a) \(V_{CH_4}=0,6\left(l\right)\)

=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,6}{1,2}.100\%=50\%\\\%V_{C_2H_4}=100\%-50\%=50\%\end{matrix}\right.\)

b) \(n_{C_2H_4}=\dfrac{1,2-0,6}{24}=0,025\left(mol\right)\)

PTHH: C₂H₄ + Br₂ --> C₂H₄Br₂ 

         0,025-->0,025

=> \(m_{Br_2}=0,025.160=4\left(g\right)\)

c) 

\(n_{CH_4}=\dfrac{0,6}{24}=0,025\left(mol\right)\)

=> n_H = 0,025.4 = 0,1 (mol)

\(n_{Cl_2}=\dfrac{0,72}{24}=0,03\left(mol\right)\)

=> n_{Cl(thế H)} = 0,03 (mol)

Do n_H > n_{Cl(thế H)}

=> H không bị thế hoàn toàn bởi Cl

=> n_HCl = 0,03 (mol)

=> m_HCl = 0,03.36,5 = 1,095 (g)

$C_2H_4 + Br_2 \to C_2H_4Br_2$

Ta có : 

$m_{C_2H_4} = m_{dd\ tăng} = 3(gam)$

$\Rightarrow n_{C_2H_4} = \dfrac{3}{28}(mol)$

$\Rightarrow n_{C_2H_6} = 0,25 - \dfrac{3}{28} = \dfrac{1}{7}(mol)$

$\%V_{C_2H_4} = \dfrac{ \dfrac{3}{28} }{0,25}.100\% = 42,9\%4

$\%V_{C_2H_6} = 100\% - 42,9\% = 57,1\%$

$\%m_{C_2H_4} = \dfrac{3}{3 + \dfrac{1}{7}.30}.100\% = 41,2\%$

$\%m_{C_2H_6} = 100\% - 41,2\% = 58,8\%$

$C_2H_4 + Br_2 \to C_2H_4Br_2$

Ta có : 

$m_{C_2H_4} = m_{dd\ tăng} = 3(gam)$

$\Rightarrow n_{C_2H_4} = \dfrac{3}{28}(mol)$

$\Rightarrow n_{C_2H_6} = 0,25 - \dfrac{3}{28} = \dfrac{1}{7}(mol)$

$\%V_{C_2H_4} = \dfrac{ \dfrac{3}{28} }{0,25}.100\% = 42,9\%$

$\%V_{C_2H_6} = 100\% - 42,9\% = 57,1\%$

$\%m_{C_2H_4} = \dfrac{3}{3 + \dfrac{1}{7}.30}.100\% = 41,2\%$

$\%m_{C_2H_6} = 100\% - 41,2\% = 58,8\%$

B

B5:

1)

\(V_{thoát}=V_{CH_4\left(đktc\right)}=3,36\left(l\right)\\ \Rightarrow\%V_{\dfrac{CH_4}{B}}=\dfrac{3,36}{4,48}.100=75\%\Rightarrow\%V_{\dfrac{C_2H_4}{B}}=100\%-75\%=25\%\)

2)

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\\ n_{CH_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ \Rightarrow n_{CaCO_3}=n_{CO_2}=n_{CH_4}=0,15\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{CaCO_3}=100.0,15=15\left(g\right)\)

\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\)  ( mol ) \(\Rightarrow m_{hh}=16x+28y=6\left(g\right)\)   (1)

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)

 x                             x                    ( mol )

\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)

  y                               2y                    ( mol )

\(n_{CO_2}=x+2y=0,4\left(mol\right)\)    (2)

\(\left(1\right);\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\%m_{CH_4}=\dfrac{0,2.16}{6}.100=53,33\%\)

\(\%m_{C_2H_4}=100-53,33=46,67\%\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

  0,1         0,1                   ( mol )

\(m_{Br_2}=0,1.160=16\left(g\right)\)

cảm ơn bạn nha^^

\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)

\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)

Từ (1)(2) suy ra: a = 0,1 ; b = 0,05

Suy ra:

\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)

b)

\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)