Bài 1: 

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)

Bài 2:

PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H₂SO₄ còn dư, KOH p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)

\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\)

\(n_{H_2SO_4}=0,5.0,15=0,075\left(mol\right)\)

PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂

Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{0,075}{1}\) => Fe hết, H₂SO₄ dư

PTHH: Fe + H₂SO₄ --> FeSO₄ + H₂

          0,05->0,05------->0,05

=> \(\left\{{}\begin{matrix}C_{M\left(FeSO_4\right)}=\dfrac{0,05}{0,15}=0,33M\\C_{M\left(H_2SO_4dư\right)}=\dfrac{0,075-0,05}{0,15}=0,167M\end{matrix}\right.\)

\(n_{H_2SO_4}=\dfrac{300.9,8\%}{98}=0,3\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ n_{HCl}=0,3.2=0,6\left(mol\right)\\ n_{BaSO_4}=n_{H_2SO_4}=0,3\left(mol\right)\\ m_{ddsau}=m_{ddBaCl_2}+m_{ddH_2SO_4}-m_{BaSO_4}=200+300-233.0,3=430,1\left(g\right)\\ C\%_{ddHCl}=\dfrac{0,6.36,5}{430,1}.100\approx5,092\%\)

\(n_{BaCl_2}=\dfrac{150.16,64\%}{137+35.2}=0,12\left(mol\right)\)

\(n_{H_2SO_4}=\dfrac{100.14,7\%}{98}=0,15\left(mol\right)\)

Phương trình hóa học : 

BaCl₂ + H₂SO₄ -----> BaSO₄ + 2HCl 

Dễ thấy \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{1}\Rightarrow H_2SO_4\text{ dư }0,15-0,12=0,03\left(mol\right)\)

c) Khối lượng kết tủa : 

\(m_{BaSO_4}=0,12.233=27,96\) (g) 

Khối lượng chất tan : \(m_{HCl}=0,24.36,5=8,76\left(g\right)\) ; 

\(m_{H_2SO_4\left(\text{dư}\right)}=0,03.98=2,94\left(g\right)\) 

c) \(C\%_{H_2SO_4}\)= \(\dfrac{2,94}{150+100}.100\%=1,176\%\)

_{\(C\%_{HCl}=\dfrac{8,76}{150+100}.100\%=3.504\%\)}

d) NaOH + HCl ---> NaCl + H₂O 

      0,24 <-- 0,24

       mol       mol

    2NaOH + H₂SO₄  ---> Na₂SO₄ + 2H₂O

  0,06 mol <-- 0,03 mol  

\(\Rightarrow n_{NaOH}=0,24+0,06=0,3\left(mol\right)\)

\(V_{NaOH}=0,3.2=0,6\left(l\right)\)

a. PTHH    BaCl2 + H2SO4 → BaSO4↓ + 2HCl

b. _ mBaCl2 = 16,61.150:100 = 24,96 g

nBaCl2 = 24.96:208 = 0,12 mol

_ mH2SO4 = 14,7.100:100 = 14,7 g

nH2SO4 = 14,7:98 = 0,15 mol

Ta thấy: nBaCl2 < nH2SO4 ⇒ BaCl2 hết, H2SO4 dư