nP = 3.1/31 = 0.1 (mol) 

4P + 5O2 -to-> 2P2O5 

0.1__0.125_____0.05

mP2O5 = 0.05*142 = 7.1 (g) 

VO2 = 0.125 * 22.4 = 2.8 (l)

tham khảo: https://hoidapvietjack.com/q/648/cho-83-g-hon-hop-a-gom-3-kim-loai-dong-nhom-va-magie-tac-d

HD:

HCl ---> H⁺ + Cl^-

0,2a     0,2a   0,2a

H₂SO₄ ---> 2H⁺ + SO₄^2-

0,2b           0,4b   0,2b

Zn + 2H⁺ ---> Zn²⁺ + H₂

0,3    0,6      0,3        0,3

Theo các pư trên ta có: số mol H⁺ = 0,2a + 0,4b = 0,6 suy ra: a + 2b = 3. (1)

Mặt khác, khối lượng muối = m(Zn²⁺) + m(Cl^-) + m(SO₄^2-) = 65.0,3 + 35,5.0,2a + 96.0,2b = 43,4. Suy ra: 71a + 192b = 238 (2).

Giải hệ (1) và (2) thu được: a = 2; b = 0,5.

Ad giải dễ hiểu tí e ms lớp 8

Cách 2: (Dễ hiểu hơn)

Theo đề bài, ta có số mol HCl là 0,2.a (mol); số mol H2SO4 = 0,2.b (mol) (chú ý phải đổi ml ra lít, số mol = nồng độ x thể tích).

Số mol H2 = 6,72/22,4 = 0,3 mol.

Zn + 2HCl ---> ZnCl2 + H2 (1)

        0,2a        0,1a      0,1a mol

Zn + H2SO4 ---> ZnSO4 + H2 (2)

        0,2b            0,2b       0,2b mol

Theo pt (1) và (2) thì số mol H2 = 0,1a + 0,2b mol. Mà số mol H2 theo đề bài = 0,3 mol nên: 0,1a + 0,2b = 0,3. Suy ra: a + 2b = 3 (3).

Mặt khác, muối thu được gồm ZnCl2 (0,1a mol) và ZnSO4 (0,2b mol). Mà theo đề bài tổng khối lượng muối là 43,3 gam. Nên ta có:

136.0,1a + 161.0,2b = 43,3 Hay 136a + 322b = 433 (4). Giải hệ (3) và (4) thu được a = 2 và b = 0,5.

1.dẫn 4g đồng 2 oxit vào 2.241 lít khí hidro ở dktc nung nóng, toàn bộ nước thu được cho tác dụng với 3.1g natrioxit .tính khối lượng chất thu được sau toàn bộ các phản ứng trên.

2.đốt cháy 3,1 g P đỏ trong bình đựng 3.36 lít khí  ở ĐKTC . sản phẩm thu được sau phản ứng cho vào nước, tính khối lượng axit thu được.

a) \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_M=a\left(mol\right)\\n_{Al}=2a\left(mol\right)\end{matrix}\right.\)

=> a.M_M + 54a = 15,6 (1)

\(n_{Cl_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

M⁰ - 2e --> M⁺²

a--->2a

Al⁰ - 3e --> Al⁺³

2a-->6a

Cl₂⁰ + 2e --> 2Cl^-1

0,6-->1,2

2H⁺¹ + 2e --> H₂⁰

            0,4<--0,2

Bảo toàn e: 2a + 6a = 1,6 

=> a = 0,2 

Thay vào (1) => M_M = 24 (g/mol)

=> M là Mg

b) Xét \(m_{Mg}+m_{Al}=0,1.24+0,2.27=7,8\left(g\right)\)

=> Không có khí thoát ra

=> pư tạo ra sản phẩm khử là NH₄NO₃

PTHH: 4Mg + 10HNO₃ --> 4Mg(NO₃)₂ + NH₄NO₃ + 3H₂O

             0,1---->0,25

            8Al + 30HNO₃ --> 8Al(NO₃)₃ + 3NH₄NO₃ + 9H₂O

            0,2--->0,75 

=> n_HNO3 = 0,25 + 0,75 = 1 (mol)

la

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cyllysylthreonylalanylthreonylseryllysylarginylalanylalanylprolylvalylisutamylprolylleucylglutamylvalylalanylllphenylalanylthreonylcysteinylglutamyllasparaginylvalylarginylphenylalanylglalanylglycylarginylglutamylisoleucyltyeinylserylisoleucylarginylserylseryllyglutamylisoleucylleucylarginylthreonylylglycylglutamyltyrosylthreonylcysteinyltyrosylglycylserylvalylserylcysteinyylvalylthreonylvalylprolylglycylglycylleucylleucylprolylglutamylarginyllysylutamylvalylvalylleucyllysylserylvalyllmylglutamylglutamylglutamylprolyllysylglutamyllysylvalyllysyllysylprolylalanolylprolyllysylprolylvalylglutamylglutlvalylthreonyllysylarginylglutamylargiylthreonyllysylvalylprolylglutamylisolylleucylprolylalanylprolylglutamylprolnylglutamylvalyllysylthreonylisoleucyllprolylglutamylprolylthreonylprolylisoylvalylprolylvalylvalylglycyllysyllysylyllysylglutamylglutamylalanylalanyllylysylglycylvalylprolyllysyllysylthreonlalanylglutamylarginylarginyllysylleuccylglutamyllysylprolylprolylaspartylglnyltyrosylglutaminylleucyllysylalanylvlyllysylglutamylisoleucyllysylaspartyltamylserylglutamylphenylalanylvalylglylanylglutamylcysteinylleucylvalylserylhreonylthreonyltryptophylmethionyllysyeucylarginylglutamylserylprolyllysylhilanylaspartylglycyllysylaspartylarginycylaspartylvalylglutaminylleucylserylahreonylcysteinylvalylleucylarginylleucylthreonylserylthreonylalanyllysylleucrolylvalylarginylphenylalanylvalyllysyamylvalylthreonylvalylvalyllysylglycylserylcysteinylglutamylleucylasparaginyalyltryptophylarginyllysylaspartylglycysylprolylglycylarginylisoleucylvalylpylmethionylarginylalanylleucylthreonylspartylaspartylthreonylaspartylalanylgreonylvalylglutamylasparaginylalanylasysteinylserylserylcysteinylvalyllysylvnylaspartyltryptophylleucylvalyllysylpinylhistidylvalyllysylprolyllysylglycylalanylcysteinylaspartylisoleucylalanyinylisoleucyllysyltryptophylphenylalanlisoleucylprolylalanylglutamylprolylasmylisoleucylleucylarginylaspartylglycyucyllysylisoleucyllysylasparaginylalanoleucylalanylglutamyltyrosylalanylvalyylarginyltyrosylprolylalanyllysylleucylglutamylvalylglutamylleucylleucyllysyylthreonylisoleucyltyrosylglutamyllysyylaspartylalanylglutamylisoleucylserylylglycylglutaminyltryptophyllysylleucyinylprolylserylprolylthreonylcysteinyllglycylglycyllysylarginylphenylalanyllyllysylleucylaspartylglutaminylalanylgaminylalanylleucylasparaginylalanylisoylleucylthreonylvalyllysylglutamylisolanylalanylvalylprolylleucyllysylaspartrginylarginylglutaminylalanylarginylphcylthreonylarginylglutamylalanylasparaysylglycylprolylaspartylisoleucylisolenylalanylaspartylisoleucylisoleucylalaisoleucylleucylvalylisoleucylasparaginylaspartylaspartylglutamylglycylvalyltutamylglycyllysyllysylthreonylserylalareonylglycylisoleucylarginylleucyllysyucylglutamylaspartylglutaminylthreonyleonylalanylthreonylphenylalanylvalylcylutamyllysylmethionylhistidylvalylvalyinylaspartylalanyllysylleucylhistidyltcylisoleucylserylserylglutamylglycyllymylmethionyllysylglutamylvalylthreonyllglutaminylisoleucyllysylalanylglutamiylthreonylalanylglutaminylleucyllysylvlyltyrosylphenylalanylthreonylvalyllysylalanylvalylglutamyllysylaspartylglutteinylglutamylvalylseryllysylaspartylvlalanyllysylaspartylglycylglutamylglutlysyltyrosylserylisoleucyllysylalanylaoleucylleucyllysylisoleucyllysyllysylaylglycylglutamyltyrosylvalylcysteinylatyllysylthreonyllysylalanylasparaginylinylleucylisoleucylglutamylvalylglutamylglutamylvalylphenylalanylvalylglycyllalanylglutamylisoleucylglutamylleucyltidylglycylglutaminyltryptophyllysylleylthreonylalanylserylprolylaspartylcystamylaspartylglycyllysyllysylhistidyliylasparaginylcysteinylglutaminylleucylylvalylserylphenylalanylglutaminylalanalanylalanylasparaginylleucyllysylvalyleucylphenylalanylisoleucylthreonylproylphenylalanylglutamyllysylaspartylglulcysteinylglutamylvalylserylarginylglularginyltryptophylleucyllysylglycylthreonylglycylaspartylaspartylarginylphenlaspartylglycylthreonyllysylhistidylselalanylalanylphenylalanylglutamylasparnylphenylalanylglutamylalanylglutamylaycyllysylleucylisoleucylisoleucylglutalphenylalanylleucylthreonylprolylleucysylglutamyllysylglutamylserylalanylvalleucylserylhistidylaspartylasparaginyllphenylalanyllysylasparaginylaspartylgnylthreonylarginylserylvalylserylmethillysylthreonylhistidylserylisoleucylthylserylisoleucylaspartylaspartylthreonlylglutamylalanylmethionylglycylmethiocylthreonylvalylleucylglutamylglycylasonylglycyllysylleucylglutaminylaspartylysylaspartylglutamylvalylisoleucylleuucylseryllysylalanylaspartylalanylprolysylaspartylglycyllysylglutamylisoleuclanylvalylisoleucyllysylthreonylasparteucylisoleucylleucyllysyllysylalanylleylglutaminyltyrosylthreonylcysteinylasyllysylthreonylserylglycyllysylleucylainylglutamylisoleucyllysylleucylvalylalglutamylvalylmethionylglutamylthreonylalanylglutamylthreonylglutamylisoleuceucylhistidylalanylasparaginyltryptophnylleucylleucylglutaminylthreonylprolylysylglutamylglutamylglycyllysylisoleustidylasparaginylcysteinylarginylleucyycylvalylaspartylphenylalanylglutaminyerylserylalanylhistidylleucylarginylvaglycylleucylleucylarginylprolylleucyllnylalanylglycylglutamylthreonylalanyltlglutamylleucylseryltyrosylglutamylaspyptophyltyrosylleucyllysylglycyllysyllyllysylvalylvalylprolylarginylserylgluylleucylthreonylleucylarginylaspartylvylglycylglutamylvalylglutaminylleucyltnyllysylthreonylhistidylalanylasparagiamylprolylprolylvalylglutamylphenylalalaspartylglutaminylthreonylvalylglutamlvalylleucylglutamylcysteinylglutamylvalanyllysylvalyllysyltryptophylphenylaglutamylisoleucylleucyllysylseryllysyllanylaspartylglycylarginylvalylarginylpartylcysteinylthreonylprolylglutamylalthreonylcysteinylaspartylalanyllysylaylcysteinylasparaginylleucylasparaginylglutamylphenylalanylleucylarginylprolminylvalylarginylglutamyllysylglutamyllutamylcysteinylglutamylleucylserylargalyllysyltryptophylphenylalanyllysylaslysyllysylglycyllysyllysyltyrosylasparylalanylvalylarginylisoleucylleucylvallleucylleucylaspartylaspartylglutamylalutamylvalylarginylthreonylalanylarginlthreonylvalylleucylglutamylglutamylglyllysylasparaginylleucylalanylasparagimylthreonylaspartylthreonylisoleucyllylseryllysylprolylglycylalanylglutamylvglycylaspartylglutamylglutamylisoleucyinyltyrosylglutamylisoleucylleucylthreylisoleucylleucylvalylisoleucylglutamilutamylaspartylalanylglycylasparaginyleucylprolylserylserylarginylthreonylastidylglutamylleucylalanylalanylglutamylylglutaminylasparaginylleucylglutamylyllysylalanylglutamylphenylalanylvalylutamylserylphenylalanylprolylvalylglutlaspartyllysylthreonylleucylglutamylseylvalylisoleucylalanylaspartylglycyllyllysylaspartylalanylthreonylleucylglutyltyrosylvalylvalylmethionylvalylglycynylhistidylleucylthreonylvalylisoleucylvalylvalylprolylleucyllysylaspartylthaminylglutaminylglutamylvalylvalylphenlvalylasparaginylthreonylglutamylglycyenylalanylarginylasparaginylglutamylglpartylserylseryllysyltyrosylisoleucyliylleucylvalyltyrosylthreonylleucylargistidylleucylaspartylaspartylglutaminylvalylserylleucylthreonylasparaginylhisylvalyllysylserylalanylalanylasparaginmylglutamylaspartylleucylarginylisoleupartylisoleucylglutamylthreonylmethionnylphenylalanyltryptophylcysteinyllysyaginylvalylthreonylleucyllysyltryptophtamylglutamylvalylprolylphenylalanylasyrosylarginylvalylaspartyllysyltyrosyllisoleucyllysylaspartylcysteinylglycyllycylglutamyltyrosylisoleucylvalylthreysylserylvalylalanylglutamylleucylleucrolylthreonylglutamylphenylalanylvalyltylglutaminylthreonylvalylthreonylglutnylvalylphenylalanylserylcysteinylglutylalanylasparaginylvalyllysyltryptophyinylglutamylisoleucyllysylglutamylglyclglutamyllysylaspartylglycylserylisolesoleucyllysylaspartylcysteinylarginyllnylglutamyltyrosylalanylcysteinylglycyerylarginylalanylarginylleucylphenylalrolylvalylglutamylisoleucylisoleucylarisoleucylleucylglutamylalanylprolylglyanylleucylalanylglutamylleucylasparagialylglutaminyltryptophylleucylarginylavalylvalylglutaminylglycylaspartyllysyylserylglutamylglycyllysylisoleucylhisylcysteinylaspartylisoleucyllysylprolytamyltyrosylarginylphenylalanylisoleuclanylarginylalanyllysylleucylglutamyllsoleucyllysylthreonylalanylaspartylglurtylvalylglycyllysylprolylleucylthreonspartylalanyltyrosylprolyllysylalanylgylalanyllysylglutamylasparaginylglutameonylisoleucylaspartylthreonylthreonylylphenylalanylarginylisoleucylleucylglllysylglycylarginyltyrosyllysylisoleucysylhistidylglycyllysylalanylglutamylgylleucyllysylvalylisoleucylaspartylvalaraginylleucylglutamylvalylthreonylgluycylglutamylvalylserylleucylalanyltryphreonylaspartylglycylglycylseryllysylivalylglutamylarginylarginylaspartylisotophylvalylleucylalanylthreonylaspartylglutamylphenylalanylthreonylvalylthreylglycylvalylglutamyltyrosylleucylphennylasparaginylarginylvalylglycylthreonthreonylaspartylasparaginylprolylvalylsylaspartylvalylprolylglycylprolylprolleucylthreonylaspartylvalylasparaginylleucylthreonyltryptophylglutamylprolylglycylalanylglutamylisoleucylthreonylaamylleucylarginylaspartyllysylthreonylrtylthreonylalanylmethionylthreonylvalylserylalanylthreonylvalylthreonylaspanylglutamyltyrosylserylphenylalanylargaraginylarginylisoleucylglycylvalylglyonylprolylphenylalanylvalyllysylvalylalarginylprolylserylprolylprolylvalylaspartylglutaminylthreonylglutaminylseryptophylglutamylprolylprolylleucyllysyleucylleucylglycyltyrosylisoleucylisolelglutamylglycyllysylaspartylasparaginylasparaginylmethionyllysylleucylvalylpysylvalylthreonylglycylleucylglutamyllucyltyrosylarginylvalylserylalanylglutylserylaspartylprolylserylglutamylisolylalanylaspartylaspartylalanylphenylalionylaspartylleucylserylalanylphenylalylvalylisoleucylvalylprolylasparaginylcylvalylprolylserylthreonylglycyltyrosthreonyltryptophylcysteinylphenylalanyamylthreonylglycylaspartylarginylvalylrylalanyltyrosylalanylglutamylleucylvalarginylserylaspartyllysylglycylisoleuglutamylasparaginylarginylvalyllysylthsoleucylaspartylvalylasparaginylvalylinylprolyllysylglutamylleucyllysylphenynyllysylaspartylserylvalylhistidylleucrolylaspartylaspartylaspartylglycylglyyrosylvalylvalylglutamyllysylarginylglltryptophylthreonyllysylvalylmethionylpartylleucylglutamylphenylalanylthreontaminylglycyllysylglutamyltyrosylleucynylarginylasparaginyllysylcysteinylglytyrosylvalylaspartylglutamylprolylvalyrolylalanylthreonylvalylprolylaspartylllysyltryptophylarginylaspartylarginylucylphenylalanylleucylthreonyltryptophnylaspartylglycylglycylserylarginylisolylglutamylarginylcysteinylprolylarginlvalylalanylcysteinylglycylglutamylpromethionylglutamylvalylthreonylglycylletophyltyrosylalanyltyrosylarginylvalylylglutaminylglycylalanylseryllysylprollglutamylisoleucylglutaminylalanylvalyalanylprolylglutamylisoleucylphenylalaucylalanylglycylleucylthreonylvalyllyslglutamylleucylprolylalanylthreonylvalprolyllysylisoleucylthreonyltryptophyllisoleucylleucyllysylglutaminylaspartyucylglutamylasparaginylvalylprolyllysyleucylvalylaspartylseryllysylarginylserosylisoleucylisoleucylglutamylalanylvarginylalanylthreonylalanylvalylvalylgspartyllysylprolylglycylprolylprolylalucylthreonylaspartylvalylthreonylaspareucylthreonyltryptophylasparaginylprolylglycylseryllysylisoleucylthreonylaspginylarginylalanylthreonylaspartylseryylleucylserylserylthreonylvalyllysylasyllysylalanylthreonyllysylleucylisoleurosylisoleucylphenylalanylarginylvalylionyltyrosylglycylalanylglycylglutamyllylisoleucylthreonylalanyllysyltyrosyllprolylglycylprolylprolylthreonylarginisoleucylthreonyllysylaspartylalanylvacysteinylglutamylprolylaspartylaspartyleucylthreonylglycyltyrosyltryptophylvolylaspartylthreonylaspartyllysyltryptyllysylmethionylprolylvalyllysylaspartyllysylglycylleucylthreonylasparaginylalanylarginylvalylleucylalanylglutamylglycyllysylprolylseryllysylserylthreoneucyllysylaspartylprolylisoleucylasparylglycyllysylprolylthreonylvalyllysylalvalylarginylleucylasparaginyltryptophylaspartylglycylglycylalanyllysylisolecylglutamylmethionylleucyllysylthreonytophylvalylarginylvalylalanylglutamylgtaminylhistidylleucylleucylprolylglycyminylglutamyltyrosylserylphenylalanylaginyllysylalanylglycylglutamylserylgluaspartylprolylvalylleucylcysteinylargiprolylserylprolylprolylarginyltryptophaginylisoleucylthreonyllysylasparaginyryptophylthreonylvalylprolylglutamyllysoleucylthreonylasparaginyltyrosylisoltylvalylarginylarginyllysylglycyltryptlthreonylthreonylvalyllysylaspartylthreonylprolylleucylthreonylglutamylglycylarginylvalylalanylalanylglutamylasparylserylaspartyltyrosylthreonylglutamylleucylalanyllysylaspartylthreonylphenyprolylprolyltyrosylalanylleucylalanylvarginylhistidylvalylaspartylleucyllysylasparaginylaspartylglycylglycylarginyrosylvalylisoleucylglutamyllysyllysylgrginyltryptophylvalyllysylalanylglycylrtylcysteinylasparaginylphenylalanylareucylglutamylglycylthreonylglutamylvalalylarginylalanylglutamylasparaginylglylprolylserylglutamylprolylthreonylglulutamylaspartylprolylthreonylserylprolrtylleucylhistidylvalylthreonylaspartyoleucylalanylisoleucylalanyltryptophylaginylglycylglycylserylprolylisoleucylglutamylmethionylcysteinylprolylvalylglmethionylarginylvalylasparaginylserylleucyllysylphenylalanyllysylvalylglutapartyllysylglutamyltyrosylvalylleucylaginylalanylisoleucylglycylvalylserylglerylglutamylasparaginylvalylvalylalanyyllysylprolylthreonylisoleucylaspartyltylisoleucylisoleucylvalylisoleucylgluisoleucylprolylvalylprolylphenylalanylthreonylvalylseryltryptophylhistidyllylysylalanylserylaspartylarginylleucyltartylhistidylisoleucylserylalanylhistirylvalylarginylalanylaspartylalanylglylthreonylleucylglutamylasparaginyllysynylserylisoleucylasparaginylvalyllysylcylprolylcysteinyllysylaspartylisoleucthreonyllysylserylserylcysteinyllysyllylprolylglutamylphenylalanylaspartylglucylhistidyltyrosylvalylleucylglutamylrginylarginylthreonyltyrosylisoleucylpmylasparaginyllysylleucylseryltryptophsoleucylprolylasparaginylglycylglutamyinylvalyllysylalanylvalylasparaginyllyyrosylisoleucylglutamylleucyllysylaspautaminylaspartylprolyllysylglutaminylplaspartylvalylglutamylvalylhistidylasplalanylmethionylthreonylisoleucylthreoltyrosylaspartylglycylglycylseryllysyleucylisoleucylglutamyllysylisoleucylalnyltryptophyllysylarginylcysteinylasparolylisoleucylleucylthreonyltyrosylthrlglutamylglycyllysylglutamyltyrosylglunylalanylglutamylasparaginylalanylalanlserylarginylalanylthreonylprolylprolyolylisoleucylaspartylalanylprolyllysylserylleucylglutamylvalyllysylarginylglleucylaspartylalanylserylisoleucylseryonylisoleucylthreonyltryptophylisoleucalylisoleucylvalylprolylglutamylglutamlanylprolylleucylvalylarginylarginylarinylglutamylglutamylglutamylprolylphenonylglutaminylarginylleucylserylisoleuylglycylglutamylserylglutaminylleucylaylarginylprolylaspartylhistidylglycyllvalylglutamylasparaginylaspartylhistidrolylcysteinylthreonylvalylserylvalyllolylprolylisoleucylasparaginylphenylalylisoleucylarginyllysylthreonylserylvautamylprolylprolylleucylaspartylaspartlisoleucylasparaginyltyrosylthreonyllethreonyllysylprolylaspartylserylglutamonylserylthreonylleucylarginylhistidylonyllysylleucylisoleucylglutamylglycylnylarginylvalylarginylalanylglutamylasrolylglycylprolylprolylcysteinylvalylsylaspartylprolylphenylalanylglycylprolllysylprolylisoleucylvalylglutamylasparylmethionylleucylvalyllysyltryptophyltylasparaginylglycylserylprolylisoleucylglutamyllysylarginylglutamylvalylaspphylserylarginylvalylasparaginyllysylsucyllysylalanylasparaginylvalylaspartyucylthreonyltyrosylvalylphenylalanylarparaginylalanylalanylglycylprolylglycyserylaspartylprolyllysylthreonylalanyllprolylprolylglycylprolylprolylisoleuclthreonylserylserylthreonylthreonylisohylglutamylprolylprolylalanylphenylalatamylisoleucylvalylglycyltyrosylphenyleucylvalylglycylthreonylasparaginyllysreonylglutamyllysylmethionylisoleucyllreonylvalyllysylglutamylisoleucylarginyllysylleucylarginylvalylserylalanylvatamylglycylprolylprolylglycylglutamyltlvalylalanylglutamylprolylglutaminylglylleucylaspartylvalylserylvalyllysylglcylmethionylalanylglycyllysylthreonylllylvalylthreonylglycylarginylprolylvallthreonyllysylglutamylglutamylglycylglginylvalylvalylisoleucylaspartylasparalutamylleucylisoleucylisoleucyllysylastylhistidylglycylarginyltyrosylvalylisginylserylcysteinylglycylseryllysylphealylglutamylvalylphenylalanylaspartylvpartylleucyllysylprolylvalylvalylthreocysteinylleucylleucylasparaginyltryptortylaspartylglycylglycylserylglutamylisoleucylisoleucylglutamylarginyllysylathreonyltryptophylarginylglutaminylprolarginylseryllysylcysteinylaspartylisotamylglycylglutaminylglutamyltyrosyllylalanyllysylasparaginyllysylphenylalanvalylglutamylisoleucylglycylprolylisollleucylglycylprolylprolylthreonylseryltyrosylthreonylglutamylarginylglutaminonylleucylaspartyltryptophyllysylglutacylglycylserylprolylisoleucylglutaminytamyllysylarginylarginylhistidylaspartutamylarginylvalylasparaginyllysylargieonylserylphenylalanylleucylvalylglutalhistidylglutaminylmethionyltyrosylglulanylvalylasparaginylglutamylisoleucylrylleucylprolylleucylasparaginylvalylvrtylglutamylvalylprolylprolylthreonyliylvalylarginylglycylaspartylthreonylislutamylprolylvalylhistidylisoleucylprolleucylprolylmethionylprolyllysylisolearaginylglutamylthreonylvalylisoleucylalanylleucylglutaminylisoleucylthreonyinylserylglutamylalanyllysylthreonylglylalanylvalylarginylglutamylaspartyllyylthreonylalanylserylasparaginylarginyarginylasparaginylvalylhistidylvalylglolylserylprolylprolylarginylasparaginysoleucyllysylalanylglutamylserylcysteispartylalanylprolylleucylaspartylaspareucylthreonylhistidyltyrosylvalylisolenylserylarginyllysyllysylalanylglutamyeonylasparaginylthreonylalanylvalylgluucyltryptophyllysylleucylisoleucylprollglutamylphenylalanylarginylvalylarginlglycylisoleucylserylaspartylglutamylclvalylisoleucylglutaminylaspartylprolyolylprolylglycyllysylprolyllysylvalyllylserylmethionylleucylvalylseryltryptotylasparaginylglycylglycylserylprolyliphylleucylglutamyllysylarginylglutamylptophylserylarginylvalylserylarginylalylglycylleucyllysylglycylvalylglutamylrginylleucylleucylglutamylglycylvalyllginylalanylmethionylalanylisoleucylaspglycylprolylprolylserylglutamylprolylsylglycylaspartylprolylisoleucylphenylaserylcysteinylprolylglutamylvalyllysyllisoleucylserylleucylglycyltryptophyllglycylglycylserylprolylisoleucyllysylgethionylglutaminylglutamylglutamylglycllysylarginylvalylasparaginylglutamylpreonylthreonylcysteinylglutamylcysteinlysylglutamylleucylarginyllysyltyrosyllalanylvalylasparaginylglutamylalanylgylaspartylthreonylthreonylglycylglutamrtylisoleucylglutaminylglutamylglutamyleucylaspartylisoleucylglycylalanylglucysteinyllysylalanylglycylserylglutamilanylvalylisoleucyllysylglycylarginylpryptophylglutamylphenylalanylaspartylghionyllysylaspartylglycylvalylhistidylrtylalanylglutaminylleucylglutamylthreerylvalylisoleucylisoleucylisoleucylprrylhistidylthreonylglycyllysyltyrosylsaraginyllysylalanylglycylglutaminyllyslarginylvalyllysylvalylmethionylaspartlaspartylleucyllysylvalylserylaspartylcysteinylarginylleucylseryltryptophyllaspartylglycylglycylaspartylarginylisocylglutamyllysylarginylthreonylisoleucylthreonyllysylvalylasparaginylprolylathreonylphenylalanylvalylvalylprolylasaminylglutaminyltyrosylphenylalanylphelutamylasparaginylarginylphenylalanylgylglutamylthreonylisoleucylglutaminylaaspartylprolylisoleucyltyrosylprolylprsylleucyllysylisoleucylglycylleucylisonylvalylhistidylleucylseryltryptophyllartylglycylglycylserylprolylvalylthreotamylcysteinylleucylalanyltryptophylasysyllysylglutamylalanyltryptophylarginylarginylaspartylvalylglutamylglutamyllvalylglutamylaspartylleucylvalylglutamylphenylalanylarginylvalyllysylalanylalylseryllysylprolylserylalanylthreonycysteinylglutaminylarginylprolylaspartylaspartylleucyllysylglutamylphenylalautamylglycylthreonylasparaginylvalylassoleucyllysylglycylvalylprolylphenylalptophylphenylalanyllysylalanylprolylprinyllysylglutamylprolylvalylleucyltyroaraginyllysylleucylvalylvalylaspartylacylvalylisoleucylprolylglutaminylserylglycylleucyltyrosylthreonylisoleucylthinylleucylglycylthreonylalanylseryllysaraginylvalylleucylglycylarginylprolylisoleucyllysylphenylalanylglutamylserymethionylthreonylleucylseryltryptophylylaspartylglycylglycylseryllysylisoleusoleucylglutamyllysylarginylglutamylaltryptophylvalylhistidylvalylserylseryllthreonyltyrosylthreonylisoleucylprolytidylglutamyltyrosylvalylphenylalanylaminylasparaginyllysyltyrosylglycylisolrtylserylglutamylprolylglutamylthreonyylalanylserylvalylprolylglycylalanylprlserylserylvalylthreonylarginylasparagraginyltryptophylglutamylglutamylprolylserylprolylvalylthreonylglycyltyrosylsylaspartylthreonylthreonylseryllysylaparaginylarginylaspartylprolylisoleucyglycylvalylseryltyrosyllysylvalylthreocylserylaspartyltyrosylglutaminylphenyleucylasparaginylalanylalanylglycylvalylserylaspartylprolylalanylthreonylalaanylprolylprolylglycylprolylprolylphenartyltryptophylthreonyllysylserylserylhylserylprolylprolylleucyllysylaspartylglycyltyrosylisoleucylvalylglutamyltyylglutamylglutamyltryptophylglutamyllyvalylarginylglycylthreonyllysylleucylvlutamylglycylalanylphenylalanyltyrosyllanylvalylasparaginylisoleucylalanylglycylglutamylvalylthreonylaspartylvalylrtylarginylleucylvalylserylprolylasparanylserylvalylarginylaspartylarginylisylglycylvalylisoleucylarginylisoleucylcyllysylprolylprolylprolylthreonylvalyonylasparaginylglutamylarginylthreonyllthreonylisoleucylglutamylthreonylthreethionylvalylisoleucyllysylasparaginylidylglutaminylglycylvalyltyrosylseryllutamylalanylglycylglutamylarginyllysyllaspartylvalylleucylaspartylvalylprolylylphenylalanylleucylalanylhistidylasputamylserylcysteinyllysylleucylthreonylutamylaspartylaspartylglycylglycylserltyrosylvalylisoleucylglutamyllysylarginylalanyltryptophylthreonylprolylvalyylarginylglutaminylasparaginylalanyltholeucylglutaminylglycyllysylalanyltyrosoleucylalanylalanylglutamylasparaginylprolylphenylalanylvalylglutamylthreonleucylarginylglutamylprolylisoleucylthlylglutamylaspartylleucylglutamylvalylraginylthreonylvalylthreonylleucylthreyllysyltyrosylaspartylglycylglycylserynyltyrosylvalylleucylglutamylserylargitamyllysylphenylalanylhistidyllysylvalginylleucylleucylserylarginyllysyltyrosylglutamylglycylaspartylthreonyltyroslanylvalylasparaginylisoleucylvalylglyphenylalanylcysteinylthreonyllysylprolpartylglutamylleucylalanylprolylprolyllphenylalanylarginylaspartyllysylleucylglutamylalanylphenylalanylalanylleucylycyllysylprolyllysylprolyllysylvalylsrtylglutamylalanylaspartylvalylleucylgnylhistidylisoleucyllysylthreonylthreoleucylglutamyllysylisoleucyllysylalanyyllysyltyrosylcysteinylvalylvalylvalylcylserylarginyllysylglycylphenylalanylvalylvalylaspartylhistidylprolylglycylerylphenylalanylaspartylglutamylvalyltlvalylisoleucylseryltryptophyllysylproylglycylseryllysylisoleucylthreonylasputamyllysyllysylglutamylvalylglycyllysrolylvalylthreonylserylalanylserylalanylvalylseryllysylleucylleucylglutamylghenylalanylarginylisoleucylhistidylalaglycylisoleucylserylaspartylprolylleucysylalanyllysylaspartylarginylphenylallprolylaspartylglutaminylprolylisoleucllysylaspartylserylalanylleucylvalylthlylhistidylaspartylglycylglycyllysylprosylisoleucylleucylglutamyllysylarginylarginyltryptophylalanylarginylvalylthistidylprolyltyrosylthreonyllysylphenyucylleucylglutamylglycylcysteinylglutainylvalylserylalanylglutamylasparaginyycylaspartylprolylserylprolylprolylserllysylaspartylprolylisoleucylalanyllysaginylprolylglutamylalanylisoleucylaspaginylserylvalylaspartylleucylthreonylinylhistidylaspartylglycylglycylseryllleucylvalylglutamyltyrosylglutaminyllymyltryptophylarginylarginylalanylasparlserylcysteinylprolylglutamylthreonyllleucylarginylaspartylglycylglutaminyltnylvalylleucylalanylvalylasparaginylalylprolylalanylhistidylvalylprolylglutatylarginylleucylglutamylprolylprolylglalanylasparaginylmethionylalanylarginyllysylvalylglycylaspartylthreonylleucysoleucyllysylglycylvalylprolylphenylalhyllysyllysylglutamylaspartylarginylasylarginylisoleucylaspartylvalylthreonylutamylisoleucylarginylasparaginylalancylglycylisoleucyltyrosylserylleucylthlalanylglycylseryllysylthreonylvalylseaspartyllysylprolylglycylprolylprolylarylglutamylisoleucylarginyllysylaspartyltryptophyllysylglutamylprolylleucylaylisoleucylthreonylasparaginyltyrosylvrtylvalylalanylserylalanylglutaminyltrlthreonylseryllysyllysyllysylserylhistleucylasparaginylglutamylglycylasparaganylarginylvalylalanylalanylglutamylasinylglycylprolylphenylalanylvalylglutayllysylalanylleucylaspartylprolylleucyolyllysylaspartylleucylhistidylhistidyeonylglutamylvalylserylleucylvalyltryplarginylaspartylglycylglycylserylprolyylvalylglutamyltyrosylglutaminylglutamspartyltryptophylisoleucyllysylphenylaraginylleucylglutamylcysteinylvalylvaltaminylglycyllysylthreonyltyrosylarginylglutamylasparaginylisoleucylvalylglythreonylthreonylisoleucylprolylisoleucyllysylleucylvalylprolylprolylserylvaleucylisoleucylglutamylglycylleucylvalyonylvalylarginylphenylalanylprolylalanlylprolylvalylprolylthreonylalanyllysyglycylserylglutamylisoleucyllysylthreohreonylvalylglutamylthreonylaspartylaslleucylthreonylisoleucyllysylasparaginrtylthreonylglycylglutamyltyrosylglutaaraginylalanylalanylglycylseryllysylthlthreonylvalylleucylaspartylvalylprolyolylisoleucylasparaginylisoleucylleucylhistidylmethionylthreonylisoleucylserysylaspartylaspartylglycylglycylserylpylisoleucylvalylglutamyllysylglutaminyylthreonyltryptophylglycylvalylvalylseyllysylleucyllysylisoleucylprolylhistiinylglutamyltyrosylvalylphenylalanylarraginyllysylisoleucylglycylvalylglycylonylprolylthreonylvalylalanyllysylhistlylserylprolylprolylglycyllysylprolylvhreonylglutamylasparaginylalanylalanyllleucylprolyllysylserylaspartylglycylgycyltyrosyltyrosylmethionylglutamylargcyllysyltryptophylvalylarginylvalylasplalanylaspartylleucyllysylphenylalanylosylglutamylglycylasparaginylthreonyltlylphenylalanylalanylglutamylasparaginlprolylserylprolylserylserylaspartylprginylprolylisoleucyllysylprolylprolylgylprolyllysylleucyllysylaspartyllysylspartylleucylvalyltryptophylthreonyllysycylserylprolylisoleucylleucylglycyltytaminyllysylprolylglycylthreonylalanylnylisoleucylasparaginyllysylaspartylglnylcysteinylalanylphenylalanylarginylvamylglycylasparaginylglutamyltyrosylarsylalanylalanylasparaginylisoleucylvallarginylglutamylleucylalanylglutamylselisoleucylleucylhistidylprolylprolylgllylthreonylcysteinylarginylaspartylvallglycylglutaminylthreonylisoleucylargillysylglycylarginylprolylglutamylprolylthreonyllysylglutamylglycyllysylvalylnylvalylaspartylleucylisoleucylglutamiglutamylleucylglutaminylisoleucyllysylartylhistidylglycyllysyltyrosylisoleucnylserylserylglycylhistidylalanylglutalasparaginylvalylleucylaspartylarginylylasparaginylleucyllysylvalylthreonylalasparaginylcysteinylthreonylisoleucylrolylleucylaspartylasparaginylglycylglsparaginylphenylalanylisoleucylvalylglraginylglutaminyllysylglycyltryptophyltylvalylthreonyllysylarginylleucylisolucylalanylasparaginylasparaginylglutamvalylcysteinylalanylglutamylasparaginyhreonylisoleucylglutamylthreonyllysyltsoleucylasparaginylprolylisoleucylaspaylglutamylasparaginylleucylhistidylisolthreonylphenylalanylvalyltyrosylleucylaspartyltyrosylaspartylglycylglycylsesylhistidylvalylglutamylarginylarginyltyltryptophylglutamylarginylvalylhistiutamylthreonylhistidyltyrosylmethionyllutamylasparaginylglutaminylisoleucyltlylglutaminylthreonyllysylasparaginylgartyltryptophylvalyllysylthreonylglutaamylaspartylleucylglutaminyllysylprolyylserylglycylvalylleucylthreonylvalyllleucylarginylleucylglutamylalanylglycylalanylprolylglutamylvalylalanyltryptotylalanylthreonylaspartylleucylthreonylisoleucylaspartylthreonylarginylalanylserylleucylthreonyllysylalanyllysylartyrosylvalylvalylthreonylalanylthreonyylphenylalanylvalylalanyltyrosylalanylaspartyllysylprolylglycylprolylvalylarlvalylaspartylvalylserylserylaspartylayltryptophylaspartylprolylprolylglutaminylglutamylisoleucylglutaminylasparagysylcysteinylglutamylthreonyllysylargieonyltyrosylserylalanylthreonylvalylleeonylvalylthreonyla

PTHH

  Fe + 2HCl --->FeCl2 + H2 
0.5==1======0.5====0.5 
2H2 + 02 ---->2H20 
0.5========0.5 
nH20=0.5 
nHCl=2  =>nHCl dư=1mol 
PTHH:

10FeCl2 + 6KMnO4 + 24H2SO4 ----> 3K2SO4 + 5Fe2(SO4)3 + 6MnSO4 + 10Cl2 + 24H2O 
0.25======0.15========================... 
2KMnO4 + 16HCl --> 2MnCl2 + 5Cl2 + 2KCl + 8H2O 
0.0625=====0.5===========0.15625 
Cl2 + 2FeCl2 ----->2FeCl3 
=====0.25======0.25 
nKMn04=0.2125mol 
VKMn04=0.425 
mFeCl3=40.625g 
Nếu sửa nồng độ HCl thành 0.65 : 
nHCl dư=1.6 mol
2KMnO4 + 16HCl --> 2MnCl2 + 5Cl2 + 2KCl + 8H2O 
0.1=======0.8 
nKMn04=0.25 mol
=>VKMn04=0.5 (l)

Đáp án : C

n_H+ = 2n_H2SO4 + n_HCl = 0,42 mol

, n_H2 = 0,17 mol => n_{H+ dư} = 0,08 mol

Trong dung dịch chắc chắn có Al³⁺ và Fe²⁺ với số mol lần lượt là x và y

=> m_Al + m_Fe = 27x + 56y = 7,52 – 2,56 = 4,96g

Lại có : 3n_Al + 2n_Fe = 2n_H2 (Bảo toàn e) => 3x + 2y = 0,34

=> x = 0,08 ; y = 0,05 mol

, n_NaNO3 = 0,02 mol

Khi cho NaNO₃ vào thì xảy ra phản ứng với Cu trước Fe²⁺

3Cu + 8H⁺ + 2NO₃^- à 3Cu²⁺ + 2NO + 4H₂O

=> Cu dư và trong muối có : 0,03 mol Cu²⁺ ; 0,02 mol Na⁺ ; 0,08 mol Al³⁺ ; 0,05 mol Fe²⁺ ; 0,18 mol SO₄^2- ; 0,06 mol Cl^-

=> m_muối = 26,75g và V_NO = 0,448 lit

b.

4P        + 5O₂ → 2P₂O₅

0,16→    0,2

Dư:      0,025

Sau pứ m_{(bình 1)} = m_P2O5 = 11,36 (g)

O₂        + 2C → 2CO

0,025→ 0,05      0,05

Dư:         0,25

Sau pứ _{m(bình 2}) = m_Cdư = 3 (g)