PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(1\right)\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}+n_{C_2H_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,01\left(mol\right)\\n_{C_2H_2}=0,015\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,01.22,4}{0,56}.100\%=40\%\\\%V_{C_2H_2}=60\%\end{matrix}\right.\)

ta có :

nBr2=\(\dfrac{16}{160}=0,1mol\)

C2H4+Br2->C2H4Br2

0,1------0,1

=>VC2H4=0,1.22,4=2,24l

=>VCH4=3,36l->n CH4=0,15 mol

->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%

=>%VCH4=60%

c)

CH4+2O2-to>CO2+2H2O

0,15---------------0,15

C2H4+3O2--to>2CO2+2H2O

0,1--------------------0,2
=>m CaCO3=0,35.100=35g

Ta có: \(V_{hhsaupư}=V_{CH_4}=\dfrac{44,8}{5,6}=8\left(l\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{8}{44,8}.100\%\approx17,86\%\\\%V_{C_2H_4}\approx82,14\%\end{matrix}\right.\)

a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

            0,025<-0,125

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)

Tính % thể tích các khí :

% V C 2 H 2  = 0,448/0,896 x 100% = 50%

% V CH 4  = % V C 2 H 6  = 25%

n Br2=\(\dfrac{32}{160}\)=0,2 mol

C2H2+2Br2->C2H2Br4

0,1------0,2 mol

=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%

=>%VCH4=100-40=60%

=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol

CH4+2O2-to>CO2+2H2O

0,15----0,3

C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O

0,1-----0,25 mol

=>VO2=(0,3+0,25).22,4=12,32l