a, Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)
\(16n_{CH_4}+28n_{C_2H_4}=3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,1\left(mol\right)\\n_{C_2H_4}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%\approx53,33\%\\\%m_{C_2H_4}\approx46,67\%\end{matrix}\right.\)
- Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)
b, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Có: m tăng = mC2H4 = 0,05.28 = 1,4 (g)
a) \(n_{hh}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a+b=0,15\\16a+28b=3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)
b) \(m=m_{C_2H_4}=0,05.28=1,4\left(g\right)\)