nNaOH=0,025mol

nH2SO4=0,015mol

2NaOH+H2SO4->Na2SO4+2H2O

Ta có 0,025/2 <0,015/1 =>H2SO4 dư

Khi nhúng quì tím vào dd thì quì tím chuyển sang màu đỏ

2NaOH+H2SO4->Na2SO4+2H2O

0,025     0,0125      0,0125

DD X: H2SO4:0,0025mol

Na2SO4: 0,0125mol

C(H2SO4)=0,00625M

C(NaOH)=0,03125M

3. Cần dùng KOH 1M để trung hòa dd X

H2SO4+2KOH->K2SO4+H2O

0,0025    0,005

V(KOH)=n/C=0,005lit=5ml

1) $n_{NaOH} = 0,015(mol) ; n_{H_2SO_4} = 0,025(mol)$
$2NaOH + H_2SO_4 \to Na_2SO_4 + H_2O$

Ta thấy : 

$n_{NaOH} : 2 < n_{H_2SO_4} : 1$ nên $H_2SO_4$ dư

Do đó quỳ tím hóa đỏ.

2)

$n_{Na_2SO_4} = \dfrac{1}{2}n_{NaOH} = 0,0075(mol)$
$n_{H_2SO_4\ dư} = 0,025 - 0,0075 = 0,0175(mol)$

$V_{dd\ X} = 0,15 + 0,25 = 0,4(lít)$

Suy ra : 

$C_{M_{Na_2SO_4}} = \dfrac{0,0075}{0,4} = 0,01875M$
$C_{M_{H_2SO_4\ dư}} = \dfrac{0,0175}{0,4}  = 0,04375M$

3)

$2KOH + H_2SO_4 \to K_2SO_4 + H_2O$
$n_{KOH} = 2n_{H_2SO_4\ dư} = 0,035(mol)$
$V_{dd\ KOH} =\dfrac{0,035}{1} = 0,035(lít)$

nHCl=0,2.0,5=0,1(mol)

nNaOH=0,2.0,3=0,06(mol)

PTHH: NaOH + HCl -> NaCl + H2O

Vì 0,1/1 > 0,06/1

=> NaOH hết, HCl dư

a) Vì HCl dư , NaCl trung tính => dung dịch sau phản ứng làm hóa đỏ quỳ tím.

b) - Dung dịch thu được gồm HCl dư và NaCl.

nHCl(p.ứ)=nNaCl=nNaOH=0,06(mol) -> mNaCl= 0,06.58,5=3,51(g)

nHCl(dư)=0,1-0,06=0,04(mol) -> mHCl(p.ứ)=0,04.36,5=1,46(g)

mddsaup.ứ= mddHCl + mdd NaOH= 200.1,12+300.1,02=530(g)

=> \(C\%ddNaCl=\dfrac{3,51}{530}.100\approx0,662\%\\ C\%ddHCl\left(dư\right)=\dfrac{1,46}{530}.100\approx0,275\%\)

a)

$NaOH + HCl \to NaCl + H_2O$

$n_{HCl} = 0,2.0,5 = 0,1(mol) > n_{NaOH} = 0,3.0,2 = 0,06(mol)$

nên HCl dư

Dung dịch làm quỳ tím hóa đỏ

b)

$m_{dd} = 200.1,12 + 300.1,02 = 510(gam)$
$n_{HCl\ dư} = 0,1 - 0,06 = 0,04(mol)$
$n_{NaCl} = n_{NaOH} = 0,06(mol)$
$C\%_{NaCl} = \dfrac{0,06.58,5}{510}.100\% = 0,69\%$
$C\%_{HCl} = \dfrac{0,04.36,5}{510}.100\% = 0,29\%$

đang cần gấp ai lm đc gúp em trong chiều nay đc ko ạ cảm ơn nhìu nhìu

\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)

\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)

\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)

a) $n_{CaCO_3} = 0,15(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{HCl} = 2n_{CaCO_3} = 0,3(mol)$
$m_{dd\ HCl} = \dfrac{0,3.36,5}{7,3\%} = 150(gam)$

b)

$n_{CaCl_2} = n_{CO_2} = n_{CaCO_3} =0,15(mol)$
$V_{CO_2} = 0,15.22,4 = 3,36(lít)$
c)

$m_{dd} = 15 + 150 - 0,15.44 = 158,4(gam)$

$C\%_{CaCl_2} = \dfrac{0,15.111}{158,4}.100\% = 10,51\%$

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

b+c) Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,3\left(mol\right)\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl}=0,6\cdot36,5=21,9\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\end{matrix}\right.\)

d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) HCl còn dư, NaOH p/ứ hết

\(\Rightarrow\) Dung dịch sau p/ứ làm quỳ tím hóa đỏ

Theo PTHH: \(\left\{{}\begin{matrix}n_{NaCl}=0,5\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,5\cdot58,5=29,25\left(g\right)\\m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddHCl}+m_{NaOH}=\dfrac{0,6\cdot36,5}{5\%}+20=458\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{29,25}{458}\cdot100\%\approx6,39\%\\C\%_{HCl\left(dư\right)}=\dfrac{3,65}{458}\cdot100\%\approx0,8\%\end{matrix}\right.\)