Gọi x, y lần lượt là số mol của Cu và Fe.

Ta có: \(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

a. PTHH: 2Cu + O₂ ---t^o---> 2CuO (1)

3Fe + 2O₂ ---t^o---> Fe₃O₄ (2)

Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Theo PT₍₁₎: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\)

Theo PT₍₁₎: \(n_{O_2}=\dfrac{1}{2}.n_{Cu}=\dfrac{1}{2}x\left(mol\right)\)

Theo PT₍₂₎: \(n_{O_2}=\dfrac{2}{3}.n_{Fe}=\dfrac{2}{3}y\left(mol\right)\)

=> \(\dfrac{1}{2}x+\dfrac{2}{3}y=0,3\)

Mà n_Cu = 0,2(mol)

Thay vào, ta được: \(\dfrac{1}{2}.0,2+\dfrac{2}{3}y=0,3\)

=> y = 0,3(mol)

=> \(m_{Cu}=0,2.64=12,8\left(g\right)\)

\(m_{Fe}=0,3.56=16,8\left(g\right)\)

b. \(\%_{Cu}=\dfrac{12,8}{12,8+16,8}.100\%=43,24\%\)

\(\%_{Fe}=100\%-43,24\%=56,76\%\)

\(a)n_{KMnO_4} = a; n_{KClO_3} = b\Rightarrow 158a + 122,5b = 99,95(1)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{O_2} = 0,5a +1,5b = \dfrac{14,56}{22,4}=0,65(2)\\ (1)(2)\Rightarrow a = 0,4 ; b = 0,3\\ \%m_{KMnO_4} = \dfrac{0,4.158}{99,95}.100\% = 63,23\%\\ \%m_{KClO_3} = 100\%-63,23\% = 36,77\%\)

\(n_{K_2MnO_4} = n_{MnO_2} = 0,5a = 0,2(mol)\\ n_{KClO_3} = b = 0,3(mol)\\ m_{hh\ sau\ pư} = 99,95 - 0,65.32 = 79,15(gam)\\ \%m_{K_2MnO_4} = \dfrac{0,2.197}{79,15}.100\% = 49,78\%\\ \%m_{MnO_2} = \dfrac{0,2.87}{79,15},100\% = 21,98\%\\ \%m_{KCl} = 28,24\%\)

ko khó lém bn ơi có câu nèo easy hơm ko

Đáp án A

Hỗn hợp rắn gồm Al, Al₂O₃, Fe với n Fe = 2 n Al 2 O 3 . Chia thành 2 phần không bằng nhau:

2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2

0,4-----------------0,2----------------------------------------0,2

2CH3COOH+CaO->(CH3COO)2Ca+H2O

0,1----------------0,05

n CO2=0,2 mol

=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)

=>%m CaO=12,28%

=>n CaO=0,05 mol

=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)

a)

\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: CaCO₃ + 2CH₃COOH --> (CH₃COO)₂Ca + CO₂ + H₂O

                0,2<---------0,4<------------------------------0,2

=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)

=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)

b)

\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)

PTHH: CaO + 2CH₃COOH --> (CH₃COO)₂Ca + H₂O

            0,05---->0,1

=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)

c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đ),t^o--> CH₃COOC₂H₅ + H₂O

Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH₃COOH

\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)

=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)