CH4+2O2-to>CO2+2H2O

x-----------------------------2x

C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O

y-----------------------------------y

=>\(\left\{{}\begin{matrix}x+y=\dfrac{3,36}{22,4}\\2x+y=\dfrac{4,5}{18}\end{matrix}\right.\)

=>\(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)

=>%VCH4=\(\dfrac{0,1.22,4}{3,36}\).100=66,67%

=>%VC2H2=100-66,67%=33,33%

b)

C2H2+2Br2->C2H2Br4

0,05-----0,1 mol

=>m Br2=0,1.160=16g

\(n_{hh\left(CH_4,C_2H_4\right)}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right)\\ C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{C_2H_4}=n_{Br_2}=0,025\left(mol\right)\)

Vì số mol tỉ lệ thuận với thể tích, nên ta có:

\(\%n_{C_2H_4}=\dfrac{0,025}{0,25}.100\%=10\%\\ \Rightarrow\%V_{C_2H_4}=10\%;\%V_{CH_4}=100\%-10\%=90\%\)

C2H4+Br2->C2H4Br2

0,05---0,05

n Br2=\(\dfrac{8}{160}\)=0,05 mol

V%C2H4=\(\dfrac{0,5.22,4}{22,4}\).100=5%

=>%CH4=95%

\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)

\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)

\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)

\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)

Dài quá!!!

Dẫn 2 khí qua dung dịch nước brom chỉ có C 2 H 4 phản ứng

Ta có: \(n_{Br_2}=\dfrac{6}{160}=0,0375\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,0375\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,0375.22,4}{6,72}.100\%=12,5\%\\\%V_{CH_4}=87,5\%\end{matrix}\right.\)