Gọi số mol KMnO4, KClO3 là a, b (mol)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
a-------------->0,5a---->0,5a--->0,5a
2KClO3 --to--> 2KCl + 3O2
b------------->b---->1,5b
=> \(\left\{{}\begin{matrix}0,5a+1,5b=0,2\\197.0,5a+87.0,5a+74,5b=21,65\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}0,5a+1,5b=0,2\\142a+74,5b=21,65\end{matrix}\right.\)
=> a = b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}m_{KClO_3}=0,1.122,5=12,25\left(g\right)\\m_{KMnO_4}=0,1.158=15,8\left(g\right)\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{KMnO_4}=x\left(mol\right)\\n_{KClO_3}=y\left(mol\right)\end{matrix}\right.\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\Rightarrow\dfrac{1}{2}x\cdot197+y\cdot74,5=21,65\left(1\right)\)
\(\Rightarrow\dfrac{1}{2}x+\dfrac{3}{2}y=0,2\left(2\right)\)
Từ (1) và (2)\(\Rightarrow\left\{{}\begin{matrix}x=0,16\\y=0,08\end{matrix}\right.\)
\(\%m_{KMnO_4}=\dfrac{0,16\cdot158}{0,16\cdot158+0,08\cdot122,5}\cdot100\%=72,06\%\)
\(\%m_{KClO_3}=100\%-72,06\%=27,94\%\)
Gọi nKMnO4 = a (mol); nKClO3 = b (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: a ---> 0,5a ---> 0,5a ---> 0,5a
2KClO3 -> (t°) 2KCl + 3O2
Mol: b ---> b ---> 1,5b
Ta có:
m chất rắn sau phản ứng = 0,5a . 197 + 0,5a . 87 + 74,5 . b = 142a + 74,5b = 21,65
nO2 = 0,5a + 1,5b = 4,48/22,4 = 0,2
=> a = b = 0,1 (mol)
mKMnO4 = 0,1. 158 = 15,8 (g)
mKClO3 = 0,1 . 122,5 = 12,25 (g)