ (1)(2) suy ra : $a = 0,35 ; b = 0,4$

$\%V_{CO_2} = \dfrac{0,35}{0,35 + 0,4}.100\% = 46,67\%$

$\%V_{SO_2} = 100\% -46,67\% = 53,33\%$